Esterification of acetic acid with butanol in the presence of ion-exchange resins as catalysts

Industrial and Engineering Chemistry Research

Volumn 42, Issue 10, 2003, Pages 2146-2155

  Gangadwala, Jignesh ^a   Mankar, Surendra ^a   Mahajani, Sanjay ^a   Kienle, Achim ^b   Stein, Erik ^b  

^a INDIAN INSTITUTE OF TECHNOLOGY BOMBAY   (India)

^b MAX PLANCK INSTITUTE FOR DYNAMICS OF COMPLEX TECHNICAL SYSTEMS   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID; CATALYSTS; DISTILLATION; ION EXCHANGE; REACTION KINETICS; RESINS;

MOLE RATIO;

ESTERIFICATION;

ACETIC ACID; AMBERLYST 15; BUTANOL; ION EXCHANGE RESIN; UNCLASSIFIED DRUG;

CATALYST;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL MODEL; CHEMICAL REACTION KINETICS; ELEY RIDEAL MODEL; ESTERIFICATION; ION EXCHANGE; LANGMUIR HINSHELWOOD HOUGEN WATSON MODEL; MATHEMATICAL ANALYSIS; PARTICLE SIZE; REACTION ANALYSIS; TEMPERATURE MEASUREMENT; VALIDATION PROCESS;

EID: 0038326894     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie0204989     Document Type: Article

References (33)

1. Leyes, C. E.; Othmer, D. F. Continuous esterification of butanol and acetic acid, Kinetic and distillation considerations. Trans. Am. Inst. Chem. Eng. 1945, 41, 157-196.
2. Chakrabarty, A.; Sharma, M. M. Cationic exchange resins as catalyst. React. Polym. 1993, 20, 1-45.
3. Zheng, R.; Zeng, J. Catalyst for butyl acetate using strong acidic cation-exchange resin. Xiamen Daxue Xuebao, Ziran Kexueban 1997, 36, 67-70; Chem. Abstr. 127, 1614845.
4. Zheng, R.; Zeng, J. Catalyst for butyl acetate using strong acidic cation-exchange resin. Xiamen Daxue Xuebao, Ziran Kexueban 1997, 36, 67-70; Chem. Abstr. 127, 1614845.
5. Zheng, R.; Zeng, J. Kinetics of esterification of acetic acid and n-butanol on strong cation-exchange resin. Xiamen Daxue Xuebao, Ziran Kexueban 1998, 37, 224-227; Chem. Abstr. 129, 951425.
6. Zheng, R.; Zeng, J. Kinetics of esterification of acetic acid and n-butanol on strong cation-exchange resin. Xiamen Daxue Xuebao, Ziran Kexueban 1998, 37, 224-227; Chem. Abstr. 129, 951425.
7. Liao, A.; Tong, Z. Synthesis of n-butyl acetate catalyzed by Amberlyst. Huaxue Fanying Gongcheng Yu Gongy 1995, 11, 34-45; Chem. Abstr. 124, 179409.
8. Liao, A.; Tong, Z. Synthesis of n-butyl acetate catalyzed by Amberlyst. Huaxue Fanying Gongcheng Yu Gongy 1995, 11, 34-45; Chem. Abstr. 124, 179409.
9. Liao, S.; Zhange, X. Study on esterification catalyzed by solid acid catalyst. II Kinetics and mechanism of liquid-phase Esterification. Hunan Ligong Daxue Xuebao, Ziran Kexueban 1997, 25, 88-92; Chem. Abstr. 128, 2433638.
10. Liao, S.; Zhange, X. Study on esterification catalyzed by solid acid catalyst. II Kinetics and mechanism of liquid-phase Esterification. Hunan Ligong Daxue Xuebao, Ziran Kexueban 1997, 25, 88-92; Chem. Abstr. 128, 2433638.
11. Liao, S.; Xu, B.; Li, Z. Catalysis of solid acid catalyst for esterification I preparation and characterization of the catalyst. Fenzi Cuihua 1993, 76, 475-478; Chem. Abstr. 120, 1376125.
12. Liao, S.; Xu, B.; Li, Z. Catalysis of solid acid catalyst for esterification I preparation and characterization of the catalyst. Fenzi Cuihua 1993, 76, 475-478; Chem. Abstr. 120, 1376125.
13. Li, B.; Li, Z.; Fang, W. Synthesis of n-butyl acetate catalyzed by inorganic salts. Guangxi Huagong 1998, 27, 19-22; Chem. Abstr. 129, 29335.
14. Li, B.; Li, Z.; Fang, W. Synthesis of n-butyl acetate catalyzed by inorganic salts. Guangxi Huagong 1998, 27, 19-22; Chem. Abstr. 129, 29335.
15. Ma, D.; Shuzhen, G. Synthesis of n-butyl acetate in liquid phase with zeolites as catalysts. Shiyon Huagong 1989, 18; Chem. Abstr. 112, 79882.
16. Ma, D.; Shuzhen, G. Synthesis of n-butyl acetate in liquid phase with zeolites as catalysts. Shiyon Huagong 1989, 18; Chem. Abstr. 112, 79882.
17. Ma, D.; Shuzhen, G.; Ronghin, Y. Continuous synthesis process of n-butyl acetate in liquid phase with zeolites as catalysts. Hauxue Shijie 1994, 35, 634-636; Chem. Abstr. 123, 173453.
18. Ma, D.; Shuzhen, G.; Ronghin, Y. Continuous synthesis process of n-butyl acetate in liquid phase with zeolites as catalysts. Hauxue Shijie 1994, 35, 634-636; Chem. Abstr. 123, 173453.
19. Zheng, H.; Zhung, M.; Li, H. Catalytic property of HZSM5 in the esterification reaction. Effect of cation exchange degree, reaction condition and structure of reactant. Ranliao Hauxue Xuebao 1989, 17, 62-68; Chem. Abstr. 112, 178027.
20. Zheng, H.; Zhung, M.; Li, H. Catalytic property of HZSM5 in the esterification reaction. Effect of cation exchange degree, reaction condition and structure of reactant. Ranliao Hauxue Xuebao 1989, 17, 62-68; Chem. Abstr. 112, 178027.
21. Li, Y.; Lin, G.; Li, Y. Application of zeolites catalyst in the esterification reaction of acetic acid in liquid phase. Tiaiyuan Gongue Daxue Xuebao 1996, 27, 53; Chem. Abstr. 126, 225003.
22. Li, Y.; Lin, G.; Li, Y. Application of zeolites catalyst in the esterification reaction of acetic acid in liquid phase. Tiaiyuan Gongue Daxue Xuebao 1996, 27, 53; Chem. Abstr. 126, 225003.
23. Janowsky, R.; Groebel, M.; Knippenberg, U. Nonlinear dynamics in reactive distillation - phenomena and their technical use; Final Report FKZ 03 D 0014 B0; Huels Infracor GmbH: experSCience, Marl, 1997.
24. Venimadhavan, G.; Malone, M. F.; Doherty, M. F. A novel distillate policy for batch reactive distillation with application to production of butyl acetate. Ind. Eng. Chem. Res. 1999, 38, 714-722.
25. Hanika, J.; Kolena, J.; Smejkal, Q. Butyl acetate via reactive distillation: Modeling and Experiments. Chem. Eng. Sci. 1999, 54, 5205-5209.
26. Zhicai, Y.; Xianbao, C.; Jing, G. Esterification - distillation of butanol and acetic acid. Chem. Eng. Sci. 1998, 53, 2081-2088.
27. Saha, B.; Chopade, S. P.; Mahajani, S. M. Recovery of dilute acetic acid through esterification in reactive distillation column. Catal. Today 2000, 60, 147-157.
28. Minotti, M.; Doherty, M. F.; Malone, M. F. Design for Simultaneous Reaction and Liquid-Liquid Extraction. Ind. Eng. Chem. Res. 1998, 37, 4748-4755.
29. NAG Fortran Library Manual; NAG Ltd.: Oxford, U.K., 1993.
30. Caracotsios, M.; Stewart, W. Sensitivity analysis of initial value problems with mixed ODEs and algebraic equations. Comput. Chem. Eng. 1985, 9, 359-365.
31. Lee, M.; Wu, H.; Kang, C.; Lin, H. Kinetics of catalytic esterification of acetic acid and amyl alcohol over Amberlyst 15. J. Chem. Eng. Jpn. 2001, 34, 960-963.
32. Lee, M.; Wu, H.; Lin, H. Kinetics of catalytic esterification of acetic acid and amyl alcohol over Dowex. Ind. Eng. Chem. Res. 2000, 39, 4094-4099.
33. Song, W.; Venimadhavan, G.; Manning, J.; Malone, M.; Doherty, M. Measurement of residue curve maps and heterogeneous kinetics in methyl acetate synthesis. Ind. Eng. Chem. Res. 1998, 37, 1917-1928.