Analysis of solvent-free ethyl oleate enzymatic synthesis at equilibrium conditions

Enzyme and Microbial Technology

Volumn 38, Issue 7, 2006, Pages 914-920

  Bucala V ^a   Foresti, M L ^a   Trubiano, G ^a   Ferreira, M L ^a   Briozzo, M ^b   Bottini, S ^a  

^a PLAPIQUI UNS CONICET   (Argentina)

^b UNIVERSIDAD NACIONAL DEL SUR   (Argentina)

Author keywords

Biphasic constant; Chemical reaction equilibrium; Enzymatic esterification; Liquid liquid equilibrium

Indexed keywords

COMPUTATION THEORY; ENZYMES; ESTERIFICATION; ETHANOL; FATTY ACIDS; REACTION KINETICS; SOLVENTS;

BIPHASIC CONSTANT; CHEMICAL REACTION EQUILIBRIUM; ENZYMATIC ESTERIFICATION; LIQUID-LIQUID EQUILIBRIUM;

OLEIC ACID;

ALCOHOL; FATTY ACID; OLEIC ACID; TRIACYLGLYCEROL LIPASE; WATER;

ARTICLE; CANDIDA ANTARCTICA; CATALYST; CHEMICAL REACTION; CONTROLLED STUDY; ENZYME SYNTHESIS; EQUILIBRIUM CONSTANT; ESTERIFICATION; NONHUMAN; PARTITION COEFFICIENT; TEMPERATURE DEPENDENCE; THERMODYNAMICS;

CANDIDA ANTARCTICA;

EID: 33645240028     PISSN: 01410229     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.enzmictec.2005.08.017     Document Type: Article

References (21)

1. E.C. Voutsas, H. Stamatis, F.N. Kolisis, and D. Tassios Solvent effects on equilibrium position and initial rate of lipase-catalyzed esterification reactions in organic solvents: experimental results and prediction capabilities Biocatal Biotransform 20 2 2002 101 109
2. J.S. Dordick Enzymatic catalysis in monophasic organic-solvents Enzyme Microb Technol 11 1989 194 211
3. N.J. Jin, S.H. Lee, and S.B. Lee Enzymatic production of enantiopure ketoprofen in a solvent-free two-phase system J Mol Catal B: Enzymatic 26 2003 209 216
4. M. Shima, M. Tanaka, Y. Kimura, S. Adachi, and R. Matsuno Hydrolysis of the oil phase of a W/O/W emulsion by pancreatic lipase J Controlled Release 94 2004 53 61
5. F. Borzeix, F. Monot, and J.P. Vandecasteele Strategies for enzymatic esterifications in organic solvents: comparison of microaqueous, biphasic and micellar systems Enzyme Microb Technol 14 1992 791 797
6. R.J. Twedell, S. Kermasha, D. Combres, and A. Marty Esterification and interesterification of lipases from Rhizopus Niveus and Mucor Miehei in three different types of organic media: a comparative study Enzyme Microb Technol 22 1998 439 445
7. A.E.M. Janssen, A. Van der Padt, M.V. Sonsbeek, and K. Van T'Riet The effect of organic solvents of the equilibrium position of enzymatic acylglycerol synthesis Biotech Bioeng 41 1993 95 103
8. G. Sandoval, J.S. Condoret, P. Monsan, and A. Marty Esterification by immobilizated lipase in solvent-free media: kinetic and thermodynamics arguments Biotechnol Bioeng 78 3 2002 313 320
9. K. Martinek, A.N. Semenov, and I.V. Berezin Enzymatic synthesis in biphasic aqueous-organic systems. I. Chemical equilibrium shift Biochim Biophys Acta 658 1981 76 89
10. T. Antczak, D. Hiler, A. Krystynowicz, S. Bielecki, and E. Galas Mathematical modeling of esther synthesis by lipase in biphasic system J Mol Catal B: Enzymatic 11 2001 1043 1050
11. D.K. Eggers, H.W. Blanch, and J.M. Prausnitz Extractive catalysis: solvent effects on equilibria of enzymatic reactions in two-phase systems Enzyme Microb Technol 11 1989 84 89
12. A.E.M. Janssen, A. Van der Padt, and K. Van T'riet Solvent effects on lipase-catalyzed esterification of glycerol and fatty acids Biotech Bioeng 42 1993 953 962
13. P.Y. Yong, and B. Al Duri Kinetic studies on immobilized lipase esterification of oleic acid and octanol J Chem Tech Biotechnol 65 1996 239 248
14. T. Garcia, A. Coteron, M. Martinez, and J. Aracil Kinetic model for the esterification of oleic acid and cetyl alcohol using an immobilized lipase as catalyst Chem Eng Sci 55 8 2000 1411 1423
15. Novo Nordisk Industries A/s. NOVO. Product sheet B 606c-GB 200, Novo Industries; 1992.
16. M.L. Foresti, and M.L. Ferreira Frequent analytical/experimental problems in lipase-mediated synthesis in solvent-free systems and how to avoid them Anal Bioanal Chem 381 7 2005 1408 1425
17. J.M. Sørensen, and W. Arlt Liquid-liquid equilibrium data collection Chemistry data series vol. V 1979 Dechema Frankfurt Part 1
18. Z. Zhang, and G. Hill Ternary liquid-liquid equilibria of water, ethanol, and oleic acid J Chem Eng Data 36 1991 453 456
19. A. Fredenslund, R.L. Jones, and J.M. Prausnitz Group-contribution estimation of activity coefficients in nonideal liquid mixtures AIChE J 21 1975 1086 1099
20. M.L. Michelsen The isothermal flash problem. Part 1. Stability Fluid Phase Equilib 9 1982 1 19
21. T.E. Daubert, and R.P. Danner Physical and thermodynamic properties of pure chemicals: data compilation 1989 Hemisphere Publishing Corp. Bristol, PA