Effect of temperature on kinetics and adsorption profile of endothermic chemisorption process: -Tm(III)-PAN loaded PUF system

Separation Science and Technology

Volumn 41, Issue 4, 2006, Pages 705-722

  Saeed, Muhammad Mufazzal ^a   Ahmed, Munir ^a  

^a PAKISTAN INSTITUTE OF NUCLEAR SCIENCE AND TECHNOLOGY   (Pakistan)

Author keywords

1 (2 pyridylazo) 2 naphthol; Adsorption; Chemisorption; Kinetics; Polyurethane foam; Thermodynamics; Tm(III)

Indexed keywords

ACTIVATION ENERGY; ADSORPTION; GIBBS FREE ENERGY; PH EFFECTS; REACTION KINETICS; THERMAL EFFECTS; THERMODYNAMICS;

1-(2-PYRIDYLAZO)-2-NAPHTHOL; KINETICS]; POLYURETHANE FOAMS; THERMODYNAMIC PARAMETERS;

CHEMISORPTION;

ACTIVATION ENERGY; ADSORPTION; CHEMISORPTION; GIBBS FREE ENERGY; PH EFFECTS; REACTION KINETICS; THERMAL EFFECTS; THERMODYNAMICS;

ABSORPTION; ABSORPTION ISOTHERM; CHEMICAL REACTION; DIFFUSION; POLYURETHANE; THERMODYNAMICS;

EID: 33644975780     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496390500527993     Document Type: Article

References (33)

1. Prasada Rao, T. and Kala, R. (2004) On-line and off-line preconcentration of trace and ultratrace amounts of lanthanides. Talanta, 63 (4): 949-959.
2. El-Shahawi, M.S. and Nassif, H.A. (2003) Retention and thermodynamic characteristics of mercury(II) complexes onto polyurethane foams. Anal. Chim. Acta, 481:29-39.
3. Rengan, K. and Sun, B.C. (2004) Sorption of Zn(II) and Cd(II) by chelating resins: comparison of three resins. J. Radioanal. Nucl. Chem., 262 (1): 175-182.
4. Gao, J., Hu, G., Kang, J., and Bai, G. (1993) 1-(2pyridylazo)-2-naphthol (PAN) as extrctant in solid-liquid extraction of some trivalent rare earth elements. Talanta, 40 (2): 195-200.
5. Sekine, T. and Hasegawa, Y. (1977) Applications of solvent extraction in analytical and inorganic chemistry. In Solvent Extraction Chemistry; Marcel Dekker, Inc.: New York, 363-649.
6. Kuznik, B. (1981) Solvent extraction of certain rare earth metal ions with 1-(2-pyridylazo)-2-naphthol (PAN). J. Inorg. Nucl. Chem., 43 (12): 3363-3368.
7. Buchmeiser, M.R. (2001) Recent advances in the quantification of lanthanides. Rev. Anal. Chem., 20 (3): 161-184.
8. Paldgyi, S. and Braun, T. (1992) Separation and preconcentration of trace elements and inorganic species on solid polyurethane foam sorbent. In Preconcentration Techniques for Trace Elements; Alfassi, Z.B. and Wai, C.M. eds., CRC Press: Boca Raton, 363-400.
9. Saeed, M.M. and Rusheed, A. (1998) Analytical application of polyurethane foam in separation and preconcentration processes - A review. Sci. Int., 10: 273-286.
10. Saeed, M.M. and Rusheed, A. (2002) Investigation of Tb(III) by 2-thenoyltrifluoroacetone supported onto polyurethane foam. Radiochim. Acta, 90 (1): 35-42.
11. Saeed, M.M., Ahmed, M., Chaudary, M.H., and Gaffar, A. (2003) Kinetics, thermodynamics, and sorption profile of Eu(III) and Tm(III) on 4-(2-pyridylazo) resorcinol (PAR) imbedded polyurethane foam. Solvent Extr. Ion Exch., 21 (6): 881-898.
12. Ruthven, D.G. (2002) Adsorption (chemical engineering). In Encyclopedia of Physical Science and Technology, 3rd ed.; Meyers, R.A. (ed.), Academic Press: New York; Vol. 1, 251-271.
13. Anderson, R.G. and Nickless, G. (1967) Heterocyclic azo dystuffs in analytical chemistry: A review. Analyst, 92: 207-238.
14. Weber, W.J. and Morris, J.C. (1963) Kinetics of adsorption on carbon from solution. J. Sanit. Eng. Div. ASCE, 89 (SA2): 31-59.
15. Reichenberg, D. (1953) Properties of ion exchange resins in relation to their structure. III. Kinetics of exchange. J. Am. Chem. Soc., 75 (2): 589-597.
16. Lagergren, S. (1898) Zur theorie der sogennanten adsorption geloster stoffe. K. Seveska Vetenskapsaked Handle, 24: 1-39.
17. Leenson, I.A. (1986) Thermodynamics and kinetics of chemical equilibrium in solution. J. Chem. Edu., 63 (5): 437-440.
18. Barrer, R.M., Bartholomew, R.F., and Rees, L.V.C. (1963) Ion exchange in porous crystals part 1. Self- and exchange-diffusion of ions in chabazites. J. Phys. Chem. Solids, 24 (1): 51-62.
19. Aly, H.M. and Kamar, E.M. (2003) Kinetic studies of some actinide ions exchange on AI-13-phosphatoantimonic acid. Solvent Extr. Ion Exch., 21 (4): 613-620.
20. Vallet, V., Wahlgren, U., and Grenthe, I. (2003) Chelate effect and thermodynamics of metal complex formation in solution: A quantum chemical study. J. Am. Chem. Soc., 125 (48): 14941-14950.
21. Choppin, G.R. and Morgenstern, A. (2000) Thermodynamics of solvent extraction. Solvent Extr. Ion Exch., 18 (6): 1029-1049.
22. Thomas, J.M. (1961) The existence of endothermic adsorption. J. Chem. Edu., 38 (3): 138-139.
23. Freundlich, H. (1926) Colloid and Capillary Chemistry; Methuen: London, 397.
24. Dubinin, M.M. and Radushkevich, L.V. (1947) The equation of the characteristic curve of activated charcoal. Proc. Acad. Sci. USSR, Phys. Chem. Sect., 55: 331-333.
25. Langrnuir, I. (1918) The adsorption of gases on plane surface of glass, mica and platinum. J. Am. Chem. Soc., 40 (7): 1361-1403.
26. Oblad, A.G., Goyal, S.K., Ramakrishnan, R., and Sunder, S. (1978) Catalysis and catalysts. In Encyclopedia of Chemical Processing and Design; McKetta, J.J. and Cunningham, W.A. eds., Marcel Dekker, Inc.: New York; Vol. 6, 436-442.
27. Faust, S.D. and Aly, O.M. (1987) Elements of surface chemistry. In Adsorption Processes for Water Treatment; Butterworth Publs.: Boston, 1-22.
28. Yadava, K.P., Tyagi, B.S., and Singh, V.N. (1991) Effect of temperature on the removal of lead(II) by adsorption on china clay and wollastonite. J. Chem. Tech. Biotechnol., 51 (1): 47-60.
29. Clark, A. (1970) Thermodynamics of adsorption. In The Theory of Adsorption and Catalysis; Academic Press: New York, 1-16.
30. El-Kamash, A.M., El-Sayed, A.A., and Aly, H.F. (2002) Thermodynamics of uranium extraction from nitric acid solution by TBP loaded on inert supporting material. J. Radioanal. Ncld. Chem., 253 (3): 489-495.
31. Sabio, E., González-Martin, M.L., Ramiro, A., González, J.F., Bruque, J.M., Labajos-Broncano, L., and Encinar, J.M. (2001) Influence of the regeneration temperature on the phenols adsorption on activated carbon. J. Colloid Interface Sci., 242 (1): 31-35.
32. Gimeno, O., Plucinski, P., Kolaczkowski, S.T., Rivas, F.J., and Alvarez, P.M. (2003) Removal of the herbicide MCPA by commercial activated carbons: Equilibrium, kinetics and reversibility. Ind. Eng. Chem. Res., 42 (5): 1076-1086.
33. Cotton, F.A., Wilkinson, G., Murillo, C.A., and Bochmann, M. (1999) Some cross-cutting topics. In Advance Inorganic Chemistry, 6th ed.; John Wiley & Sons, Inc., 27-29.