Removal of the herbicide MCPA by commercial activated carbons: Equilibrium, kinetics, and reversibility

Industrial and Engineering Chemistry Research

Volumn 42, Issue 5, 2003, Pages 1076-1086

  Gimeno, Olga ^a   Plucinski, Pawel ^a   Kolaczkowski, Stan T ^a   Rivas, Francisco J ^b   Alvarez, Pedro M ^b  

^a University of Bath   (United Kingdom)

^b UNIVERSITY OF EXTREMADURA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; HERBICIDES; ISOTHERMS; MASS TRANSFER; OXIDATION;

ACTIVATED CARBON REGENERATION;

ACTIVATED CARBON;

2 (4 CHLORO 2 METHYLPHENOXY)ACETIC ACID; ACTIVATED CARBON; HERBICIDE;

ACTIVATED CARBON; ADSORPTION; EQUILIBRIUM; HERBICIDE; KINETIC THEORY; MASS TRANSFER; MODELING; TEMPERATURE EFFECT;

ADSORPTION; ADSORPTION KINETICS; ARTICLE; CALCULATION; EXPERIMENTAL MODEL; FUNCTIONAL ASSESSMENT; HEAT; ISOTHERM; OXIDATION; TEMPERATURE;

EID: 0037420142     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie020424x     Document Type: Article

References (38)

1. Philip, H. H. In Handbook of Environmental Fate and Exposure Data for Organic Chemicals; Michalenko, E. M., Jarvis, W. F., Basu, D. K., Sage, G. W., Meyland, W. M., Beauman, J. A., Gray, D. A., Eds.; Lewis Publishers Inc.: Chelsea, MI, 1991; Vol. III, Pesticides.
2. Walker, M.; Lawrence, H. EPA's Pesticide Fact Sheet Database; Lewis Publishers Inc.: Chelsea, MI, 1992.
3. Beltrán, F. J.; Garcia-Araya, J. F.; Acedo, B. Advanced oxidation of atrazine in water-I. Ozonation. Water Res. 1994, 28, 2153.
4. Meijers, R. T.; Oderwald, E. J.; Nuhn, P.; Kruithof, J. C. Degradation of pesticides by ozonation and advanced oxidation. Ozone: Sci. Eng. 1995, 17 (6), 673.
5. 2 oxidation of atrazine first degradation products: Deethylatrazine and deisopropylatrazine. Environ. Toxicol. Chem. 1996, 15 (6), 868.
6. Romero, E.; Dios, G.; Mingorance, M. D.; Matallo, M. B.; Pena, A.; Sanchez-Rasero, F. Photodegradation of mecoprop and dichlorprop on dry, moist and amended soil surfaces exposed to sunlight. Chemosphere 1998, 37 (3), 577.
7. Stangroom, S. J.; Macleod, C. L.; Lester, J. N. Photosensitized transformation of the herbicide 4-chloro-2-methylphenoxy acetic acid (MCPA) in water. Water Res. 1998, 32 (3), 623.
8. 2. J. Photochem. Photobiol. A: Chem. 2001, 140 (3), 249.
9. Lai, M. S.; Jensen, J. N.; Weber, A. S. Oxidation of simazine: ozone, ultraviolet, and combined ozone/ultraviolet oxidation. Water Environ. Res. 1995, 67, 340.
10. 3 in drinking water treatment. Int. J. Anal. Chem. 1995, 58, 247.
11. Pignatello, J. J.; Baehr, K. Ferric complexes as catalysts for Fenton degradation of 2,4-D and metolachlor in soil. J. Environ. Qual. 1994, 23 (2), 365.
12. Weber, J. B.; Coble, H. D. Microbial Decomposition of Diquat Adsorbed on Montmorillonite and Kaolinite Clays. J. Agric. Food Chem. 1968, 16, 475.
13. El-bid, M. A.; Aly, O. A. Removal of phenylamide pesticides from drinking waters. I. Effect of chemical coagulation and oxidants. Water Res. 1977, 11, 611.
14. Ioannis, K. K.; Triantafyllos, A. A.; Dimitrios, E. P.; Philip, J. P. Removal of herbicides from aqueous solutions by adsorption on Al-pillared clays, Fe-Al pillared clays and mesoporous alumina aluminium phosphates. Water Res. 2000, 34 (12), 3123.
15. Inacio, J.; Taviot-Gueho, C.; Forano, C.; Besse, J. P. Adsorption on MCPA pesticide by MgA1-layered double hydroxides. Appl. Clay Sci. 2001, 18, 255.
16. Albanis, T. A.; Danis, T. G.; Kourgia, M. G. Adsorptiondesorption studies of selected chlorophenols and herbicides and metal released in soil mixtures with fly ash. Environ. Technol. 1998, 19, 25.
17. Jian-Ying, H.; Takako, A.; Yutaka, O.; Takeshi, M.; Yasumoto, M. Adsorptive characteristics of ionogenic aromatic pesticides in water on powdered activated carbon. Water Res. 1998, 32 (9), 2593.
18. Heijman, S. G. J.; Hopman, R. Activated carbon filtration in drinking water production: Model prediction and new concepts. Colloids Surf. A 1999, 151, 303-310.
19. Baup, S.; Jaffre, C.; Wolbert, D.; Laplanche, A. Adsorption of Pesticides onto Granular Activated Carbon: Determination of Surface Diffusivities Using Simple Batch Experiments. Adsorption 2000, 6, 219.
20. Streat, M.; Horner, D. J. Adsorption of highly soluble herbicides from water using activated carbon and hypercrosslinked polymers. Trans Inst. Chem. Eng. B 2000, 78, 363.
21. Sotelo, J. L.; Ovejero, G.; Delgado, J. A.; Martinez, I. Comparison of adsorption equilibrium and kinetics of four chlorinated organics from water onto GAC. Water Res. 2002, 36, 599.
22. Shende R. V.; Mahajani V. V. Wet oxidative regeneration of activated carbon loaded with reactive dye. Waste Manage. 2002, 22, 73.
23. Brunauer, S.; Deming, L. S.; Deming, W. S.; Teller, E. On a theory of the van der Waals adsorption of gases. J. Am. Chem. Soc. 1940, 62, 1723.
24. Giles, C.; MacEwan, T.; Nakhwa, S.; Smith, D. Studies in adsorption. Part IV. A system of classification of solution isotherms and its use in diagnosis of adsorption mechanisms and in measurement of specific surface areas of solids. J. Chem. Soc. 1960, 3, 3973.
25. Karanfil, T.; Kilduff, J. E. Role of Granular Activated Carbon Surface Chemistry on the Adsorption of Organic Compounds. 1. Priority Pollutants. Environ. Sci. Technol. 1999, 33, 3217.
26. Faust, S. D.; Aly, O. M. Adsorption Processes for Water Treatment; Butterworth Publishers: Stoneham, MA, 1987.
27. Espínola, A. Equilibrio y cinética de adsorción sobre carbón activado de tres pesticidas en disolución acuosa. Ph.D. Dissertation, Universidad Complutense, Madrid, Spain, 1998.
28. Jaroniec, M.; Lu, X.; Madey, R.; Choma, J. Comparative studies of the overall adsorption isotherm associated with Dubinin-Asthakov equation. Carbon 1990, 28, 243.
29. Jaroniec, M.; Madey, R. Physical Adsorption on Heterogeneous Solids; Elsevier: New York, 1988.
30. Sabio, E.; Gonzalez-Martin, M. L.; Ramiro, A.; Gonzalez, J. F.; Bruque, J. M.; Labajos-Broncano, L.; Encinar, J. M. Influence of the regeneration temperature on the phenols adsorption on activated carbon. J. Colloid Interface Sci. 2001, 242, 31.
31. Adamson, A. W. Physical Chemistry of Surface 5th ed., John Wiley & Sons: New York, 1990.
32. Parfitt, G. D.; Rochester, C. H. Adsorption from Solution at the Solid/Liquid Interface; Academic Press: New York, 1983.
33. Jaroniec, M.; Madey R. Physical Adsorption on Heterogeneous Solids; Elsevier: New York, 1988.
34. Mattson, J. S.; Mark, H. B., Jr.; Malbin, M. D.; Weber, W. J.; Crittenden, J. C. Surface chemistry of active carbon: specific adsorption of phenols. J. Colloid Interface Sci. 1969, 31, 116.
35. Khraisheh, M.; Al-Degs, Y.; Allen, S.; Ahmad, M. Elucidation of controlling steps of reactive dye adsorption on activated carbon. Ind. Eng. Chem. Res. 2002, 41, 1651.
36. McGuire, M. J.; Suffet, I. H. Adsorption of organics from domestic water supplies. J. Am. Water Works Assoc. 1978, 70 (11), 621.
37. Chen, B.; Hui, C.; McKay, G. Film-pore diffusion modeling for the sorption of metals ions from aqueous effluents onto peat. Water Res. 2001, 35, 3345.
38. Spahn, H.; Schlunder, E. The scale up of activated carbon columns for water purification I. Based on results from batch tests. Chem. Eng. Sci. 1975, 30, 529.