Kinetic studies on the first dihydrogen aquacomplex, [Ru(H 2)(H2O)5]2+: Formation under H 2 pressure and catalytic H/D isotope exchange in water

Inorganica Chimica Acta

Volumn 359, Issue 6, 2006, Pages 1795-1806

  Grundler, Pascal V ^a   Yazyev, Oleg V ^a   Aebischer, Nicolas ^a   Helm, Lothar ^a   Laurenczy, Gábor ^a   Merbach, André E ^a  

^a INSTITUTE OF CHEMICAL SCIENCES AND ENGINEERING   (Switzerland)

Author keywords

Complex formation reactions; DFT; Dihydrogen complex; H D isotope exchange; NMR under pressure; Ruthenium aquacomplex

Indexed keywords

EQUILIBRIUM CONSTANTS; HYDROGEN; ISOTOPES; KINETIC THEORY; LIGANDS; RATE CONSTANTS; REACTION INTERMEDIATES; ULTRAVIOLET VISIBLE SPECTROSCOPY;

COMPLEX FORMATION REACTIONS; COMPLEX FORMATIONS; DEUTERATED WATER; DIHYDROGEN COMPLEXES; HYDROGEN EXCHANGE; ISOTOPE EXCHANGE; ISOTOPE LABELING; UV-VIS SPECTROSCOPY;

RUTHENIUM COMPOUNDS;

EID: 33644905548     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2005.06.056     Document Type: Article

References (62)

1. B. Cornils W.A. Herrmann Applied Homogeneous Catalysis with Organometallic Compounds vols. 1-2 1996 VCH Weinheim
2. I.T. Horváth F. Joó Aqueous Organometallic Chemistry and Catalysis NATO ASI Series 3 1995 Kluwer Academic Publishers Dordrecht
3. F. Joó Aqueous Organometallic Catalysis 2001 Kluwer Academic Publishers Dordrecht
4. P.A. Grieco Organic Synthesis in Water 1998 Blackie London
5. B. Cornils W.A. Herrmann Aqueous Phase Organometallic Catalysis second ed. 2004 Wiley-VCH Weinheim
6. P.V. Grundler, G. Laurenczy, and A.E. Merbach Helv. Chim. Acta 84 2001 2854
7. O. Lentzen, C. Moucheron, and A. Kirsch-De Mesmaeker M. Gielen E.R.T. Tiekink Perspectives of Ruthenium Complexes in Cancer Therapy in Metallotherapeutic Drugs and Metal-Based Diagnostic Agents: The Use of Metals in Medicine 2005 Wiley Chichester
8. C.S. Allardyce, P.J. Dyson, D.J. Ellis, and S.L. Heath Chem. Commun. 2001 1396
9. C.S. Allardyce, P.J. Dyson, D.J. Ellis, P.A. Salter, and R. Scopelliti J. Organomet. Chem. 668 2003 35
10. N. Aebischer, E. Sidorenkova, M. Ravera, G. Laurenczy, D. Osella, J. Weber, and A.E. Merbach Inorg. Chem. 36 1997 6009
11. U. Kölle Coord. Chem. Rev. 134/135 1994 623
12. R.H. Grubbs, and D.M. Lynn Alkene metathesis B. Cornils W.A. Herrmann Aqueous-Phase Organometallic Catalysis second ed. 2004 Wiley-VCH Weinheim
13. G. Laurenczy, and A.E. Merbach J. Chem. Soc., Chem. Commun. 1993 187
14. G. Laurenczy, L. Helm, A. Ludi, and A.E. Merbach Helv. Chim. Acta 74 1991 1236
15. G. Laurenczy, L. Helm, A. Ludi, and A.E. Merbach Inorg. Chim. Acta 189 1991 131
16. N. Aebischer, U. Frey, and A.E. Merbach Chem. Commun. 1998 2303
17. R.R. Schrock, and J.A. Osborn Chem. Commun. 1970 567
18. R.R. Schrock, and J.A. Osborn J. Am. Chem. Soc. 98 1976 2134
19. G.J. Kubas, C.J. Burns, G.R.K. Khalsa, L.S. van der Sluys, G. Kiss, and C.D. Hoff Organometallics 11 1992 3390
20. W.C. Chan, C.P. Lau, L. Cheng, and Y.S. Leung J. Organomet. Chem. 464 1994 103
21. P. Bernhard, H.-B. Bürgi, J.M. Hauser, H. Lehmann, and A. Ludi Inorg. Chem. 21 1982 3936
22. A. Cusanelli, U. Frey, D.T. Richens, and A.E. Merbach J. Am. Chem. Soc. 118 1996 5265
23. A. Cusanelli, U. Frey, D. Marek, and A.E. Merbach Spectrosc. Eur. 9 1997 22
24. U. Frey, L. Helm, A.E. Merbach, R. Roulet, M. Gielen, R. Willem, Wrackmeyer, B. (Eds.), High Pressure NMR in Organometallic Chemistry in Advanced Applications of NMR to Organometallic Chemistry.
25. L. Helm, and A. Borel NMRICMA 2.03 1998 Lausanne University Lausanne, Switzerland
26. H. Günther NMR Spectroscopy: Basic Principles, Concepts and Applications in Chemistry second ed. 1995 Wiley New York pp. 235-236
27. Scientist 2.0, MicroMath, Inc., Salt Lake City, UT, 1995.
28. G. te Velde, F.M. Bickelhaupt, S.J.A. van Gisbergen, C. Fonseca Guerra, E.J. Baerends, J.G. Snijders, and T. Ziegler J. Comput. Chem. 22 2001 931
29. C. Fonseca Guerra, J.G. Snijders, G. te Velde, and E.J. Baerends Theor. Chem. Acc. 99 1998 391
30. ADF2004.01, SCM, Theoretical Chemistry, Vrije Universiteit, Amsterdam, The Netherlands. Available from: 〈 http://www.scm.com〉.
31. S.H. Vosko, L. Wilk, and M. Nusair Can. J. Phys. 58 1980 1200
32. A.D. Becke Phys. Rev. A 38 1988 3098
33. J.P. Perdew Phys. Rev. B 36 1986 8822
34. S.F. Boys, and F. Bernardi Mol. Phys. 19 1970 553
35. P.A. Maltby, M. Schlaf, M. Steinbeck, A.J. Lough, R.H. Morris, W.T. Klooster, T.F. Koetzle, and R.C. Srivastava J. Am. Chem. Soc. 118 1996 5396
36. R.H. Crabtree Acc. Chem. Res. 23 1990 95
37. H. Günther NMR Spectroscopy: Basic Principles, Concepts and Applications in Chemistry second ed. 1995 Wiley New York pp. 228-231
38. K.A. Earl, G. Jia, P.A. Maltby, and R.H. Morris J. Am. Chem. Soc. 113 1991 3027
39. C.L. Young IUPAC Solubility Data Series Hydrogen and Deuterium vol. 5/6 1981 Pergamon Press Oxford 306
40. N. Aebischer, G. Laurenczy, A. Ludi, and A.E. Merbach Inorg. Chem. 32 1993 2810
41. N. Aebischer, R. Churlaud, L. Dolci, U. Frey, and A.E. Merbach Inorg. Chem. 37 1998 5915
42. R.H. Crabtree The Organometallic Chemistry of the Transition Metals 1994 Wiley New York pp. 19-20
43. M.S. Chinn, and D.M. Heinekey J. Am. Chem. Soc. 109 1987 5865
44. T.P. Fong, A.J. Lough, R.H. Morris, A. Mezzetti, E. Rocchini, and P. Rigo J. Chem. Soc., Dalton Trans. 1998 2111
45. M.S. Chinn, D.M. Heinekey, N.G. Payne, and C.D. Sofield Organometallics 8 1989 1824
46. W.J.C Orr, and J.A.V. Butler J. Chem. Soc. 1937 330
47. L. Helm, and A.E. Merbach Chem. Rev. 105 2005 1923
48. G.J. Kubas Metal Dihydrogen and σ-Bond Complexes 2001 Kluwer Academic Publishers New York (Chapters 7 and 9)
49. N. Aebischer, and A.E. Merbach Inorg. React. Mech. 1 1999 233
50. C. Creutz, and H. Taube Inorg. Chem. 10 1971 2664
51. G.J. Kubas J. Organomet. Chem. 635 2001 37
52. T. Funaioli, C. Cavazza, F. Marchetti, and G. Fachinetti Inorg. Chem. 38 1999 3361
53. G. Kovacs, L. Nadasdi, G. Laurenczy, and F. Joo Green Chem. 5 2003 213
54. J.D. Gilbertson, N.K. Szymczak, and D.R. Tyler Inorg. Chem. 43 2004 3341
55. N.V. Belkova, A.V. Ionidis, L.M. Epstein, E.S. Shubina, S. Gruendenmann, N.S. Golubev, and H.-H. Limbach Eur. J. Inorg. Chem. 2001 1753
56. V.I. Bakhmutov, E.V. Bakhmutova, N.V. Belkova, C. Bianchini, L.M. Epstein, D. Masi, M. Peruzzini, E.S. Shubina, E.V. Voronstov, and F. Zanobini Can. J. Chem. 79 2001 479
57. M.G. Basallote, J. Duran, M.J. Fernandez-Trujillo, M.A. Manez, and J. Rodriguez de la Torre J. Chem. Soc. Dalton Trans. 1998 745
58. M.G. Basallote, J. Duran, M.J. Fernandez-Trujillo, and M.A. Manez J. Organomet. Chem. 609 2000 745
59. D. Marx, M.E. Tuckerman, J. Hutter, and M. Parrinello Nature 379 1999 601
60. R.G. Schmidt, and J. Brickmann Solid State Ionics 77 1995 3
61. M. Eigen Angew. Chem. 75 1963 489
62. E. Pines, B.-Z. Magnes, M.L. Lang, and G.R. Fleming Chem. Phys. Lett. 281 1997 413