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Volumn 16, Issue 3, 2005, Pages 429-454

Synthesis and stereochemical/electrochemical analyses of cuboctahedral-based Pd(23)(CO)x(PR3)(10) clusters (x = 20 with R3 = Bu(3)n, Me 2Ph; x = 20, 21, 22 with R(3) = Et3): Geometrically analogous Pd23(PEt3)10 fragments with variable carbonyl ligations and resulting implications

Author keywords

Electrochemical analyses; Palladium clusters; Stereochemical; Variable ligation; X ray crystallographic

Indexed keywords


EID: 33644636582     PISSN: 10407278     EISSN: 15728862     Source Type: Journal    
DOI: 10.1007/s10876-005-0003-3     Document Type: Article
Times cited : (17)

References (62)
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    • note
    • 6 face in 2. The nonbonding separations between the C(1)O(1) and C(2)O(2) ligands are 2.91 Åfor C(1)...C(2) and 2.74 Å for O(1)...O(2) in 2 and 2.89 Å for C(1)...C(2) and 2.71 Å for O(1)...O(2) in 3.
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    • D. F. Shriver, H. D. Kaesz, and R. D. Adams, (eds.) VCH Publishers, New York, Chap. 2
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    • Mingos, D.M.P.1    May, A.P.2
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    • note
    • (a) This reversibility is remarkable and was observed during more than 20 full cycles without any signs of decomposition of 10 and its electrochemically generated derivatives;
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    • note
    • 3) [16c].


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