Structure and reactivity of an unusual rhodium(I) bis(ethylene) complex, RhCl(CH2=CH2)2(PMe3)2

Organometallics

Volumn 23, Issue 15, 2004, Pages 3756-3758

  Choi, Jun Chul ^a   Sakakura, Toshiyasu ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; CATALYSIS; CHEMICAL BONDS; DEHYDROGENATION; ETHYLENE; HYDROGEN; LOW TEMPERATURE EFFECTS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; STOICHIOMETRY; X RAY CRYSTALLOGRAPHY;

PERCURSORS; REACTIVITY; TRANSIENT FORMATION; WEAK COORDINATING LIGANDS;

RHODIUM COMPOUNDS;

EID: 3342996951     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0400144     Document Type: Article

References (22)

1. (a) Spillett, C. T.; Ford, P. C. J. Am. Chem. Soc. 1989, 111, 1932-1933,
2. (b) Bridgewater, J. S.; Netzel, T. L.; Sohoonover, J. E.; Massiok, S. M.; Ford, P. C. Inorg. Chem, 2001, 40, 1466-1476.
3. (c) Ford, P. C.; Netzel, T. L.; Spillett, C. T.; Fourreau, D. B. Pure Appl. Chem. 1990, 62, 1091-1094.
4. (a) Sakakura, T.; Sodeyama, T.; Tanaka, M. New. J. Chem. 1989, 13, 737-746.
5. (b) Sakakura, T.; Abe, F.; Tanaka, M. Chem. Lett. 1991, 297-298.
6. (c) Tanaka, M.; Sakakura, T. Adv. Chem. Ser. 1992, 230, 181-196.
7. (d) Sakakura, T.; Sodeyama, T.; Sasaki, K.; Wada, K.; Tanaka, M. J. Am. Chem. Soc. 1990, 112, 7221-7229.
8. (a) Maguire, J. A.; Boese, W. T.; Goldman, M. E.; Goldman, A. S. Coord. Chem. Rev. 1990, 97, 179-192.
9. (b) Maguire, J. A.; Boese, W. T.; Goldman, A. S. J. Am. Chem. Soc. 1989, 111, 7088-7093.
10. (c) Boyd, S. E.; Field, L. D.; Partridge, M. G. J. Am. Chem. Soc. 1994, 116, 9492-9497.
11. (d) Rosini, G. P.; Boese, W. T.; Goldman, A. S. J. Am. Chem. Soc. 1994, 116, 9498-9505.
12. (e) Margl, P.; Ziegler, T.; Blöohl, P. E. J. Am. Chem. Soc. 1996, 118, 5412-5419.
13. Hutschka, F.; Dedieu, A.; Eichberger, M.; Fornika, R.; Leitner, W. J. Am. Chem. Soc. 1997, 119, 4432-4443.
14. (a) Choi, J.-C.; Sakakura, T., J. Am. Chem. Soc. 2003, 125, 7762-7763.
15. See also: (b) Choi, J.-C.; Kobayashi, Y.; Sakakura, T. J. Org. Chem. 2001, 66, 5262-5263. Bitterwolf, T. E.; Kline, D. L.; Linehan, J. C.; Yonker, C. R.; Addleman, R. S. Angew. Chem., Int. Ed. 2001, 40, 2692-2694.
16. See also: (b) Choi, J.-C.; Kobayashi, Y.; Sakakura, T. J. Org. Chem. 2001, 66, 5262-5263. Bitterwolf, T. E.; Kline, D. L.; Linehan, J. C.; Yonker, C. R.; Addleman, R. S. Angew. Chem., Int. Ed. 2001, 40, 2692-2694.
17. A similar iridium complex was reported by Milstein. Aizenberg, M.; Milstein, D.; Tulip, T. H. Organometallics 1898, 15, 4093-4095.
18. 2 are well characterized including X-ray structure; see: Busetto, C.; D'Alfonso, A.; Maspero, F.; Perego, G.; Zazzetta, A. J. Chem, Soc., Dalton Trans. 1977, 1828-1834.
19. Hughea, R. P. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: London, 1982; Vol. 5; pp 296-307.
20. Ryan, R. R.; Schaeffer, R.; Clark, P.; Hartwell, G. Inorg. Chem. 1973, 14, 3039-3042.
21. Aresta, M.; Nobile, F. Inorg. Chim. Acta 1977, 24, L49-L50.
22. Gibaon, D. H. Chem. Rev. 1996, 96, 2063-2095.