Reactions of distibines Sb2R4 and dibismuthine Bi2Et4 with trialkyltrieles MR3

Organometallics

Volumn 23, Issue 15, 2004, Pages 3615-3621

  Kuczkowski, A ^a   Fahrenholz, S ^a   Schulz, S ^a   Nieger, M ^a  

^a UNIVERSITY OF BONN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; DECOMPOSITION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RESONANCE; SINGLE CRYSTALS; SUBSTITUTION REACTIONS; X RAY DIFFRACTION ANALYSIS;

ADDUCTS; HETEROCYCLES; LIGANDS; MASS SPECTROSCOPY;

ORGANOMETALLICS;

EID: 3342993553     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om049746m     Document Type: Article

References (52)

1. 3 was reported by Gay-Lussac almost 200 years ago (Gay-Lussac, J. L.; Thenard, J. L. Mem. Phys. Chim. Soc. d'Arcueil 1809, 2, 210. Cited in: Jonas, V.; Frenking, G. Chem. Commun. 1984, 1489).
2. 3 was reported by Gay-Lussac almost 200 years ago (Gay-Lussac, J. L.; Thenard, J. L. Mem. Phys. Chim. Soc. d'Arcueil 1809, 2, 210. Cited in: Jonas, V.; Frenking, G. Chem. Commun. 1984, 1489).
3. For a recent review see: Breunig, H. J. Adv. Organomet. Chem. 2003, 49, 95.
4. (a) Bailey, N. A.; Frisch, P. D.; McCleverty, J. A.; Walker, N. W. J.; Williams, J. J. Chem. Soc., Chem. Commun. 1975, 350.
5. (b) Bultitude, J.; Larkworthy, L. F.; Povey, D. C.; Smith, G. W.; Dilworth, J. R.; Leigh, G. J. J. Chem. Soc., Chem. Commun. 1986, 1748.
6. (c) Vogel, S.; Barth, A.; Huttner, G.; Klein, T.; Zsolnai, L.; Kremer, R. Angew. Chem., Int. Ed. Engl. 1991, 30, 303.
7. (d) Schrock, R. R.; Glassman, T. E.; Vale, M. G.; Kol, M. J. Am. Chem. Soc. 1993, 115, 1760.
8. (e) Sharma, P.; Rosas, N.; Hernandez, S.; Cabrera, A. J. Chem. Soc., Chem. Commun. 1995, 1325.
9. (a) Nöth, H. Z. Naturforsch., B 1960, 15, 327.
10. (b) Burg, A. B.; Wagner, R. I. J. Am. Chem. Soc. 1953, 75, 3872.
11. (c) Burg, A. B.; Brendel, J. J. Am. Chem. Soc. 1958, 80, 3198.
12. (d) Burg, A. B. J. Am. Chem. Soc. 1961, 83, 2226.
13. (e) Carrell, H. L.; Donohue, J. Acta Crystallogr., Sect. B 1968, 24, 699.
14. (f) Schmidbaur, H.; Wimmer, T.; Grohmann, A.; Steigelmann, O.; Müller, G. Chem. Ber. 1989, 122, 1607.
15. Kuczkowski, A.; Schulz, S.; Nieger, M.; Saarenketo, P. Organometallics 2001, 20, 2000.
16. Kuczkowski, A.; Schulz, S.; Nieger, M. Angew. Chem., Int. Ed. 2001, 40, 4222.
17. Breunig, H. J.; Stanciu, M.; Rösler, R.; Lork, E. Z. Anorg. Allg. Chem. 1998, 624, 1965.
18. Samaan, S. In Houben Weyl: Methoden der Organischen Chemie, 4th ed.; Thieme Verlag: Stuttgart, Germany, 1978; Metallorganische Verbindungen des Arsens, Antimons und Bismuts.
19. Breunig, H. J.; Fichtner, W. Z. Anorg. Allg. Chem. 1981, 477, 119.
20. (a) Cowley, A. H.; Jones, R. A.; Nunn, C. M.; Westmoreland, D. L. Chem. Mater. 1990, 2, 221.
21. (b) Park, H. S.; Schulz, S.; Wessel, H.; Roesky, H. W. Chem. Vap. Deposition 1999, 5, 179.
22. Lehmkuhl, H.; Olbrysch, O.; Nehl, H. Liebigs Ann. Chem. 1973, 708.
23. Coates, G. E.; Wade, K. In Organometallic Compounds, The Main Group Elements; Methuen: London, 1967.
24. Reier, F. W.; Wolfram, P.; Schumann, H. J. Cryst. Growth 1988, 93, 41.
25. Breunig, H. J.; Breunig-Lyriti, V.; Knobloch, T. P. Chem. Z. 1977, 101, 399.
26. Meinema, H. A.; Martens, H. F.; Noltes, J. G. J. Organomet. Chem. 1973, 51, 223.
27. Breunig, H. J.; Kanig, W. J. Organomet. Chem. 1980, 186, C5.
28. Breunig, H. J., Müller, D. Angew. Chem., Int. Ed. Engl. 1982, 21, 439.
29. Sheldrick, G. M. SHELXS-97, Program for Structure Solution. Acta Crystallogr., Sect. A 1990, 46, 467.
30. Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement; Universität Göttingen, Göttingen, Germany, 1997.
31. Ashe, A. J., III; Ludwig, E. G., Jr.; Oleksyszyn, J.; Huffman, J. C. Organometallics 1884, 3, 337.
32. Mundt, O.; Riffel, H.; Becker, G.; Simon, A. Z. Naturforsch., B 1984, 39, 317.
33. Becker, G.; Freudenblum, H.; Witthauer, C. Z. Anorg. Allg. Chem. 1982, 492, 37.
34. Becker, G.; Meiser, M.; Mundt, O.; Weidlein, J. Z. Anorg. Allg. Chem. 1989, 569, 62.
35. Mundt, O.; Becker, G.; Wessely, H.-J.; Breunig, H. J.; Kischkel, H. Z. Anorg. Allg. Chem. 1982, 486, 70.
36. See the following and references therein: (a) Schulz, S.; Kuczkowski, A.; Nieger, M. J. Organomet. Chem. 2000, 604, 202.
37. (b) Schulz, S.; Nieger, M. J. Chem. Soc., Dalton Trans. 2000, 639.
38. 4 has not been determined, to date, allowing no structural comparisons between the sum of the bond angles of the uncomplexed distibine and 1.
39. 2SbMe (R = Me, Et, i-Pr) formed according to the reaction mechanism.
40. For a detailed structural comparison of M-Sb heterocycles see: Thomas, F.; Schulz, S.; Nieger, M. Z. Anorg. Allg. Chem. 2002, 625, 235.
41. Schulz, S.; Nieger, M. J. Organomet. Chem. 1908, 570, 275.
42. Cowley, A. H.; Jones, R. A.; Kidd, K. B.; Nunn, C. M.; Westmorland, D. L. J. Organomet. Chem. 1988, 341, C1.
43. Foos, E. E.; Jouet, R. J.; Wells, R. L.; White, P. S. J. Organomet. Chem. 2000, 598, 182.
44. Foos, E. E.; Wells, R. L.; Rheingold, A. L. J. Cluster Sci. 1999, 10, 121.
45. Schulz, S.; Nieger, M. Angew. Chem., Int. Ed. Engl. 1900, 38, 967.
46. Thomas, F.; Schulz, S.; Nieger, M. Organometallics 2002, 21, 2793.
47. Thomas, F.; Schulz, S.; Mansikkamäki, H.; Nieger, M. Angew. Chem., Int. Ed. 2003, 42, 5641.
48. Holleman, A. F.; Wiberg, E. Lehrbuch der Anorganischen Chemie, 101st ed.; Walter de Gruyter: Berlin, 1995; p 1838 ff.
49. (a) Kuczkoweki, A.; Schulz, S.; Nieger, M. Eur. J. Inorg. Chem. 2001, 2605.
50. (b) Kuczkowski, A.; Thomas, F.; Schulz, S.; Nieger, M. Organometallics 2000, 19, 5758.
51. Wiberg, E.; Mödritzer, K. Z. Naturforsch., B 1957, 12, 132.
52. 3, 209 kJ/mol. McMillen, D. F.; Golden, D. M. Annu. Rev. Phys. Chem. 1982, 33, 493.