Uranocene. The first member of a new class of organometallic derivatives of the f elements

Organometallics

Volumn 23, Issue 15, 2004, Pages 3562-3583

  Seyferth, Dietmar ^a  

^a MASSACHUSETTS INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

LIGANDS; OGANOACTINIDE CHEMISTRY; RADIOCHEMICAL METHOD; REACTION MIXTURES;

BENZENE; CHEMICAL BONDS; CRYSTAL STRUCTURE; CRYSTALS; DERIVATIVES; EVAPORATION; MIXTURES; RARE EARTH ELEMENTS; SOLUTIONS; SUBLIMATION; SYNTHESIS (CHEMICAL);

ORGANOMETALLICS;

EID: 3342951134     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0400705     Document Type: Review

References (211)

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8. 3UCO is sufficiently stable to permit its isolation as a dark red-purple, crystalline solid whose X-ray crystal structure was determined at -123°C (Conejo, M. d. M.; Parry, J. S.; Carmona, E.; Schultz, M.; Brennan, J. G.; Beshouri, S. M.; Andersen, R. A.; Rogers, R. D.; Coles, S.; Hursthouse, M. Chem. Eur. J. 1999, 5, 3000).
9. 3UCO is sufficiently stable to permit its isolation as a dark red-purple, crystalline solid whose X-ray crystal structure was determined at -123°C (Conejo, M. d. M.; Parry, J. S.; Carmona, E.; Schultz, M.; Brennan, J. G.; Beshouri, S. M.; Andersen, R. A.; Rogers, R. D.; Coles, S.; Hursthouse, M. Chem. Eur. J. 1999, 5, 3000).
10. 3UCO is sufficiently stable to permit its isolation as a dark red-purple, crystalline solid whose X-ray crystal structure was determined at -123°C (Conejo, M. d. M.; Parry, J. S.; Carmona, E.; Schultz, M.; Brennan, J. G.; Beshouri, S. M.; Andersen, R. A.; Rogers, R. D.; Coles, S.; Hursthouse, M. Chem. Eur. J. 1999, 5, 3000).
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12. 3UCO is sufficiently stable to permit its isolation as a dark red-purple, crystalline solid whose X-ray crystal structure was determined at -123°C (Conejo, M. d. M.; Parry, J. S.; Carmona, E.; Schultz, M.; Brennan, J. G.; Beshouri, S. M.; Andersen, R. A.; Rogers, R. D.; Coles, S.; Hursthouse, M. Chem. Eur. J. 1999, 5, 3000).
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81. Ulrich Müller-Westerhoff, born 1937 in Düsseldorf, Germany. Initial chemistry studies at University of Marburg; Diplom (with G. N. Schrauzer) at Universität München, 1964; Ph.D., 1967 with K. Hafner, beginning in Universität München, continuing at University of Darmstadt. Postdoctoral studies (theory and synthesis) at University of California at Berkeley with A. Streitwieser, 1967-1968. On technical staff of IBM Research Laboratory in San Jose, 1968-1982. Professor of Chemistry at University of Connecticut, Storrs, CT since 1982.
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100. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
101. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
102. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
103. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
104. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
105. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
106. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
107. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
108. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
109. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
110. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
111. This has been a very active area, and a complete listing and discussion of the many papers dealing with the electronic structure of the actinocenes is beyond the scope of this essay. Some of these papers are cited below, but the list is not all-inclusive, (a) Rösch, N.; Streitwieser, A., Jr. J. Organomet. Chem. 1978, 145, 195. (b) Rösch, N.; Streitwieser, A., Jr. J. Am. Chem. Soc. 1983, 105, 7237. (c) Rösch, N. Inorg. Chim. Acta 1984, 94, 297, (d) Hayes, R. G.; Edelstein, N. J. Am. Chem. Soc. 1972, 94, 8688. (e) Warren, K. D. Struct. Bonding 1977, 33, 98. (f) Chang, A. H. H.; Pitzer, R. M. J. Am. Chem. Soc. 1989, 111, 2500. (g) Parry, J. A.; Cloke, F. G. N.; Coles, S. J.; Hursthouse, M. B. J. Am. Chem. Soc. 1999, 121, 6867. (h) Kaltsoyannis, N.; Bursten, B. E. J. Organomet. Chem. 1997, 528, 19. (i) Li, J.; Bursten, B. E. J. Am. Chem. Soc. 1998, 120, 11456. (j) Boerrigter, P. M.; Baerends, E. J.; Snijders, J. G. Chem. Phys. 1988, 122, 357. (k) Li, J.; Bursten, B. E. In Computational Organometallic Chemistry; Cundari, T. R., Ed.; Marcel Dekker: New York, 2001, Chapter 14, pp 345-379, and references therein. (l) Pepper, M.; Bursten, B. E. Chem. Rev. 1991, 91, 719 (a general review of the electronic structures of actinide-containing molecules).
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