Estimation of the enthalpy of formation of multialkane synthetic mixtures: Measurement by mixing calorimetry and modeling by the UNIQUAC model

Journal of Chemical and Engineering Data

Volumn 49, Issue 4, 2004, Pages 899-906

  Briard, Anne Julie ^a   Bouroukba, Mohammed ^a   Dirand, Michel ^a  

^a UNIVERSITÉ DE LORRAINE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

AMBIENT TEMPERATURES; ENERGY OF INTERACTIONS; ENTHLAPY OF FORMATION; WAXY DEPOSITS;

CALORIMETRY; CHROMATOGRAPHIC ANALYSIS; CRUDE PETROLEUM; DISSOLUTION; MATHEMATICAL MODELS; MIXTURES; MOLECULAR STRUCTURE; PARAFFINS; PHASE EQUILIBRIA; SOLUBILITY; SOLVENTS; X RAY DIFFRACTION ANALYSIS;

ENTHALPY;

EID: 3342907149     PISSN: 00219568     EISSN: None     Source Type: Journal    
DOI: 10.1021/je030244+     Document Type: Article

References (56)

1. Coutinho, J. A. P. Phase Equilibria in Petroleum Fluids, Multiphase Regions and Wax Formation. Ph.D. Thesis, Technical University of Denmark, Lingby, 1995.
2. Coutinho, J. A. P.; Stenby, E. H. Predictive Local Composition Models for Solid/Liquid Equilibrium in n-Alkanes Systems: Wilson Equation for Multicomponent Systems, Ind. Eng. Chem. Res. 1996, 35, 918-925.
3. Lira-Galeana, C.; Firoozabadi, A.; Prausnitz, J. M. Thermodynamics of Wax Precipitation in Petroleum Mixtures. AIChE J. 1996, 42, 239-247.
4. Coutinho, J. A. P. Predictive Local Composition Models: NRTL and UNIQUAC and Their Application to Model Solid-Liquid Equilibrium of n-Alkanes. Fluid Phase Equilib. 1999, 158, 447-457.
5. Hoerr, C. W.; Harwood, H. J. Solubilities of High Molecular Weight Aliphatic Compounds in n-Hexane. J. Org. Chem. 1951, 16, 779-791.
6. Dernini, S.; De Santis, R. Solubility of Solid Hexadecane and Tetracosane in Hexane. Can. J. Chem. Eng. 1976, 54, 369-370
7. Madsen, H. E. L.; Boistelle, R. Solubility of Long-Chain n-Paraffins in Pentane and Heptane. J. Cryst. Growth 1976, Paper 5/1466, 1078-1081.
8. Madsen, H. E. L.; Boistelle, R. Solubility of Octacosane and Hexatriacontane in Different n-Alkane Solvents. J. Chem. Soc., Faraday Trans. 1979, 75, 1254-1258.
9. Chang, S. S.; Maurey, J. R.; Pummer, W. J. Solubilities of Two n-Alkanes in Various Solvents. J. Chem. Eng. Data 1983, 28, 187-189.
10. Bosselet, F.; Létoffé, J. M.; Claudy, P.; Esson, S.; Valentin, P. Etude du Comportement Thermique des n-Alcanes dans des Milieux Hydrocarbonés Complexes par Analyse Calorimétrique Différentielle. I. Etude du Comportement Thermique des n-Alcanes en Programmation Linéaire de Température. Thermochim. Acta 1983, 70, 7-18.
11. Bosselet, F.; Létoffé, J. M.; Claudy, P.; Valentin, P. Etude du Comportement Thermique des n-Alcanes dans des Milieux Hydrocarbonés Complexes par Analyse Calorimétrique Différentielle. II. Détermination du Taux de n-Alcanes Contenu dans un Gazole. Détermination du Point de Trouble. Thermochim. Acta 1983, 70, 19-34.
12. Beiny, D. H. M.; Mullin, J. W. Solubilities of Higher Normal Alkanes in m-Xylene. J. Chem. Eng. Data 1987, 32, 9-10.
13. Domanska, U.; Hofman, T.; Rolinska, J. Solubility and Vapour Pressures in Saturated Solutions of High-Molecular-Weight Hydrocarbons. Fluid Phase Equilib. 1987, 32, 273-293.
14. Domanska, U.; Rolinska, J.; Szafranski, A. M. International Data Series Selected Data on Mixtures 1987, 4, 269-276.
15. Domanska, U. Solubility of n-paraffin hydrocarbons in binary solvent mixtures. Fluid Phase Equilib. 1987, 35, 217-237.
16. 58 in Pure Hydrocarbons. Fluid Phase Equilib. 1989, 45, 25-38.
17. 24) in Ethylbenzene. J. Chem. Thermodyn. 1989, 21, 925-934.
18. Ghogomu, P. M.; Dellacherie, J.; Balesdent, D. Impurity Effects on the Solubility of High Molecular Weight Normal Alkanes in Ethylbenzene. Thermochim. Acta 1990, 157, 241-257.
19. Domanska, U.; Kniaz, K. International Data Series Selected Data on Mixtures 1990, 3, 194-206.
20. Kniaz, K. Solubility of n-Docosane in n-Hexane and Cyclohexane. J. Chem. Eng. Data. 1991, 36, 471-472.
21. Brecevic, L.; Garside, J. Solubilities of Tetracosane in Hydrocarbon Solvents. J. Chem. Eng. Data 1993, 38, 598-601.
22. Ksiazczak, A.; Moorthi, K.; Nagata, I. Solid-Solid Transition and Solubility of Even n-Alkanes. Fluid Phase Equilib. 1994, 95, 15-29.
23. Roberts, K. L.; Rousseau, R. W.; Teja, A. S. Solubility of Long-Chain n-Alkanes in Heptane between 280 and 350 K. J. Chem. Eng. Data 1994, 39, 793-795.
24. Aoulmi, A.; Bouroukba, M.; Solimando, R.; Rogalski, M. Thermodynamics of Mixtures Formed by Polycyclic Aromatic Hydrocarbons with Long Chain Alkanes. Fluid Phase Equilib. 1995, 110, 283-297.
25. Ghogomu, P. M.; Schuffenecker, L.; Dellacherie, J.; Dirand, M.; Balesdent, D. Dissolution of Some Normal Alkanes in Ethylbenzene: Deduction of the Enthalpy of Mixing of Two n-Alkanes in the Solid State. Thermochim. Acta 1997, 294, 147-155.
26. Ghogomu, P. M.; Bouroukba, M.; Dellacherie, J.; Balesdent, D.; Dirand, M. Calorimetric Measurement of Mole Excess Enthalpies of Dilute Solutions of Ethylbenzene + Higher n-Alkanes. Thermochim. Acta 1997, 302, 159-164.
27. Ghogomu, P. M.; Bouroukba, M.; Dellacherie, J.; Balesdent, D.; Dirand, M. Excess Thermodynamic Properties of Some Binary Solutions of Ethylbenzene + n-Alkanes. Thermochim. Acta 1997, 302, 153-158.
28. Flöter, E.; Hollanders, B.; de Loos, T. W.; de Swaan Arons, J. The Ternary System (n-Heptane + Docosane + Tetracosane): The Solubility of Mixtures of Docosane and Tetracosane in Heptane and Data on Solid-Liquid and Solid-Solid Equilibria in the Binary Subsystem (Docosane + Tetracosane). J. Chem. Eng. Data 1997, 42, 562-565.
29. 28) in Heptane, Methylcyclohexane, and Toluene. J. Chem. Eng. Data 1998, 43, 745-749.
30. Mahmoud, R.; Solimando, R.; Bouroukba, M.; Rogalski, M. Solid-Liquid Equilibrium and Excess Enthalpy Measurements in Binary {Dibenzofuran or Xanthene + Normal Long-Chain Alkane} Systems. J. Chem. Eng. Data 2000, 45, 433-436.
31. Provost, E.; Chevallier, V.; Bouroukba, M.; Dirand, M.; Ruffier-Meray, V.; Behar, E. Experimental Determination and Representation of Binary and Ternary Diagrams of n-Hexacosane, n-Octacosane and n-Heptane. Revue de l'Institut Français du Pétrole 1998, 53, 27-33.
32. Bosselet, F.; Létoffé, J. M.; Claudy, P.; Esson, S.; Valentin, P. Etude du Comportement Thermique des n-Alcanes dans des Milieux Hydrocarbonés Complexes par Analyse Calorimétrique Différentielle. III. Etude en Programmation Discontinue de Température. Thermochim. Acta 1983, 70, 35-47.
33. Bosselet, F.; Létoffé, J. M.; Claudy, P.; Damin, B.; Maldonado, P. Etude du Comportement Thermique des n-Alcanes dans des Milieux Hydrocarbonés Complexes par Analyse Calorimétrique Différentielle. IV. Etude de L'action D'additifs Abaissant le Point de Trouble de Gazoles. Thermochim. Acta 1983, 70, 49-62.
34. Brady, T. J.; Wei-guo, S.; Williamson, A. G. Enthalpies of Mixing of Multicomponent Alkane Mixtures. Aust. J. Chem. 1988, 41, 1763-1767.
35. Daridon, J. L.; Xans, P.; Montel, F. Phase Boundary Measurement on a Methane + Decane + Multiparaffins System. Fluid Phase Equilib. 1996, 117, 241-248.
36. Pauly, J.; Dauphin, C.; Daridon, J. L. Liquid-Solid Equilibria in a Decane + Multi-Paraffin System. Fluid Phase Equilib. 1998, 149, 191-207.
37. Dauphin, C.; Daridon, J. L.; Coutinho, J. A. P.; Baylère, J.; Potin-Gautier, M. Wax Content Measurements in Partially Frozen Paraffinic Systems. Fluid Phase Equilib. 1999, 161, 135-151.
38. Chevallier, V.; Briard, A. J.; Bouroukba, M.; Petitjean, D.; Daridon, J. L.; Pauly, J.; Dirand, M. Solubility of an Industrial Multiparaffinic Wax in the Normal Tetradecane: Phase Diagram. Entropie 2001, 237, 38-42.
39. Ghogomu, P. M.; Bouroukba, M.; Dellacherie, J.; Balesdent, D.; Dirand, M. On the Ideality of Liquid Mixtures of Long-Chain n-Alkanes. Thermochim. Acta 1997, 306, 69-71.
40. Briard, A. J.; Bouroukba, M.; Petitjean, D.; Dirand, M. Variations of Dissolution Enthalpies of Pure n-Alkanes in Heptane as Function of Carbon Chain Length. J. Chem. Eng. Data 2003, 48, 1574-1577.
41. Dirand, M.; Bouroukba, M.; Chevallier, V.; Provost, E.; Petitjean, D. Multicomponent Paraffin Waxes and Petroleum Solid Deposits: Structural and Thermodynamic State. Fuel 1998, 77, 1253-1260.
42. Chevallier, V.; Provost, E.; Bourdet, J. B.; Bouroukba, M.; Petitjean, D.; Dirand, M. Mixtures of Numerous Different n-Alkanes - I. Structural Studies by X-ray Diffraction at Room Temperature - Correlation between the Crystallographic Long c Parameter and the Average Composition of Multi-Alkane Phases. Polymer 1999, 40, 2121-2128.
43. Chevallier, V.; Petitjean, D.; Bouroukba, M.; Dirand, M. Mixtures of Numerous Different n-Alkanes - II. Studies by X-ray Diffraction and Differential Thermal Analyses with Increasing Temperature. Polymer 1999, 40, 2129-2137.
44. Craig, S. R.; Hastie, G. P.; Roberts, K. J.; Gerson, A. R.; Sherwood, J. N.; Tack, R. D. Investigation into the Structures of Binary-, Tertiary- and Quaternary- Mixtures of n-Alkanes and Real Diesel Waxes Using High-Resolution Synchrotron X-ray Powder Diffraction. J. Mater. Chem. 1998, 4, 859-869.
45. Retief, J. J.; Le Roux, J. H. Crystallographic Investigation of a Paraffinic Fischer-Tropsch Wax in Relation to a Theory of Wax Structure and Behaviour. S. Afr. J. Sci. 1983, 79, 234-239.
46. Dirand, M.; Achour, Z.; Jouti, B.; Sabour, A. Binary Mixtures of n-Alkanes. Phase Diagram Generalization: Intermediate Solid Solutions, Rotator Phases. Mol. Cryst. Liq. Cryst. 1996, 275, 293-304.
47. Nouar, H.; Bouroukba, M.; Petitjean, D.; Dirand, M. Ternary Phase Diagram n-Docosane:n-Tricosane:n-Tetracosane Molecular Alloys at 293 K. Mol. Cryst. Liq. Cryst. 1998, 309, 273-282.
48. Nouar, H.; Petitjean, D.; Bouroukba, M.; Dirand, M. Isothermal Sections of Ternary Mixtures: n-Docosane + n-Tricosane + n-Tetracosane. Mol. Cryst. Liq. Cryst. 1999, 326, 381-394.
49. Chevallier, V.; Petiljean, D.; Ruffier-Meray, V.; Dirand, M. Correlations between the Crystalline Long c-Parameter and the Number of Carbon Atoms of Pure n-Alkanes. Polymer 1999, 40, 5953-5956.
50. Daridon, J. L.; Dauphin, C. Measurement of Pressure Effect on Wax Content in Partially Frozen Paraffinic Systems. Meas. Sci. Tech. 1999, 10, 1309-1314.
51. Abrams, D. S.; Prausnitz, J. M. Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems. AIChE J. 1975, 21, 116-127.
52. Wilson, G. M. Vapor-Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing. J. Am. Chem. Soc. 1964, 86, 127-130.
53. Larsen, B. L.; Rasmussen, P.; Fredenslund, A. A Modified UNIFAC Group-Contribution Model for Prediction of Phase Equilibria and Heats of Mixing. Ind. Eng. Chem. Res. 1987, 26, 2274-2286.
54. 30- J. Chem. Eng. Data 1997, 42, 190-197.
55. Queimada, A. J. N.; Dauphin, C.; Marrucho, I. S.; Coutinho, J. A. P. Low-Temperature Behaviour of Refined Products from DSC Measurements and Their Thermodynamical Modelling. Thermochim. Acta 2001, 372, 93-101.
56. Mirante, F. I. C.; Coutinho, J. A. P. Cloud Point Prediction of Fuels and Fuel Blends. Fluid Phase Eguilib. 2001, 180, 247-255.