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Volumn , Issue 4, 2006, Pages 1034-1042

Acceleration of thiol ester hydrolysis by cyclodextrins: Evidence from rate and computational studies

Author keywords

Computational studies; Cyclodextrins; Diaryl thiol esters; Hydrolysis; Rate acceleration

Indexed keywords


EID: 33144482602     PISSN: 1434193X     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejoc.200500770     Document Type: Article
Times cited : (9)

References (43)
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    • 33144470577 scopus 로고    scopus 로고
    • note
    • 1H-NMR chemical shifts exhibit upfield shift for H-3, H-5 protons of all thiol esters for example the chemical shift (in Hz) for uncomplexed β-CD H1 - 1462, H2 - 1014, H3 - 1105, H4 - 1033, H5 - 1096, H6 - 1125 and for β-CD (1) complex H1 - 1462, H2 - 1014, H3 - 1104, H4 - 1033, H5 - 1092, H6 - 1125 such change in chemical shift values are known to be the consequence of diamagnetic anisotropic effect of the aromatic ring residing inside the cavity and are considered to be evidence for the formation of inclusion complex in aqueous CD solution.
  • 43


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.