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85033140485
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Supporting Information
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Supporting Information.
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19
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0003467672
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March, J.1
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33846193529
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The small change in rate with buffer concentration might indicate general base catalysis of hydrolysis for the reaction in water. The same relative increase in rate with buffer concentration indicates that the reaction mediated by β-CD is not affected by buffer as it was found for other ester hydrolysis reactions. See Breslow, R.; Czarnniecki, M. F.; Emert, J.; Hamaguchi, H. J. Am.Chem. Soc 1980, 102, 762.
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Czarnniecki, M.F.2
Emert, J.3
Hamaguchi, H.4
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23
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85033154658
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Reference 16, p 378.
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Reference 16, p 378.
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24
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33845183356
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Ba-Saif, S.; Luthra, A. K.; Williams, A. J. Am. Chem. Soc. 1989, 111, 2647.
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Manion Schilling, M. L.; Roth, H. D.; Herndon, W. C. J. Am. Chem. Soc. 1980, 102, 4272.
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Roth, H.D.2
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85033154393
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note
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- and water reaction, respectively.
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30
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85033152480
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Unpublished results from our laboratory indicate that for a compound with a better leaving group as p-chlorophenol, there is significant general base catalysis
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Unpublished results from our laboratory indicate that for a compound with a better leaving group as p-chlorophenol, there is significant general base catalysis.
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32
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33947338055
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a of β-CD is 12.1 (see Van Etten, R. L.; Sebastian, J. F.; Clowes, G. A.; Bender, M. L. J. Am. Chem. Soc. 1967, 89, 3253).
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J. Am. Chem. Soc.
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Van Etten, R.L.1
Sebastian, J.F.2
Clowes, G.A.3
Bender, M.L.4
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37
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33846193529
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Breslow, R.; Czarniecki, F. M.; Emert, J.; Hamaguchi, H. J. Am. Chem. Soc. 1980, 102, 762.
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J. Am. Chem. Soc.
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Breslow, R.1
Czarniecki, F.M.2
Emert, J.3
Hamaguchi, H.4
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40
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85033135925
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Reference 5b
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Reference 5b.
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44
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0344897984
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Oxford University Press: London
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"Analytical Chemisty. The Working Tools"; Strouts, C. R. N., Gilgilan, J. H.; Wilson, H. N., Ed.; Oxford University Press: London, 1958; pp 228-233.
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Analytical Chemisty. the Working Tools
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Strouts, C.R.N.1
Gilgilan, J.H.2
Wilson, H.N.3
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45
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85033127417
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Cyclodextrins were a gift from the pharmaceutical company Ferromet S. A. Buenos Aires, Argentina
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Cyclodextrins were a gift from the pharmaceutical company Ferromet S. A. Buenos Aires, Argentina.
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