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32544456815
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note
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2), -0.12 (s, 3 H, ZrMe), -0.32 (s, 3 H, GaMe).
-
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-
-
35
-
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32544440662
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note
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22 All of the C-H hydrogen atoms except H(3A) were included in geometrically idealized positions and refined with the riding model. Localization of the H(3A) hydrogen from the electron density map in both structures proved to be more accurate than its fixing in the idealized position and led to lowering of the R1 and wR2 values. The hydrogen atom from the OH in 2 was localized from the difference electron density map and refined isotropically. (d) Compound 3 crystallizes as a pseudomerohedral twin emulating orthorhombic crystal system. The twin law was determined as - 1000 - 10001, and the ratio of the domains was refined as 0.33/0.67.
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36
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