Nitrogen heterocycles as building blocks for new metallo-supramolecular architectures

Molecules

Volumn 9, Issue 6, 2004, Pages 440-448

  Steel, Peter J ^a  

^a UNIVERSITY OF CANTERBURY   (New Zealand)

Author keywords

Bridging ligands; Chiral ligands; Cyclometallation; Heterocyclic ligands

Indexed keywords

HETEROCYCLIC COMPOUND; NITROGEN DERIVATIVE;

CHEMICAL REACTION; CHIRALITY; CONFERENCE PAPER; METALLATION; REACTION ANALYSIS; SYNTHESIS;

EID: 3242881233     PISSN: 14203049     EISSN: None     Source Type: Journal    
DOI: 10.3390/90600440     Document Type: Conference Paper

References (38)

1. Blau, F. Die destillation pyridinmonocarbonsaurer salze. Chem. Ber. 1888, 21, 1077-1078.
2. Constable, E. C. Homoleptic complexes of 2,2′-bipyridine. Adv. Inorg. Chem. 1989, 34, 1-63.
3. Constable, E. C.; Steel, P. J. N,N′-Chelating biheteroaromatic ligands; a survey. Coord. Chem. Rev. 1989, 93, 205-223.
4. Richardson, C.; Steel, P. J. Benzotriazole as a structural component in chelating and bridging heterocyclic ligands; ruthenium, palladium, copper and silver complexes. J. Chem. Soc., Dalton Trans. 2003, 992-1000.
5. Richardson, C.; Steel, P. J. Unpublished results, 2000.
6. Steel, P. J. Aromatic nitrogen heterocycles as bridging ligands; a survey. Coord. Chem. Rev. 1990, 106, 227-265.
7. Kaes, C.; Katz, A.; Hosseini, M. W. Bipyridine: the most widely used ligand. A review of molecules comprising at least two 2,2′-bipyridine units. Chem. Rev. 2000, 100, 3553-3590.
8. Gavrilova, A. L.; Bosnich, B. Principles of mononucleating and binucleating ligand design. Chem. Rev. 2004, 104, 349-383.
9. Balzani, V.; Juris, A.; Venturi, M.; Campagna, S.; Serroni, S. Luminescent and redox-active polynuclear transition metal complexes. Chem. Rev. 1996, 96, 759-833.
10. Phillips, I. G.; Steel, P. J. Mono- and bi-nuclear complexes of the doubly bidentate, bridging ligand 4,6-di(2-pyridyl)pyrimidine. Aust. J. Chem. 1998, 51, 371-382.
11. Phillips, I. G. Syntheses and complexes of heterocyclic ligands. Ph.D. Thesis, University of Canterbury, 1995.
12. Downard, A. J.; Honey, G. E.; Phillips, L. F.; Steel, P. J. Synthesis and properties of a tris(2,2′-bipyridine)ruthenium(II) dimer directly coupled at the C4 carbon. Inorg. Chem. 1991, 30, 2259-2260.
13. Constable, E. C. Cyclometallated complexes incorporating a heterocyclic donor atom; the interface of coordination chemistry and organometallic chemistry. Polyhedron 1984, 3, 1037-1057.
14. Steel, P. J.; Caygill, G. B. Cyclometallated compounds. II. Proton and carbon-13 nuclear magnetic resonance spectral assignments of cyclopalladated compounds. J. Organomet. Chem. 1987, 327, 101-114.
15. de Geest, D. J.; O'Keefe, B. J.; Steel, P. J. Cyclometallated compounds. XIII. Cyclopalladation of 2-phenoxypyridine and structurally-related compounds. J. Organomet. Chem. 1999, 579, 97-105.
16. Caygill, G. B.; Hartshorn, R. M.; Steel, P. J. Cyclometallated compounds. IV. Cyclopalladation of phenyl pyrimidines and X-ray structure of a doubly cyclopalladated derivative of 4,6-diphenylpyrimidine. J. Organomet. Chem. 1990, 382, 455-469.
17. de Geest, D. J.; Steel, P. J. Cyclometallated compounds. XII. Syntheses of two new doubly-cyclometallated compounds. Inorg. Chem. Commun. 1998, 1, 358-360.
18. O'Keefe, B. J.; Steel, P. J. Cyclometallated compounds. XV. A tetranuclear, acetate-bridged, cyclopalladated molecular box. Acta Crystallogr. 2000, C56, 1440-1441.
19. O'Keefe, B. J.; Steel, P. J. Cyclometallated compounds. XVI. Double cyclopalladations of bis(2-pyridyloxy)naphthalenes. Kinetic versus thermodynamic control over regioselectivity. Organometallics 2003, 22, 1281-1292.
20. Slater, J. W.; Lydon, D. P.; Rourke, J. P. Doubly cyclopalladated pyridazines: chiral liquid crystals. J. Organomet. Chem. 2002, 645, 246-255.
21. Sumby, C. J.; Steel, P. J. Cyclometallated compounds. XVII. The first three-fold cyclopalladation of a single benzene ring. Organometallics 2003, 22, 2358-2360.
22. Ghosh, A. K.; Mathivanan, P.; Cappiello, J. C2-symmetric chiral bis(oxazoline)-metal complexes in catalytic asymmetric synthesis. Tetrahedron: Asymmetry 1998, 9, 1-45.
23. Mamula, O.; von Zelewsky, A. Supramolecular coordination compounds with chiral pyridine and polypyridine ligands derived from terpenes. Coord. Chem. Rev. 2003, 242, 87-95.
24. 3Pd. Acta Crystallogr. 1983, C39, 1623-1625.
25. House, D. A.; Steel, P. J.; Watson, A. A. Chiral heterocyclic ligands. IV. Synthesis and metal complexes of 2,6-bis(pyrazol-1-ylmethyl)-pyridine and chiral derivatives. Inorg. Chim. Acta 1987, 130, 167-176.
26. Watson, A. A.; House, D. A.; Steel, P. J. Chiral heterocyclic ligands. VII. Syntheses of some chiral 2,6-bis(N-pyrazolyl)pyridines. J. Org. Chem. 1991, 56, 4072-4074.
27. Watson, A. A.; House, D. A.; Steel, P. J. Chiral heterocyclic ligands. VIII. Syntheses and complexes of new chelating ligands derived from camphor. Aust. J. Chem. 1995, 48, 1549-1572.
28. Downard, A. J.; Phillips, I. G.; Steel. P. J. Chiral heterocyclic ligands. X. Synthesis and metal complexes of hindered and chiral 2,2′-bipyrimidines. Aust. J. Chem. submitted for publication.
29. 2-symmetric, linear-bridging ligand. New J. Chem. 2000, 24, 945-947.
30. Hennrich, G.; Anslyn, E. V. 1,3,5-2,4,6-Functionalized, facially segregated benzenes - exploitation of sterically predisposed systems in supramolecular chemistry. Chem. Eur. J. 2002, 8, 2218-2224.
31. Hartshorn, C. M.; Steel, P. J. Self-assembly and X-ray structure of a ten-component, three-dimensional, metallosupramolecular cage. Chem. Commun. 1997, 541-542.
32. Hartshorn, C. M.; Steel, P. J. Colenterands: a new class of metal-encapsulating ligands. Angew. Chem., Int. Ed. Engl. 1996, 35, 2655-2657.
33. Hartshorn, C. M.; Steel, P. J. Bis(3-(2-pyridyl)pyrazol-1-ylmethyl) benzenes, doubly-chelating binucleating ligands and encapsulation of a linear trisilver(I) moiety. Inorg. Chem. Commun. 2000, 3, 476-481.
34. O'Keefe, B. J. Synthesis and complexes of heterocyclic ligands. Ph.D. Thesis, University of Canterbury, 1999.
35. Piguet, C.; Bernardinelli, G.; Hopfgartner, G. Helicates as versatile supramolecular complexes. Chem. Rev. 1997, 97, 2005-2062.
36. Albrecht, M. "Let's twist again"-double-stranded, triple-stranded, and circular helicates. Chem. Rev. 2001, 101, 3457-3497.
37. O'Keefe, B. J.; Steel, P. J. Self-assembly and X-ray structure of a triple helicate with two trigonal silver(I) termini. Inorg Chem. Commun. 2000, 3, 473-475.
38. McMorran, D. A.; Steel, P. J. The first coordinatively-saturated quadruply-stranded helicate and its encapsulation of a hexafluorophosphate anion. Angew. Chem., Int. Ed. 1998, 37, 3295-3297.