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Volumn 10, Issue 14, 2004, Pages 3486-3502

Spectral, structural, and electrochemical properties of ruthenium porphyrin diaryl and aryl(alkoxyrcarbonyl) carbene complexes: Influence of carbene substituents, porphyrin substituents, and trans-axial ligands

Author keywords

Carbene ligands; Electrochemistry; Macrocyclic ligands; Porphyrins; Ruthonium

Indexed keywords

CRYSTAL STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PORPHYRINS; RUTHENIUM COMPOUNDS; ULTRAVIOLET RADIATION;

EID: 3242878878     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200305758     Document Type: Article
Times cited : (60)

References (81)
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  • 34
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    • For previously reported osmium porphyrin carbene complexes, see: refs. [4,5a,d]; b) L. K. Woo, D. A. Smith, Organometallics 1992, 11, 2344;
    • (1992) Organometallics , vol.11 , pp. 2344
    • Woo, L.K.1    Smith, D.A.2
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    • 3042977115 scopus 로고
    • Electrochemical studies on metalloporphyrin carbene complexes are extremely rare. The only report on such studies appeared about 20 years ago and deals with iron porphyrin heteroatom-stabilized carbene and vinylcarbene complexes: J.-P. Battioni, D. Lexa, D. Mansuy, J.-M. Savéant, J. Am. Chem. Soc. 1983, 105, 207.
    • (1983) J. Am. Chem. Soc. , vol.105 , pp. 207
    • Battioni, J.-P.1    Lexa, D.2    Mansuy, D.3    Savéant, J.-M.4
  • 45
    • 3242890339 scopus 로고    scopus 로고
    • note
    • 2- = 5,10,15,20-tetrakis(3, 4,5-trimethoxyphenyl)porphyrinato. For simplicity, the 2- charge on these ligands are not shown in the text and in Table 6.
  • 53
    • 3242888526 scopus 로고    scopus 로고
    • note
    • 1H NMR spectrum in CDC13 shows no signals that are assignable to an axial trans ligand. Therefore, in solution, this complex should be a five-coordinate monomer.
  • 64
    • 61849138035 scopus 로고
    • For a review on electrochemical studies on metalloporphyrins, see a) K. M. Kadish, Prog. Inorg. Chem. 1986, 34, 435;
    • (1986) Prog. Inorg. Chem. , vol.34 , pp. 35
    • Kadish, K.M.1
  • 66
    • 0003641908 scopus 로고    scopus 로고
    • (Eds.: Kadish, K. M. Smith, K. M., R. Guilard), Academic Press, San Diego
    • c) K. M. Kadish, E. van Camelbecke, G. Royal in Porphyrin Handbook, Vol. 8 (Eds.: K. M. Kadish, K. M. Smith, R. Guilard), Academic Press, San Diego, 2000, pp. 1-114.
    • (2000) Royal in Porphyrin Handbook , vol.8 , pp. 1-114
    • Kadish, K.M.1    Van Camelbecke, E.2
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    • (Ed.: K. M. Smith), Elsevier, Amsterdam, Chapter 10
    • a) H. Scheer, J. J. Katz in Porphyrins and Metalloporphyrins (Ed.: K. M. Smith), Elsevier, Amsterdam, 1975, Chapter10, pp. 460-462;
    • (1975) Porphyrins and Metalloporphyrins , pp. 460-462
    • Scheer, H.1    Katz, J.J.2
  • 81
    • 0012974340 scopus 로고
    • c) D. P. Rillema, J. K. Nagle, L. F. Barringer, Jr., T. J. Meyer, J. Am. Chem. Soc. 1981, 103, 56. Note that the formulation [Ru-(por)(CO)] is just used for simplicity, since such complexes may contain oxygen-donor solvents or water in the axial sites (see ref. [23b]).
    • (1981) J. Am. Chem. Soc. , vol.103 , pp. 56
    • Rillema, D.P.1    Nagle, J.K.2    Barringer Jr., L.F.3    Meyer, T.J.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.