Controlled polymerization of methyl methacrylate and various functional acrylates by atom transfer radical polymerization

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

Volumn 38, Issue 1, 1997, Pages 456-457

  Matyjaszewski, Krzysztof ^a   Grimaud, Thomas ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DERIVATIVES; MOLECULAR WEIGHT; MONOMERS; POLYMERIZATION; REACTION KINETICS; SYNTHESIS (CHEMICAL);

ATOM TRANSFER RADICAL POLYMERIZATION (ATRP); FUNCTIONAL METHACRYLATE; METHYL METHACRYLATE; POLYDISPERSITIES;

POLYMETHYL METHACRYLATES;

EID: 3242834516     PISSN: 00323934     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Article

References (13)

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5. n < 30,000) under dry argon, or in sealed tubes under vacuum for higher molecular weights. Monomer were filtered through an alumina column, then dried over molecular sieves, degassed by argon bubbling and stored under argon. Diphenyl ether was dried over molecular sieves, degassed and stored in the same way. Copper bromide was purified with glacial acetic acid and washed with pure ethanol, then stored under argon. p-Toluenesulfonyl chloride was used as received. Reaction mixtures were degased three times by freeze-pump-thaw cycles before heating and adding initiator.
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