In situ speciation studies of copper-humic substances in a contaminated soil during electrokinetic remediation

Journal of Environmental Quality

Volumn 33, Issue 4, 2004, Pages 1280-1287

  Liu, S H ^a   Wang, H Paul ^a  

^a NATIONAL CHENG KUNG UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; CHELATION; CONTAMINATION; COPPER COMPOUNDS; ELECTRIC FIELDS; ELECTROLYTES; X RAY SPECTROSCOPY;

COPPER-HUMIC SUBSTANCES; EXTENDED X-RAY ABSORPTION FINE STRUCTURE (ESAFS) SPECTROSCOPY;

REMEDIATION;

CARBON MONOXIDE; COPPER; COPPER DERIVATIVE; HYDROGEN SULFIDE; OXIDE;

ARTICLE; BIOREMEDIATION; CHEMICAL BINDING; CHEMICAL STRUCTURE; COMPLEX FORMATION; ELECTROCHEMICAL ANALYSIS; ELECTROKINETIC REMEDIATION; ELECTROLYTE BALANCE; EXTENDED X RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY; HUMIC SUBSTANCE; LIGAND BINDING; METAL BINDING; NONHUMAN; SOIL POLLUTION; SPECIES DIFFERENTIATION; X RAY ANALYSIS; XANES SPECTROSCOPY;

EID: 3242781686     PISSN: 00472425     EISSN: None     Source Type: Journal    
DOI: 10.2134/jeq2004.1280     Document Type: Article

References (45)

1. Acar, Y.B., and A.N. Alshawabkeh. 1993. Principles of electrokinetic remediation. Environ. Sci. Technol. 27:2638-2647.
2. Acar, Y.B., and A.N. Alshawabkeh. 1996. Electrokinetic remediation: 1. Pilot-scale tests with Lead-spiked kaolinite. J. Geotech. Eng. 122: 173-185.
3. Acar, Y.B., J.T. Hamed, A.N. Alshawabkeh, and R.J. Gale. 1994. Cd(II) removal from saturated kaolinite by application of electrical current. Geotechnique 44:239-254.
4. Ankudinov, A.L., B. Ravel, J.J. Rehr, and S.D. Conradson. 1998. Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure. Phys. Rev. B 58:7565-7576.
5. Boyd, S.A., L.E. Sommers, and D.W. Nelson. 1981. Copper (II) and iron(III) complexation by the carboxylate group of humic acid. Soil Sci. Soc. Am. J. 45:1241-1242.
6. 4 with copper oxide. Environ. Sci. Technol. 35:3259-3262.
7. Chisholm-Brause, C.J., P.A.O. Day, G.E. Brown, Jr., and G.A. Parks. 1990. Evidence for multinuclear metal-ion complexes at solid water interfaces from X-ray absorption spectroscopy. Nature (London) 348:528-531.
8. Eykholt, G.R., and D.E. Daniel. 1994. Impact of system chemistry on electroosmosis in contaminated soil. J. Geotech. Eng. 120:797-815.
9. 2 catalysts by EXAFS, XANES and PCA. Mikrochim. Acta 109: 281-293.
10. 3-water interface. J. Colloid Interface Sci. 220:133-147.
11. 2+-binding sites in aquatic humic substances. Environ. Sci. Technol. 34:2138-2142.
12. Gee, G.W., and J.W. Bauder. 1986. Particle-size analysis. p. 399-404. In A. Klute (ed.) Methods of soil analysis. Part 1. 2nd ed. Physical and mineralogical methods. Agron. Monogr. 9. ASA and SSSA, Madison, WI.
13. Giller, K.E., E. Witter, and S.P. McGrath. 1998. Toxicity of heavy metals to microorganisms and microbial processes in agricultural soils: A review. Soil Biol. Biochem. 30:1389-1414.
14. Guthrie, E.A., J.M. Bortiatynski, J.D.H. Vanheemst, J.E. Richman, K.S. Hardy, E.M. Kovach, and P.G. Hatcher. 1999. Determination of [C-13]pyrene sequestration in sediment microcosms using flash pyrolysis GC-MS and C-13 NMR. Environ. Sci. Technol. 33:119-125.
15. Hamed, J., Y.B. Acar, and R.J. Gale. 1991. Pb(II) removal from kaolinite using electrokinetics. J. Geotech. Eng. 117:241-271.
16. Hicks, R.E., and S. Tondorf. 1994. Electrorestoration of metal contaminated soils. Environ. Sci. Technol. 28:2203-2210.
17. Ho, S.V., C.J. Athmer, P.W. Sheridan, and A.P. Shapiro. 1997. Scale-up aspects of the Lasagna™ process for in situ soil decontamination. J. Hazard. Mater. 55:39-60.
18. 4 effected by copper oxide clusters in the channels of ZSM-5. J. Phys. Chem. A 103:6514-6516.
19. Huang, Y.-J., H.P. Wang, and J.-F. Lee. 2003. Speciation of copper in ZSM-48 during NO reduction. Appl. Catal. B 40:111-118.
20. Huheey, J.E. 1978. Inorganic chemistry: Principles of structure and reactivity. Harper and Row, New York.
21. Iwamoto, M., T. Zengyo, A.M. Hernandez, and H. Araki. 1998. Intermediate addition of reductant between an oxidation and a reduction catalyst for highly selective reduction of NO in excess oxygen. Appl. Catal. B 17:259-266.
22. Khan, L.I., and M.S. Alam. 1994. Heavy metal removal from soil by coupled electric-hydraulic gradient. J. Environ. Eng. (Reston, VA) 120:1524-1543.
23. Korshin, G.V., A.I. Frenkel, and E.A. Stern. 1998. EXAFS study of the inner shell structure in copper(II) complexes with humic substances. Environ. Sci. Technol. 32:2699-2705.
24. Korshin, G.V., M.U. Kumke, C.W. Li, and F.H. Frimmel. 1999. Influence of chlorination on chromophores and fluorophores in humic substances. Environ. Sci. Technol. 33:1207-1212.
25. Lageman, R. 1993. Electroreclamation: Applications in the Netherlands. Environ. Sci. Technol. 27:2648-2650.
26. Lin, K.-S., and H.P. Wang. 1999. Shape selectivity of trace by-products for supercritical water oxidation of 2-chlorophenol effected by CuO/ZSM-48. Appl. Catal. B 22:261-267.
27. 2+ cations and copper oxide clusters. Environ. Sci. Technol. 34:4849-4854.
28. Liu, S.-H., H.P. Wang, H.-C. Wang, and Y.W. Yang. 2001. in-situ EXAFS study of copper in the electrokinetic remediation process. J. Synchrotron Radiat. 8:919-921.
29. Lu, X.Q., and W.D. Johnson. 1997. The reaction of aquatic humic substances with copper(II) ions: An ESR study of complexation. Sci. Total Environ. 203:199-207.
30. McIntyre, C., B.D. Batts, and D.R. Jardine. 1997. Electrospray mass spectrometry of groundwater organic acids. J. Mass Spectrom. 32: 328-330.
31. Mitchell, J.K. 1993. Fundamentals of soil behavior. 2nd ed. John Wiley & Sons, New York.
32. Nakamoto, K. 1978. Infrared and raman spectra of inorganic and coordination compounds. John Wiley & Sons, New York.
33. Paciolla, M.D., G. Davies, and S.A. Jansen. 1999. Generation of hydroxyl radicals from metal-loaded humic acids. Environ. Sci. Technol. 33:1814-1818.
34. Page, A.L. 1982. Methods of soil analysis. 2nd ed. SSSA, Madison, WI.
35. Palladino, L., S. Della Longa, A. Reale, M. Belli, A. Scafati, G. Onori, and A. Santucci. 1993. X-ray absorption near edge structure (XANES) of Cu(II)-ATP and related compounds in solution-Quantitative determination of the distortion of the Cu site. J. Chem. Phys. 98:2720-2726.
36. Pamukcu, S., and J.K. White. 1992. Electrokinetic removal of selected heavy metals from soils. Environ. Prog. 11:241-250.
37. Probstein, R.F., and R.E. Hicks. 1993. Removal of contaminants from soils by electric fields. Science (Washington, DC) 260:498-503.
38. Sah, J.G., and J.Y. Chen. 1998. Study of the electrokinetic process on Cd and Pb spiked soils. J. Hazard. Mater. 58:301-315.
39. Sarr, R.A., and J.H. Weber. 1980. Lead (II) complexation by fulvic acid: How it differs from fulvic acid complexation of copper (II) and cadmium (II). Geochim. Cosmochim. Acta 44:1381-1384.
40. Senesi, N., G. Sposito, and J.P. Martin. 1986. Copper (II) and Iron (III) complexation by soil humic acids an IR and ESR study. Sci. Total Environ. 55:351-362.
41. Stern, E.A., M. Newville, B. Ravel, Y. Yacoby, and D. Haskel. 1995. The uwxafs analysis package - Philosophy and details. Physica B (Amsterdam) 209:117-120.
42. Trombly, J. 1994. Electrochemical remediation: Take to the field Environ. Sci. Technol. 28:A289-A291.
43. Wada, S.-I., and Y. Umegaki. 2001. Major ion and electrical potential distribution in soil under electrokinetic remediation. Environ. Sci. Technol. 35:2151-2155.
44. Yamashita, H., M. Matsuoka, K. Tsuji, Y. Shioya, M. Anpo, and M. Che. 1996. In-situ XAFS, photoluminescence, and IR investigations of copper ions included within various kinds of zeolites - Structure of Cu(I) ions and their interaction with CO molecules. J. Phys. Chem. 100:397-402.
45. Yeung, A.T., C. Hsu, and R.M. Menon. 1996. EDTA-enhanced electrokinetic extraction of lead. J. Geotech. Eng. 122:666-673.