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Volumn 15, Issue 3, 1996, Pages 1075-1078

Metal-dependent stabilization of Si-S bonds to hydrolysis in iridium and rhodium silyls. Hydrolyzability as a probe for Si-H reductive elimination

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EID: 0037611473     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om950791r     Document Type: Article
Times cited : (15)

References (39)
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    • 3Si analogs of 6 are fully characterized and exhibit completely analogous spectral data; see: Thorn, D. L.; Harlow, R. L. Inorg. Chem. 1990, 29, 2017. Aizenberg, M.; Milstein, D. Angew. Chem. 1994, 106, 344; Angew. Chem., Int. Ed. Engl. 1994, 33, 317. Aizenberg, M.; Milstein, D. J. Am. Chem. Soc. 1995, 117, 6456.
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    • note
    • Attempts to prepare rhodium analogs of 5 and 6 were unsuccessful.
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    • For RS-H oxidative additions see, for example: (a) Singer, H.; Wilkinson, G. J. Chem. Soc. A 1968, 2516. (b) Crooks, G. R.; Johnson, B. F. G.; Lewis, J.; Williams, I. G. J. Chem. Soc. A 1969, 797. (c) Stiddard, M. H. B.; Townsend, R. E. J. Chem. Soc. A 1970, 2719. (d) Rauchfuss, T. B.; Roundhill, D. M. J. Am. Chem. Soc. 1975, 97, 3386. (e) Collman, J. P.; Rothrock, R. K.; Stark, R. A. Inorg. Chem. 1977, 16, 437.
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    • and references therein
    • The reductive elimination of Si-H bonds is well-known, and its kinetics was investigated. See for example: (a) Haszeldine, R. N.; Parish, R. V.; Taylor, R. J. J. Chem. Soc., Dalton Trans. 1974, 2311. (b) Hostetler, M. J.; Bergman, R, G. J. Am. Chem. Soc. 1990, 112, 8621. (c) Hostetler, M. J.; Butts, M. D.; Bergman, R. G. Organometallics 1993, 12, 65. (d) Johnson, C. E.; Eisenberg, R. J. Am. Chem. Soc. 1985, 107, 6531. (e) Hays, M. K., Eisenberg, R. Inorg. Chem. 1991, 30, 2623. (f) Cleary, B. P.; Mehta, R.; Eisenberg, R. Organometallics 1995, 14, 2297 and references therein.
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    • and references therein
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