Preparation of trialkylgermyl and -stannyl derivatives of methyl isothiocyanate by in situ trapping of anionic intermediates with chloro(trialkyl)germane and -stannanes

Arkivoc

Volumn 2001, Issue 9, 2001, Pages 7-11

  Brandsma, Lambert ^a   Nedolya, Nina A ^b  

^a Siberian Br of the Russ Acad Sci ^*  (Netherlands)

^b A E FAVORSKY IRKUTSK INSTITUTE OF CHEMISTRY   (Russian Federation)

Author keywords

(Trialkylstannyl)methyl isothiocyanates; (Trimethylgermyl)methyl isothiocyanates; Deprotonation; Lithium diisopropylamide

Indexed keywords

(ISOTHIOCYANATOMETHYL)(TRIMETHYL)GERMANE; (ISOTHIOCYANATOMETHYL)(TRIMETHYL)STANNANE; [ISOTHIOCYANATO(TRIMETHYLGERMYL)METHYL](TRIMETHYL)GERMANE; AMIDE; CHLORO(TRIMETHYL)GERMANE; ETHER; ISOTHIOCYANIC ACID DERIVATIVE; LITHIUM DIISOPROPYLAMIDE; METHYLISOTHIOCYANATE; TETRAHYDROFURAN; TIN DERIVATIVE; TRIBUTYL(ISOTHIOCYANATOMETHYL)STANNANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; SYNTHESIS;

EID: 3242762178     PISSN: 14246376     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (9)

1. de Jong, R. L. P.; Verkruijsse, H. D.; Brandsma, L. in Perspectives in the Organic Chemistry of Sulfur, Zwanenburg, B.; Klunder, A. J. H. Eds., Elsevier: Amsterdam, 1987, 105.
2. (a) Brandsma, L.; Nedolya, N. A.; Tarasova, O. A.; Trofimov, B. A. Chem. Heterocycl. Compd. (N.Y.). 2000, 36, 1241. Brandsma, L.; Nedolya, N. A.; Tarasova, O. A.; Trofimov, B. A. Khim. Geterotsikl. Soedin. 2000, 1443.
3. (a) Brandsma, L.; Nedolya, N. A.; Tarasova, O. A.; Trofimov, B. A. Chem. Heterocycl. Compd. (N.Y.). 2000, 36, 1241. Brandsma, L.; Nedolya, N. A.; Tarasova, O. A.; Trofimov, B. A. Khim. Geterotsikl. Soedin. 2000, 1443.
4. (b) Brandsma, L. Eur. J. Org. Chem. 2001, in press.
5. Nedolya N.A., Novel Chemistry Based on Isothiocyanates and Polar Organometallics. Thesis Utrecht University, 1999.
6. Brandsma, L.; Nedolya, N. A.; Verkruijsse, H. D.; Trofimov, B. A. Synthesis 1997, 423.
7. Andringa, H.; Heus-Kloos, Y. A.; Brandsma, L. J. Organomet. Chem. 1987, 336, C41.
8. Brandsma, L.; Nedolya, N. A.; Trofimov, B. A. Mendeleev Commun. 1997, 232.
9. Nedolya, N. A.; Brandsma, L.; Trofimov, B. A. Tetrahedron Lett. 1997, 38, 6279.