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Our DSC experiments on collected "sandwiched" PEO-b-PS single crystals from amyl acetate solution showed that the heiat of fusion under the melting endotherm of these crystals is 8.2 kJ/mol, which equvalent to 95% of the PEO crystal-unity (the equilibrium heat of fusion is 8.66 kJ/mol). Note that this calculation needs to take the percentage of the PEO blocks in the diblock copolymer into account.
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PS for these PS samples were estimated from hydrodynamic radius in amyl acetate were 2.7, 4.1, and 5.4 nm, respectively. The results show that for PS chains amyl acetate is a very good solvent, which is about 6 times better than the mixed chlorobenzene/octane solvent (the mixed solvent is close to the 8 condition).
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