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Volumn 38, Issue 13, 1997, Pages 3151-3212

Kinetics of crystallization from the melt and chain folding in polyethylene fractions revisited: Theory and experiment

Author keywords

Chain folding; Characteristic ratio; Forced reptation; Friction coefficient; Growth rate; Kuhn length; Lamellar thickness; Nucleation theory; Physical adsorption; Polyethylene; Regime transition; Reptation of slack; Substrate length; Surface free energy

Indexed keywords

CRYSTAL GROWTH FROM MELT; CRYSTAL STRUCTURE; CRYSTALLIZATION; FREE ENERGY; INTERFACIAL ENERGY; MATHEMATICAL MODELS; MOLECULAR WEIGHT; NUCLEATION; REACTION KINETICS;

EID: 0031166119     PISSN: 00323861     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0032-3861(97)00071-2     Document Type: Review
Times cited : (991)

References (208)
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    • 110 was evidently free of such an adsorbed layer. Regarding removal of the adsorbed molecules, we speculate that prolonged storage of single crystals at an appropriate temperature in the presence of excess solvent may permit migration of most of the molecules adsorbed on the fold surface to the growth front at the crystal edge where they could crystallize.
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    • W = 32.1K) at 90°C and 100°C.
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    • The authors thank Prof S. Z. D. Cheng, University of Akron, for providing independent confirmation of the existence of irregular spherulites in range D-D′. The measurements were made by Mr Fang-Chyou Chiu.
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    • 2. For the experiments cited in the text, it is evident that the initial lamellar thickness is separable from the effects of subsequent thickening.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.