Reversible disulfur monoxide (S2O)-forming retro-Diels-Alder reaction. Disproportionation of S2O to trithio-ozone (S3) and sulfur dioxide (SO2) and reactivities of S2O and S3

Journal of the American Chemical Society

Volumn 126, Issue 29, 2004, Pages 9085-9093

  Nakayama, Juzo ^a   Aoki, Satoshi ^a   Takayama, Jun ^a   Sakamoto, Akira ^a   Sugihara, Yoshiaki ^a   Ishii, Akihiko ^a  

^a SAITAMA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; CHEMICAL REACTIONS; ISOMERIZATION; ISOMERS; MIXTURES; ORGANIC COMPOUNDS; OXIDATION; THERMAL EFFECTS;

CYCLOADDITION; HIGH YIELD; ISOMERIC MIXTURE;

SULFUR;

3,4 DI TERT BUTYLTHIOPHENE 1 OXIDE; 5,6 DI TERT BUTYL 2,3,7 TRITHIABICYCLO[2.2.1]HEPT 5 ENE 2 ENDO 7 ENDO DIOXIDE; 5,6 DI TERT BUTYL 2,3,7 TRITHIABICYCLO[2.2.1]HEPT 5 ENE 2 EXO 7 ENDO DIOXIDE; 5,6 DI TERT BUTYL 2,3,7 TRITHIABICYCLO[2.2.1]HEPT 5 ENE 7 ENDO OXIDE; DIMETHYLDIOXIRANE; DISULFUR MONOXIDE; NORBORNENE DERIVATIVE; OZONE; SULFUR DIOXIDE; SULFUR OXIDE; THIOL DERIVATIVE; THIOPHENE DERIVATIVE; TRITHIOOZONE; UNCLASSIFIED DRUG;

ARTICLE; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; DIELS ALDER REACTION; DIPOLE; RETRO DIELS ALDER REACTION;

EID: 3242744396     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja047729i     Document Type: Article

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