(Salen)chromium(III)/DMAP: An efficient catalyst system for the selective synthesis of 5-substituted oxazolidinones from carbon dioxide and aziridines

Organic Letters

Volumn 6, Issue 14, 2004, Pages 2301-2304

  Miller, Aaron W ^a   Nguyen, SonBinh T ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AZIRIDINE; CARBON DIOXIDE; CHROMIUM; OXAZOLIDINONE DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL BOND; CROSS COUPLING REACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; SYNTHESIS;

EID: 3242723482     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol049689t     Document Type: Article

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20. 2 (20 mL) through a solvent-wet silica plug that was doped with triethylamine (100 μL) before introduction of the aliquot. Yield was determined via GC, using peak areas and undecane internal standard.) Further purification by column chromatography over neutral alumina (150 mesh, 58 Å, hexanes: ethyl acetate 60:40) gave pure oxazolidinone product (mixture of 4- and 5-substituted isomers).