Synthesis and characterization of castor oil/trimethylol propane polyol as raw materials for polyurethanes using time-of-flight mass spectroscopy

International Journal of Polymer Analysis and Characterization

Volumn 10, Issue 5-6, 2005, Pages 373-386

  Kaushik, Anupama ^a   Singh, Paramjit ^a  

^a PANJAB UNIVERSITY   (India)

Author keywords

Castor oil; MALDI MS; Polyol; Trimethylol propane

Indexed keywords

EID: 31544443006     PISSN: 1023666X     EISSN: None     Source Type: Journal    
DOI: 10.1080/10236660500479585     Document Type: Article

References (25)

1. Ramamurthi, S., V. Manohar, and V. V. S. Mani. (1998). Characterisation of fatty acid isomers in dehydrated castor oil by gas chromatography and gas chromatography mass spectrometry techniques. J. Am. Oil Chem. Soc. 75(10), 1297-1303.
2. Naughton, F. C. (1974). Production, chemistry and commercial applications of various chemicals from castor oil. J. Am. Oil Chem. Soc. 51(3), 65-71.
3. Saxena, P. K., S. R. Srinivasan, J. Hrouz, and M. Ilavský. (1992). The effect of castor oil on the structure and properties of polyurethane elastomers. J. Appl. Polym. Sci. 44(8), 1343-1347.
4. Tran, N. B. and Q. T. Pham. (1997). Castor oil-based polyurethanes. II: Tridimensional polyaddition in bulk between castor oil and diisocyanates - Gelation and determination of Fw(OH). Polymer 38(13), 3307-3314.
5. Tran, N. B., J. Vialle, and Q. T. Pham. (1997). Castor oil-based polyurethanes. I: Structural characterization of castor oil - Nature of intact glycerides and distribution of hydroxyl groups. Polymer 38(10), 2467-2473.
6. Somani, K. P., S. S. Kansara, N. K. Patel, and A. K. Rakshit. (2003). Castor oil based polyurethane adhesives for wood-to-wood bonding. Int. J. Adhes. Adhes. 23(4), 269-275.
7. Eckey, E. W. and P. M. Lawrence. (1954). Vegetable Fats and Oils. New York: Reinhold Publishing Corporation.
8. Lyon, C. K., V. H. Garrett, and L. A. Goldblatt. (1962). Solvent-blown, rigid urethane foams from low cost castor oil polyol mixtures. J. Am. Oil Chem. Soc. 39, 69-71.
9. Lyon, C. K. and V. H. Garrett. (1973). New castor oil-based urethane elastomers. J. Am. Oil Chem. Soc. 50(4), 112-114.
10. Petrovic, Z. S. and D. Fajnik. (1984). Preparation and properties of castor oil-based polyurethanes. J. Appl. Polym. Sci. 29(4), 1031-1040.
11. Ghatge, N. D. and V. B. Phadke. (1967). Elastomers from castor oil. J. Appl. Polym. Sci. 11(5), 629-638.
12. Lal, K. and V. Carrick. (1994). Performance testing of lubricants based on high oleic vegetable oils. Synth. Lubr. 11(3), 189-206.
13. Nayak, P., D. K. Mishra, K. C. Sahoo, N. C. Pati, P. K. Jena, S. Lenka, and P. L. Nayak. (2001). Polymers from renewable resources. XIII: Interpenetrating polymer networks derived from castor oil-hexamethylene diisocyanate and polymethacrylamide. J. Appl. Polym. Sci. 80(9), 1349-1353.
14. Prashantha, K., K. V. K. Pai, B. S. Sherigar, and S. Prasannakumar. (2001). Interpenetrating networks based on polyol modified castor oil polyurethane and poly(2-hydroxylmethacrylate): Synthesis, chemical, mechanical and thermal properties. Bull Mater. Sci. 24(5), 535-538.
15. Noureddini, H. and D. Zhu. (1997). Kinetics of transesterification of soybean oil. J. Am. Oil Chem. Soc. 74(11), 1457-1463.
16. Abreu, F. R., D. G. Lima, E. H. Hamu, C. Wolf, and P. A. Z. Suarez. (2004). Utilization of metal complexes as catalysts in the transesterification of Brazilian vegetable oils with different alcohols. J. Molec. Catal. A. Chem. 209(1-2), 29-33.
17. Agra, I. B., S. Warnijati, and Wiratni. (1996). Two steps ethanolysis of castor oil using sulfuric acid as catalist to produce motor oil. Renew. Energy 9(1-4), 1025-1028.
18. Gelbard, G. and F. Vielfaure-Joly. (2000). Polynitrogen strong bases as immobilised catalysts for the transesterification of vegetable oils. Surf. Chem. Catal. 3, 563-567.
19. Suppes, G. J., M. A. Dasari, E. J. Doskocil, P. J. Mankidy, and M. J. Goff. (2004). Transesterification of soybean oil with zeolite and metal catalysts. Appl. Catal. A. 257(2), 213-223.
20. Gryglewicz, S., W. Piechocki, and G. Gryglewicz. (2003). Preparation of polyol esters based on vegetable and animal fats. Bioresour. Technol. 87(1), 35-39.
21. Yunus, R., A. Fakhru'l-Razi, T. L. Ooi, S. E. Iyuke, and J. M. Perez. (2004). Lubrication properties of trimethylolpropane esters based on palm oil and palm kernel oils. Eur. J. Lipid Sci. Technol. 106(1), 52-60.
22. Ayorinde, F. O., E. Elhilo, and C. Hlongwane. (1999). Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry of canola, castor and olive oils. Rapid Commun. Mass Spectrom. 13(8), 737-739.
23. Ayorinde, F. O. (2000). Determination of the molecular distribution of triacylglycerol oils using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Lipid Technol. 12, 41-44.
24. Ayorinde, F. O., K. Garvin, and K. Saeed. (2000). Determination of the fatty acid composition of saponified vegetable oils using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Rapid Commun. Mass Spectrom. 14(7), 608-615.
25. Stubiger, G., E. Pittenauer, and G. Allmaier. (2003). Characterisation of castor oil by on-line and off-line non-aqueous reverse-phase high-performance liquid chromatography-mass spectrometry (APCI and UV/MALDI). Phytochem. Anal. 14(6), 337-346.