메뉴 건너뛰기




Volumn 126, Issue 27, 2004, Pages 8366-8367

Bridging the gap between homogeneous and heterogeneous catalysis: Ortho/para H2 conversion, hydrogen isotope scrambling, and hydrogenation of olefins by Ir(CO)Cl(PPh3)2

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE; HYDROGEN; IRIDIUM COMPLEX; METAL COMPLEX;

EID: 3142748444     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0475961     Document Type: Article
Times cited : (44)

References (32)
  • 2
    • 37049159291 scopus 로고
    • For studies of SC of diamagnetic transition metal complexes in solution, see: (a) Calvin, M. Trans. Faraday Soc. 1938, 34, 1181.
    • (1938) Trans. Faraday Soc. , vol.34 , pp. 1181
    • Calvin, M.1
  • 5
    • 0012469595 scopus 로고
    • For studies of IS of diamagnetic transition metal complexes in solution, see: (a) Eberhardt, G. G.; Vaska, L. J. Catal. 1967, 8, 183.
    • (1967) J. Catal. , vol.8 , pp. 183
    • Eberhardt, G.G.1    Vaska, L.2
  • 16
    • 0003471615 scopus 로고    scopus 로고
    • Fackler, J. P., Ed.; Kluwer Academic/Plenum Publishers: New York
    • (c) Kubas, G. J. Metal Dihydrogen and σ-Bond Complexes; Fackler, J. P., Ed.; Kluwer Academic/Plenum Publishers: New York, 2001.
    • (2001) Metal Dihydrogen and σ-Bond Complexes
    • Kubas, G.J.1
  • 18
    • 33748644326 scopus 로고
    • (a) Limbach, H. H.; Scherer, G.; Maurer, M.; Chaudret, B. Angew. Chem. 1992, 104, 1414; Angew. Chem., Int. Ed. Engl. 1992, 31, 1369.
    • (1992) Angew. Chem., Int. Ed. Engl. , vol.31 , pp. 1369
  • 20
    • 3142784128 scopus 로고    scopus 로고
    • note
    • Preliminary model calculations show that a dipolar magnetic SC is operative in the solid state and a scalar magnetic SC in the liquid state when ΔE is reduced to the order of the magnetic interactions involved. For that purpose, the H-H distances need to be increased to more than about 1.3 Å.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.