NMR and INS line shapes of transition metal hydrides in the presence of coherent and incoherent dihydrogen exchange

Journal of the American Chemical Society

Volumn 120, Issue 31, 1998, Pages 7929-7943

  Limbach, Hans Heinrich ^a   Ulrich, Stefan ^a   Gründemann, Stephan ^a   Buntkowsky, Gerd ^a   Sabo Etienne, Sylviane ^b   Chaudret, Bruno ^b   Kubas, Gregory J ^c   Eckert, Jürgen ^c  

^a FREIE UNIVERSITÄT BERLIN   (Germany)

^b LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

^c LOS ALAMOS NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN; ISOTOPE; METAL;

ARTICLE; ELECTRON TRANSPORT; MATHEMATICAL ANALYSIS; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; NUCLEAR MAGNETIC RESONANCE; PROTON TRANSPORT; REACTION ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 0032511432     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962903r     Document Type: Article

References (7)

1. (a) Kubas, G. J.; Ryan, R. R.; Swanson, B. I.; Vergamini, P. J.; Wasserman, H. J. J. Am. Chem. Soc. 1984, 106, 451.
2. (b) Kubas, G. J. Acc. Chem. Res. 1988, 21, 120.
3. Ernst, R. R.; Andersen, W.A. Rev. Sci. Instr. 1966, 37, 93.
4. (a) Wallach, D.; Steele, W. A. J. Chem. Phys. 1976, 52, 2534.
5. (b) National Bureau of Standards, Tables relating to Mathieu functions; Columbia University Press: New York, NY, 1951.
6. Limbach, H. H. Dynamic NMR Spectroscopy in the Presence of Kinetic Hydrogen Deuterium Isotope Effects. In NMR Basic Principles and Progress; Berlin, Heidelberg, New York, 1990; Vol. 26, Chapter 2.
7. Bell, R. P. The Tunnel Effect, 2nd ed.; Chapman and Hall: London, 1980.