Rapid equilibrium between trigonal-bipyramidal and square-pyramidal geometries of 1-popanethiolato platinum(II) complex with tris[2- (diphenylphosphino)ethyl]phosphine

Chemistry Letters

Volumn 33, Issue 4, 2004, Pages 384-385

  Aizawa, Sen Ichi ^a   Kobayashi, Tadashi ^a  

^a UNIVERSITY OF TOYAMA   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1 PROPANETHIOLATOPLATINUM COMPLEX; PHENYL GROUP; PHOSPHINE DERIVATIVE; PLATINUM COMPLEX; TRIS[2 (DIPHENYLPHOSPHINO)ETHYL]PHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; DISSOCIATION; GEOMETRY; LOW TEMPERATURE; SUBSTITUTION REACTION; SYNTHESIS;

EID: 3142731580     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2004.384     Document Type: Article

References (17)

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2. R. G. Wilkins, in "Kinetics and Mechanism of Reaction of Transition Metal Complexes," 2nd ed., VCH, Weinheim (1991), Chap. 4; B. J. Cross, "Mechanisms of Inorganic and Organometallic Reactions," ed. by M. V. Twigg, Plenum, New York (1988), Chap. 5; Z. Lin and M. B. Hall, Inorg. Chem., 30, 646 (1991).
3. R. G. Wilkins, in "Kinetics and Mechanism of Reaction of Transition Metal Complexes," 2nd ed., VCH, Weinheim (1991), Chap. 4; B. J. Cross, "Mechanisms of Inorganic and Organometallic Reactions," ed. by M. V. Twigg, Plenum, New York (1988), Chap. 5; Z. Lin and M. B. Hall, Inorg. Chem., 30, 646 (1991).
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8. R. B. King, R. N. Kapoor, M. S. Saran, and P. N. Kapoor, Inorg. Chem., 10, 1851 (1971); C. A. Ghilardi, S. Midollini, and L. Sacconi, Inorg. Chem., 14, 1790 (1975); A. Orlandini and L. Sacconi, Inorg. Chem., 15, 78 (1976); W. H. Hohman, D. J. Kountz, and D. W. Meek, Inorg. Chem., 25, 616 (1986).
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11. 3CN are omitted here.
12. P-Pt = 970 Hz).
13. P-Pt = 1191 Hz).
14. P-Pt = 1061 Hz) (unpublished results).
15. P-P = 26 Hz.
16. P-Pt = 1400 Hz) (unpublished results).
17. -1, respectively, under the conditions in Figure 1.