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Volumn 43, Issue 14, 2004, Pages 4289-4299

Molecular structure and vibrational spectra of spin-crossover complexes in solution and colloidal media: Resonance Raman and time-resolved resonance Raman studies

Author keywords

[No Author keywords available]

Indexed keywords

2,2' BIPYRIDINE DERIVATIVE; N,N' BIS(BENZYL) N,N' BIS(2 PYRIDYLMETHYL) 6,6' BIS(AMINOMETHYL) 2,2' BIPYRIDINE; N,N,N',N' TETRAKIS(2 PYRIDYLMETHYL) 6,6' BIS(AMINOMETHYL) 2,2' BIPYRIDINE; RUTHENIUM DERIVATIVE; UNCLASSIFIED DRUG; ZINC DERIVATIVE;

EID: 3142704376     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic049809t     Document Type: Article
Times cited : (41)

References (63)
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    • (1995) SMART, SAINT, and XPREP
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    • Hazell, A. KRYSTAL; Aarhus University: Aarhus, Denmark, 1995.
    • (1995) KRYSTAL
    • Hazell, A.1
  • 35
    • 3142678492 scopus 로고    scopus 로고
    • Ph.D. Thesis, Queens University of Belfast, Belfast, U.K.
    • Brady, C. Ph.D. Thesis, Queens University of Belfast, Belfast, U.K., 2002.
    • (2002)
    • Brady, C.1
  • 41
    • 3142784077 scopus 로고    scopus 로고
    • note
    • 2, respectively. The in-plane distortion relieves the strain at the M-N-C angles.
  • 42
    • 85086528263 scopus 로고    scopus 로고
    • note
    • 3CN).
  • 43
    • 85086527361 scopus 로고    scopus 로고
    • note
    • 3), 111.3(4).
  • 45
    • 3142723852 scopus 로고    scopus 로고
    • note
    • A subroutine within a multivariate analysis program, "The Unscrambler", selected the most correlated spectral peaks from the entire series of spectra (Figure S3) as input. The optimum correlation emerged when the spectra were input in two time segments, 15-100 and 150-5000 ns. Although the procedure here involves a partial least-squares linear regression and is not therefore a kinetic analysis, the appearance of the optimum correlation by taking the data in two time segments is qualitatively consistent with the biphasic decay which emerges from the kinetic analysis.
  • 46
    • 3142697483 scopus 로고    scopus 로고
    • note
    • The picosecond transient absorption (ps-TA) studies were also performed at the RAL facility. The measurements were carried out using two independently tunable and synchronized 200-300 fs pulses generated by a regenerative amplifier system operated at 800 Hz. The pump pulse was obtained at 400 nm, and a white light continuum was used as a probe. This white light was separated into two beams, one passing through the sample and the other used as a reference; both beams were dispersed onto two identical photodiode arrays. The probe beam was delayed with respect to the pump beam by means of an optical delay line.
  • 55
    • 3142663721 scopus 로고    scopus 로고
    • note
    • Although there is clear spectral evidence for the spin equilibrium in the colloid, it is not possible to state whether the position of equilibrium remains the same as in homogeneous solution.
  • 56
    • 3142771079 scopus 로고    scopus 로고
    • note
    • B at 77 K and RT, respectively. The origin of the second high-spin isomer is unclear at present.
  • 61
    • 85086527836 scopus 로고    scopus 로고
    • note
    • -, centered transitions, but if a substantial amount of this species were present, a marked reduction in the intensities of the neutral ligand bands would be expected.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.