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3142784077
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note
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2, respectively. The in-plane distortion relieves the strain at the M-N-C angles.
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42
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85086528263
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note
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3CN).
-
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43
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85086527361
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note
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3), 111.3(4).
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A subroutine within a multivariate analysis program, "The Unscrambler", selected the most correlated spectral peaks from the entire series of spectra (Figure S3) as input. The optimum correlation emerged when the spectra were input in two time segments, 15-100 and 150-5000 ns. Although the procedure here involves a partial least-squares linear regression and is not therefore a kinetic analysis, the appearance of the optimum correlation by taking the data in two time segments is qualitatively consistent with the biphasic decay which emerges from the kinetic analysis.
-
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46
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3142697483
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note
-
The picosecond transient absorption (ps-TA) studies were also performed at the RAL facility. The measurements were carried out using two independently tunable and synchronized 200-300 fs pulses generated by a regenerative amplifier system operated at 800 Hz. The pump pulse was obtained at 400 nm, and a white light continuum was used as a probe. This white light was separated into two beams, one passing through the sample and the other used as a reference; both beams were dispersed onto two identical photodiode arrays. The probe beam was delayed with respect to the pump beam by means of an optical delay line.
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Although there is clear spectral evidence for the spin equilibrium in the colloid, it is not possible to state whether the position of equilibrium remains the same as in homogeneous solution.
-
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56
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3142771079
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B at 77 K and RT, respectively. The origin of the second high-spin isomer is unclear at present.
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85086527836
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-, centered transitions, but if a substantial amount of this species were present, a marked reduction in the intensities of the neutral ligand bands would be expected.
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