Preparation of silyl-substituted dizinciomethanes and their reactions with electrophiles

Synlett

Volumn , Issue 12, 1998, Pages 1315-1316

  Matsubara, Seijiro ^a   Otake, Yasuyuki ^a   Morikawa, Takuya ^a   Utimoto, Kiitiro ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0002386712     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1998-1977     Document Type: Article

References (18)

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3. (b) Matsubara, S.; Kawamoto, K.; Utimoto, K. Synlett 1998, 267.
4. (c) Matsubara, S.; Sugihara, M.; Utimoto, K. Synlett 1998, 313.
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6. Nakamura, E.; Kubota, K.; Sakata, G. J. Am. Chem. Soc., 1997, 119, 5457.
7. Oxidation of C-Si bond into C-O bond: Colvin, E. W. In Comprehensive Organic Synthesis, Vol. 7; Ley, S.V.; Trost, B. M.; Fleming, I. Eds.; Pergamon Press: Oxford, 1991, p641.
8. gem-Dimagnesium derivatives: Bertini, F.; Grasselli, P.; Zubiani, G.; Cainelli, G Tetrahedron 1970, 26, 1281;
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15. 8 at -63 °C): δ-1.62 (s, 1H), -0.09 (s, 9H).
16. 8, 20 °C); δ 0.05 (s, 9H), 1.52 (d, J = 12.9 Hz, 1H), 5.94 (d, J = 15.0 Hz, 1H), 6.66 (dd, J = 15.0, 12.9 Hz, 1H), 6.87-7.37 (m, 5H).
17. Knochel, P.; Singer, R. D. Chem. Rev., 1993, 93, 2117;
18. Knochel, P. Synlett 1995, 393.