Kinetics and mechanisms in carbocationic polymerization: The quest for true rate constants

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 43, Issue 22, 2005, Pages 5394-5413

  Puskas, Judit E ^a,e   Chan, Sam W P ^a   McAuley, Kimberley B ^b,f   Shaikh, Sohel ^c   Kaszas, Gabor ^d  

^a The University of Akron   (United States)

^b QUEEN S UNIVERSITY   (Canada)

^c UNIVERSITY OF WESTERN ONTARIO   (Canada)

^d Lanxess Inc   (Canada)

^e International Union of Pure and Applied Chemistry   (United Kingdom)

^f School of Graduate Studies and Research

Author keywords

Activation enthalpy; Carbocationic polymerization; Electron pair donor effect; Isobutylene; Kinetics (polym.); Mechanism; Rate constant of propagation; Styrene styene derivatives; Vinyl ethers

Indexed keywords

ACTIVATION ENTHALPY; CARBOCATIONIC POLYMERIZATION; ELECTRON PAIR DONOR EFFECTS; ISOBUTYLENE; KINETIC (POLYM.); RATE CONSTANT OF PROPAGATION; STYRENE-STYRENE DERIVATIVES; VINYL ETHERS;

ENTHALPY; ETHERS; MECHANISMS; RATE CONSTANTS; REACTION KINETICS; THERMAL EFFECTS;

CATIONIC POLYMERIZATION;

EID: 30544450666     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.21011     Document Type: Article

References (71)

1. Roth, M.; Mayr, H. Macromolecules 1996, 29, 6104-6109.
2. Plesch, P. H. Prog React Kinet 1993, 18, 1-62.
3. Williams, F.; Hayashi, K.; Ueno, K.; Hayashi, K.; Okamura, S. Trans Faraday Soc 1967, 63, 1501-1511.
4. Sorgo, M.; Pepper, D.; Szwarc, M. J. C. S. Chem Commun 1973, 13, 419-420.
5. Brendle, M.; Ilvoas, A. Br Polym J 1976, 8, 11-21.
6. Vairon, J.; Rives, A.; Bunel, C. Macromol Symp 1992, 60, 97-105.
7. Li, D.; Hadjikyriacou, S.; Faust, R. Macromolecules 1996, 29, 6061-6067.
8. Faust, R. Macromol Symp 2000, 157, 101-108.
9. Vairon, J. P.; Moreau, M.; Charleaux, B.; Cretol, A.; Faust, R. Macromol Symp 2002, 183, 43-52.
10. Sigwalt, P.; Moreau, M.; Polton, A. Makromol Chem Macromol Symp 2002, 183, 35-42.
11. De, P.; Faust, R.; Schimmel, H.; Mayr, H.; Moreau, M.; Charleaux, B.; Vairon, J. Symposium Lecture Notes, International Symposium of Ionic Polymerizations and Related Processes 2003, Boston, MA, 2003.
12. De, P.; Faust, R.; Schimmel, H.; Ofial, A.; Mayr, H. Macromolecules 2004, 37, 4422-4433.
13. Taylor, R.; Williams, F. Polym Prepr (Am Chem Soc Div Polym Chem) 1968, 9(2), 1227-1230.
14. Chmelir, M.; Marek, M.; Wichterle, O. J Polym Sci Polym Symp 1967, 16, 833-839.
15. Taylor, R.; Williams, F. J Am Chem Soc 1969, 91, 3728-3732.
16. Toman, L.; Marek, M. Makromol Chem 1976, 11, 3325-3343.
17. Magagnini, P.; Cesca, S.; Giusti, P.; Priola, A.; Maina, M. Makromol Chem 1977, 178, 2235-2248.
18. Schlaad, H.; Kwon, Y.; Sipos, L.; Faust, R.; Charleaux, B. Macromolecules 2000, 33, 8225-8232.
19. Sipos, L.; De, P.; Faust, R. Macromolecules 2003, 36, 8282-8290.
20. Williams, F. Macromolecules 2005, 38, 206-209.
21. Hayashi, K.; Hayashi, K.; Okamura, S. J Polym Sci Part A-1: Polym Chem 1971, 9, 2305-2321.
22. Chung, Y.; Rooney, J.; Squire, D.; Stannett, V. Polymer 1975, 16, 527-530.
23. Subira, F.; Sauvet, G.; Vairon, J.; Sigwalt, P. J Polym Sci Polym Symp 1976, 56, 221-231.
24. Stannett, V.; Garreau, H.; Ma, C.; Rooney, J.; Squire, D. J Polym Sci Polym Symp 1976, 56, 233-240.
25. Bonin, M.; Busler, W.; Williams, F. J Am Chem Soc 1965, 87, 199-207.
26. Williams, F.; Shinkawa, A. J Polym Sci Polym Symp 1976, 56, 421-430.
27. Puskas, J. E.; Lanzendorfer, M. G. Macromolecules 1998, 31, 8684-8690.
28. Storey, R. F.; Maggio, T. L. Macromolecules 2000, 33, 681-688.
29. Paulo, C.; Puskas, J. E.; Angepat, S. Macromolecules 2000, 33, 4634-4638.
30. Storey, R. F.; Curry, C. L.; Hendry, L. K. Macromolecules 2001, 34, 5416-5432.
31. Mayr, H.; Schimmel, H.; Kobayashi, S.; Kotani, M.; Prabarakaran, T.; Sipos, L.; Faust, R. Macromolecules 2002, 35, 4611-4615.
32. Wu, Y.; Tan, Y.; Wu, G. Macromolecules 2002, 35, 3801-3805.
33. Thomas, Q. A.; Storey, R. F. Macromolecules 2003, 36, 10120-10125.
34. Storey, R. F.; Thomas, Q. A. Macromolecules 2003, 36, 5065-5071.
35. Mayr, H.In Cationic Polymerizations: Mechanisms, Synthesis, and Application; Matyjaszewski K., Ed.; Plastics Engineering 35; Marcel Dekker: New York, 1996; p 51.
36. Puskas, J. E.; Wilson, G.; Duffy, J. Ullman's Encyclopedia of Industrial Chemistry, 7th ed.; Wiley: New York, 2004 Section 3.3.
37. Kaszas, G.; Puskas, J. E.; Baade, W. In Polymeric Materials Encyclopedia; Salamone, J., Ed.; CRC: Boca Raton, FL, 1996.
38. Puskas, J. E. Confidential Bayer Technical Report 1992-04-22; Bayer Inc.: Sarnia, Canada, 1992.
39. Richard, J. P.; Jencks, W. P. J Am Chem Soc 1984, 106, 1373-1383.
40. Schlaad, H.; Kwon, Y.; Faust, R.; Mayr, H. Macromolecules 2000, 33, 743-747.
41. (a) Mayr, H.; Patz, M. Angew Chem 1994, 106, 990-1010;
42. (b) Mayr, H.; Patz, M. Angew Chem Int Ed Engl 339, 938-955.
43. Mayr, H.; Kuhn, O.; Gotta, M. F.; Patz, M. J Phys Org Chem 1998, 11, 642-654.
44. Mayr, H. In Ionic Polymerization and Related Processes; Puskas, J. E., Ed.; NATO Science Series E 359; Kluwer Academic: Dordrecht, Boston, London, 1999; pp 99-115.
45. (a) Schimmel, H.; Ofial, A. R.; Mayr, H. Private communication, 2004, Munich, Germany;
46. (b) Schimmel, H.; Ofial, A. R.; Mayr, H. Macromolecules 2002, 35, 5454-5458.
47. Mayr, H.; Kempf, B.; Offial, A. R. Acc Chem Res 2003, 36, 66-77.
48. Shaikh, S.; Puskas, J. E.; Kaszas, G. J Polym Sci Part A: Polym Chem 2004, 42, 4084-4100.
49. Rudin, A. The Elements of Polymer Science and Engineering, 2nd ed.; Academic: San Diego, 1999; pp 266-268.
50. Mayr, H. Private communications, 2004, Ludwig-Maximilian Universitat, Munich, Germany.
51. Hayes, M. J.; Pepper, D. C. Proc Chem Soc 1958, 228-229.
52. Pepper, D. C.; Reilly, P. J. Proc Chem Soc 1961, 460.
53. Barton, J. M.; Pepper, D. C. J Chem Soc 1964, 1573-80.
54. Charleux, B.; Rives, A.; Vairon, J. P.; Matyjaszewski, K. Macromolecules 1996, 29, 5777-5783.
55. Müller, A. H. E.; Litvinenko, G.; Yan, D. Macromolecules 1996, 29, 2339-2345.
56. Wulkow, M.PREDICI®, Simulation Package for Polyreactions, Version 5.18.5; CiT GmbH: Berlin, Germany, 2001.
57. Yao, K. Z.; Shaw, B.; Kou, B.; McAuley, K. B.; Bacon, D. Polym React Eng 2003, 11, 563-588.
58. Puskas, J. E.; Shaikh, S.; Yao, K. Z.; McAuley, K. B.; Kaszas, G. Eur Polym J 2005, 41, 1-14.
59. Puskas, J. E.; Kaszas, G.; Litt, M. Macromolecules 1991, 24, 5278-5282.
60. Kaszas, G.; Puskas, J. E. Polym React Eng 1994, 2, 251-73.
61. Majoros, I.; Nagy, A.; Kennedy, J. P. Adv Polym Sci 1994, 112, 1-114.
62. Plesch, P. H. Macromolecules 2001, 34, 1143-1147.
63. Charleux, B.; Moreau, M.; Vairon, J. P.; Hadjikyriacou, S.; Faust, R. Macromol Symp 1998, 132, 25-35.
64. Puskas, J. E. In In-Situ Spectroscopy of Monomer and Polymer Synthesis; Puskas, J. E., Ed.; Kluwer Academic/Plenum: Dordrecht, Boston, London, 2003; pp 37-58.
65. Puskas, J. E.; Chan, S. W.; McAuley, K. B. Polym Prep (Am Chem Soc Div Polym Sci) 2005, 46(1), 834-835.
66. Storey, R.; Choate, K. Jr. Macromolecules 1997, 30, 4799-4806.
67. Fodor, Z.; Bae, Y.; Faust, R. Macromolecules 1998, 31, 4439-4446.
68. Storey, R. F.; Chisholm, B. J.; Brister, L. B. Macromolecules 1995, 28, 4055-4061.
69. Puskas, J. E.; Lanzendörfer, M. E.; Pattern, W. E. Polym Bull 1998, 40, 55-61.
70. Qiu, Y.; Wu, Y.; Gu, X.; Xu, X.; Wu, G. Eur Polym J 2005, 41, 349-358.
71. Puskas, J. E.; Shaikh, S. Makromol Chem Macromol Symp 2004, 215, 231-54.