Bis-axial cyanide coordination induces high nucleophilicity of the in-plane thiolato ligands bound to a Co(III) center: Model complexes related to the Co-containing nitrile hydratases

Inorganica Chimica Acta

Volumn 357, Issue 9, 2004, Pages 2462-2468

  Heinrich, Laurent ^a   Mary Verla, Aude ^a   Vaissermann, Jacqueline ^b   Chottard, Jean Claude ^a   Li, Yun ^a  

^a UNIVERSITÉ PARIS DESCARTES   (France)

^b SORBONNE UNIVERSITÉ   (France)

Author keywords

Carboxamido complexes; Chloromethanesulfido ligands; Cobalt; Nitrile hydratases; Oxygenation; S sulfinato ligands

Indexed keywords

COBALT; CYANIDES; LIGANDS; OXYGENATION;

AXIAL COORDINATION; CARBOXAMIDO COMPLEXES; CHLOROMETHYLATION; NITRILE HYDRATASES; NUCLEOPHILICITIES; SQUARE PLANAR COMPLEX; TETRADENTATE LIGANDS; THIOLATO LIGANDS;

COBALT COMPOUNDS;

COBALT; COBALT COMPLEX; CYANIDE; LIGAND; NITRILE HYDRATASE; SULFUR DERIVATIVE; THIOL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; COMPLEX FORMATION; LIGAND BINDING; METHYLATION; OXYGENATION;

EID: 3042623541     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2004.02.011     Document Type: Article

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