Latent reactive groups unveiled through equilibrium dynamics and exemplified in crosslinking during film formation from aqueous polymer colloids

Chemical Communications

Volumn , Issue 47, 2005, Pages 5904-5906

  Berrisford, David J ^a   Lovell, Peter A ^a   Suliman, Nadia R ^a   Whiting, Andrew ^b  

^a UNIVERSITY OF MANCHESTER   (United Kingdom)

^b DURHAM UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

POLYMER; STYRENE DERIVATIVE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; COLLOID; CROSS LINKING; DEHYDRATION; EMULSION; FILM; MOLECULAR DYNAMICS; MOLECULAR STABILITY; POLYMER PRODUCTION; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 29644438935     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b512073j     Document Type: Article

References (28)

1. (a) J. P. Howard, Chem. Ind., 1996, 796;
2. (b) A. Guyot, F. Chu, M. Schneider, C. Graillat and T. F. McKenna, Prog. Polym. Sci., 2002, 27, 1573;
3. J. W. Taylor and M. A. Winnik, JCT Res., 2004, 1, 163.
4. (a) S. J. Rowan, S. J. Cantrill, G. R. L. Cousins, J. K. M. Sanders and J. F. Stoddart, Angew. Chem., Int. Ed, 2002, 41, 898;
5. (b) e.g. D. H. Zhao and J. S. Moore, J. Am. Chem. Soc., 2002, 124, 9996.
6. For a related use of latent functional groups see: (a) P. P. Matloka, J. C. Sworen, F. Zuluaga and K. B. Wagener, Macromol. Chem. Phys., 2005, 206, 218;
7. (b) K. R. Brzezinska, R. Schitter and K. B. Wagener, J. Polym. Sci., Part A: Polym. Chem., 2000, 38, 1544.
8. Reactive dyes involving sulfone chemistry are well known, e.g.: (a) Z. Z. Zhu, J. M. Xia and K. C. Chen, Dyes Pigm., 1991, 17, 171;
9. (b) Z. Z. Zhu, J. M. Xia and K. C. Chen, Dyes Pigm., 1991, 17, 217;
10. (c) M. H. Zohdy, A. M. El Naggar and W. A. Abdallah, Polym. Degrad Stab., 1997, 55, 185;
11. (d) L. M. Jiang and Z. H. Zhu, Dyes Pigm., 1998, 36, 347;
12. (e) Z. H. Zhu and L. M. Jiang, Dyes Pigm., 1998, 36, 355.
13. Sulfones are used as linkers in solid phase organic synthesis, e.g.: (a) S. B. Katti, P. K. Misra, W. Haq and K. B. Mathur, J. Chem. Soc., Chem. Commun., 1992, 843;
14. (b) F. E. K. Kroll, R. Morphy, D. Rees and D. Gani, Tetrahedron Lett., 1997, 38, 8573;
15. (c) W. S. Wade, F. Yang and T. J. Sowin, J. Comb. Chem., 2000, 2, 266;
16. (d) W. C. Cheng, M. M. Olmstead and M. J. Kurth, J. Org. Chem., 2001, 66, 5528;
17. (e) W. C. Cheng and M. J. Kurth, J. Org. Chem., 2002, 67, 4387;
18. (f) W. C. Cheng, M. Wong, M. M. Olmstead and M. J. Kurth, Org. Lett., 2002, 4, 741;
19. (g) R. V. Connors, A. J. Zhang and S. J. Shuttleworth, Tetrahedron Lett., 2002, 43, 6661;
20. (h) K. H. Kong, Y. Chen, M. Xiang, W. K. Chui and Y. L. Lam, J. Comb. Chem., 2004, 6, 928.
21. D. J. Berrisford, P. A. Lovell and A. Whiting, Hydroxyethylsulfones - new functional monomers for emulsion polymerisations; UMIST: 2004, UK Patent, PCT/GB2003/005240.
22. G. K. Biswas and P. Bhattacharyya, Synth. Commun., 1991, 21, 569.
23. (a) H. Kamogawa, A. Kanzawa, M. Kadoya, T. Naito and M. Nanasawa, Bull. Chem. Soc. Jpn., 1983, 56, 762;
24. (b) H. Kamogawa, T. Hayashi and M. Nanasawa, Chem. Lett., 1976, 419;
25. (c) H. Kamogawa, H. Inoue, H. Fukuyama and M. Nanasawa, Bull. Chem. Soc. Jpn., 1979, 52, 3010.
26. P. A. Lovell, in Emulsion Polymerization and Emulsion Polymers; P. A. Lovell and M. S. El-Aasser, Eds.; John Wiley & Sons: Chichester, UK, 1997, p. 239.
27. (a) A. Khan and A. Marsh, Synth. Commun., 2000, 30, 2599;
28. (b) T. Pathak, Eur. J. Org. Chem., 2004, 3361.