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For a comprehensive series of studies on intramolecular exciplexes in arene-amine systems see the work developed by F.D. Lewis:
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0001928585
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The possibility of occurring the existence of a non-linear triple exciplex like the described in this paper can not be ruled out although a X-ray crystal structure of 1 shows that both amine groups are not pointing into the same direction (Chem. Eur. J., accepted for publication)
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Fages F., Desvergne J.P., Bouas-Laurent H. J. Am. Chem. Soc. 111:1989;96. The possibility of occurring the existence of a non-linear triple exciplex like the described in this paper can not be ruled out although a X-ray crystal structure of 1 shows that both amine groups are not pointing into the same direction (Chem. Eur. J., accepted for publication)
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40
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2942728171
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note
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This parameter does not only refer to the overall changes in the geometry but also to the differences in bond distances (force constants) within the arene, changing from neutral to anion
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0037026795
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