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Volumn 101, Issue 27, 1997, Pages 4922-4928

Estimation of the bimolecular rate constant for exciplex formation from the analysis of its emission spectrum

Author keywords

[No Author keywords available]

Indexed keywords

AMINES; CHARGE TRANSFER; ELECTRONS; EMISSION SPECTROSCOPY; FLUORESCENCE; GIBBS FREE ENERGY; QUENCHING; REACTION KINETICS; SOLVENTS;

EID: 0031551190     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp970202q     Document Type: Article
Times cited : (11)

References (61)
  • 5
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    • Marcus, R. A. J. Phys. Chem. 1989, 993, 3078, and references therein.
    • (1989) J. Phys. Chem. , vol.993 , pp. 3078
    • Marcus, R.A.1
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    • note
    • f); see ref 5.
  • 31
    • 0000192894 scopus 로고
    • This same behavior is predicted by the well-known Lippert-Mataga equation. However, the Lippert-Mataga equation was derived for an unspecific substrate (in the point-dipole approximation) using the reaction field method. Hence, it does not give explicit information regarding the radiative back electron transfer reaction. (a) Von Lippert, E. Z. Electrochem. 1957, 61, 962. (b) Mataga, N.; Kaifu, Y.; Koizumi, M. Bull. Chem. Soc. Jpn. 1956, 29, 465, and references cited therein.
    • (1957) Electrochem. , vol.61 , pp. 962
    • Von Lippert, E.Z.1
  • 32
    • 0001444812 scopus 로고
    • and references cited therein
    • This same behavior is predicted by the well-known Lippert-Mataga equation. However, the Lippert-Mataga equation was derived for an unspecific substrate (in the point-dipole approximation) using the reaction field method. Hence, it does not give explicit information regarding the radiative back electron transfer reaction. (a) Von Lippert, E. Z. Electrochem. 1957, 61, 962. (b) Mataga, N.; Kaifu, Y.; Koizumi, M. Bull. Chem. Soc. Jpn. 1956, 29, 465, and references cited therein.
    • (1956) Bull. Chem. Soc. Jpn. , vol.29 , pp. 465
    • Mataga, N.1    Kaifu, Y.2    Koizumi, M.3
  • 46
    • 0000065608 scopus 로고
    • and ref 44
    • 37.5 were taken from a minimum number of sources. Most values correspond to that reported by Weller et al.: Knibbe, H.; Rhem, D.; Weller, A. Ber. Bunsen-Ges. Phys. Chem. 1969, 73, 839, and ref 44. The reduction potentials of 1-methylnaphthalene and 9,10-dicyanoanthracene were taken from: Murov, S. L.; Carmicheal, I.; Hug, G. L. Handbook of Photochemistry, 2nd ed.; Marcel Dekker Inc.: New York, 1993.
    • (1969) Ber. Bunsen-Ges. Phys. Chem. , vol.73 , pp. 839
    • Knibbe, H.1    Rhem, D.2    Weller, A.3
  • 47
    • 0003924674 scopus 로고
    • Marcel Dekker Inc.: New York
    • 37.5 were taken from a minimum number of sources. Most values correspond to that reported by Weller et al.: Knibbe, H.; Rhem, D.; Weller, A. Ber. Bunsen-Ges. Phys. Chem. 1969, 73, 839, and ref 44. The reduction potentials of 1-methylnaphthalene and 9,10-dicyanoanthracene were taken from: Murov, S. L.; Carmicheal, I.; Hug, G. L. Handbook of Photochemistry, 2nd ed.; Marcel Dekker Inc.: New York, 1993.
    • (1993) Handbook of Photochemistry, 2nd Ed.
    • Murov, S.L.1    Carmicheal, I.2    Hug, G.L.3
  • 56
    • 0004249665 scopus 로고
    • Wiley & Sons: New York, Chapter6
    • Marcus, T. Ion Salvation; Wiley & Sons: New York, 1985; Chapter 6.
    • (1985) Ion Salvation
    • Marcus, T.1
  • 57
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    • Whery, E. L., Ed.; Plenum Press: New York, Chapter 5, and references therein.
    • For a detailed discussion on the interpretation of the temperature effect on the quenching rate constants, see: Froehlich, P.; Whery, E. L. In Modern Fluorescence Spectroscopy; Whery, E. L., Ed.; Plenum Press: New York, 1976; Chapter 5, and references therein. See also: Chow, Y. L.; Johansson, C. J. J. Phys. Chem. 1995, 99, 17566.
    • (1976) Modern Fluorescence Spectroscopy
    • Froehlich, P.1    Whery, E.L.2
  • 58
    • 0000118485 scopus 로고
    • For a detailed discussion on the interpretation of the temperature effect on the quenching rate constants, see: Froehlich, P.; Whery, E. L. In Modern Fluorescence Spectroscopy; Whery, E. L., Ed.; Plenum Press: New York, 1976; Chapter 5, and references therein. See also: Chow, Y. L.; Johansson, C. J. J. Phys. Chem. 1995, 99, 17566.
    • (1995) J. Phys. Chem. , vol.99 , pp. 17566
    • Chow, Y.L.1    Johansson, C.J.2
  • 60
    • 85033177469 scopus 로고    scopus 로고
    • note
    • -et should be incorrect, making eq 7 entirely inadequate. However, it does not seem the case for the D/A systems studied here.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.