Stereoelectronic influence of the type of bifunctional ansa- monocyclopentadienyldimethylsilylamido ligand on the molecular structures displayed by zirconium dichloride and 1,4-diphenylbutadiene complexes

Inorganic Chemistry

Volumn 43, Issue 13, 2004, Pages 3976-3987

  Braun, Leonie F ^a   Dreier, Thorsten ^a   Christy, Matthew ^a   Petersen, Jeffrey L ^a  

^a WEST VIRGINIA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1,3 BUTADIENE DERIVATIVE; 1,4 DIPHENYLBUTADIENE DERIVATIVE; AMIDE; CYCLOPENTADIENYLDIMETHYLSILYLAMIDE; LIGAND; MAGNESIUM DERIVATIVE; UNCLASSIFIED DRUG; ZIRCONIUM DERIVATIVE;

ARTICLE; CHELATION; CHEMICAL BOND; CHEMICAL STRUCTURE; ELIMINATION REACTION; ENVIRONMENTAL TEMPERATURE; ISOMERISM; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SOLID STATE; STEREOCHEMISTRY; STRUCTURE ANALYSIS; TEMPERATURE DEPENDENCE;

EID: 2942737272     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic040001i     Document Type: Article

References (53)

1. (a) Shapiro, P. J.; Cotter, W. D.; Schaefer, W. P.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 1994, 116, 4623-4640.
2. (b) Piers, W. E.; Shapiro, P. J.; Bunel, E. E.; Bercaw, J. E. Synlett 1990, 2, 74-84.
3. (c) Shapiro, P. J.; Bunel, E. E.; Schaefer, W. P.; Bercaw, J. E. Organometallics 1990, 9, 867-869.
4. Stevens, J. C.; Timmers, F. J.; Rosen, G. W.; Knight, G. W.; Lai, S. Y. Eur. Patent Appl. EP 0 416 815 A2, 1991.
5. Canich, J. M. Eur. Patent Appl. EP 0 420 436 A1, 1991.
6. McKnight, A. L.; Masood, M. A.; Waymouth, R. M.; Straus, D. A. Organometallics 1997, 16, 2879-2885.
7. (a) Okuda, J. Chem. Ber. 1990, 123, 1649-1651.
8. (b) Okuda, J.; Schattenmann, F. J.; Wocadlo, S.; Massa, W. Organometallics 1995, 14, 789-795.
9. (c) Okuda, J. In Metallocenes; Togni, A., Halterman, R. L., Eds.; Wiley-VCH: Weinheim, 1999; pp 415-450 and references therein.
10. Strickler, J. R.; Power, J. M. U.S. Patent 5,359,105, 1994.
11. (a) Hughes, A. K.; Meetsma, A.; Teuben, J. H. Organometallics 1993, 12, 1936-1945.
12. (b) Sinnema, P.-J.; van der Veen, L.; Spek, A. L.; Veldman, N.; Teuben, J. H. Organometallics 1997, 16, 4245-4247.
13. Hermmann, W. A.; Morawietz, M. J. A. J. Organomet. Chem. 1994, 482, 169-181.
14. Carpenetti, D. W.; Kloppenburg, L.; Kupec, J. T.; Petersen, J. L. Organometallics 1996, 15, 1572-1581.
15. Leung, W.-P.; Song, F.-Q.; Zhou, Z.-Y.; Xue, F.; Mak, T. C. W. J. Organomet. Chem. 1999, 575, 232-241.
16. Kloppenburg, L. Ph.D. dissertation, University of Münster, 1997.
17. Brenner, S.; Kempe, R.; Arndt, P. Z. Anorg. Allg. Chem. 1995, 621, 2021-2024.
18. (a) Sinnema, P.-J.; Liekelema, K.; Stall, O. K. B.; Hessen, B.; Teuben, J. H. J. Mol. Catal. 1998, 128, 143-153.
19. (b) Sinnema, P.-J. Ph.D. dissertation, University of Gröningen, 1999.
20. (a) Devore, D. D.; Timmers, F. J.; Hasha, D. L.; Rosen, R. K.; Marks, T. J.; Deck, P. A.; Stern, C. L. Organometallics 1995, 14, 3132-3134.
21. (b) Devore, D. D.; Stevens, J. C.; Timmers, F. J.; Rosen, R. K. U.S. Patent 5,539,068, 1996.
22. (a) Cowley, A. H.; Hair, G. S.; McBumett, B. G.; Jones, R. A. J. Chem. Soc., Chem. Commun. 1999, 437-438.
23. (b) Hair, G. S.; Jones, R. A.: Cowley, A. H.; Lynch, V. Inorg. Chem. 2001, 40, 1014-1019.
24. Dahlmann, M.; Schottek, J.; Fröhlich, R.; Kunz, D.; Nissinen, M.; Erker, G.; Fink, G.; Kleinschmidt, R. J. Chem. Soc., Dalton Trans. 2000, 1881-1886.
25. Strauch, J. W.; Petersen, J. L. Organometallics 2001, 20, 2623-2630.
26. (a) Gassman, P. G.; Winter, C. H. J. Am. Chem. Soc. 1988, 110, 6130-6135.
27. (b) Richardson, D. E.; Alameddin, N. G.; Ryan, M. F.; Hayes, T.; Eyler, J. R.; Siedle, A. R. J. Am. Chem. Soc. 1996, 118, 11244-11253.
28. Pupi, R. M.; Coalter, J. N.; Petersen, J. L. J. Organomet. Chem. 1995, 497, 17-25.
29. Yue, N.; Hollink, E.; Guerin, F.; Stephan, D. W. Organometallics 2001, 20, 4424-4433.
30. SpinWorks, version 2.1 (Professor Kirk Marat, Department of Chemistry, University of Manitoba, Manitoba, Canada R3T 2N2), permits off-line processing of 1D and 2D NMR data and may be used for the simulation and analysis of complex second-order spectra and dynamic NMR spectral data.
31. Benn, R.; Schroth, G. J. Organomet. Chem. 1982, 228, 71-85.
32. (a) Erker, G.; Krüger, C.; Müller, G. Adv. Organomet. Chem. 1985, 24, 1-39.
33. (b) Erker, G.; Engel, K.; Krüger, C.; Müller, G. Organometallics 1984, 3, 128-133.
34. (c) Krüger, C.; Müller, G.; Erker, G.; Dorf, U.; Engel, K. Organometallics 1985, 4, 215-223.
35. (d) Erker, G.; Engel, K.; Krüger, C.; Chiang, A.-P. Chem. Ber. 1982, 115, 3311-3323.
36. (e) Erker, G.; Wicher, J.; Engel, K.; Rosenfeldt, F.; Dietrich, W.; Krüger, C. J. Am. Chem. Soc. 1980, 102, 6346-6348.
37. Lappert, M. F.; Martin, T. R.; Atwood, J. L.; Hunter, W. E. J. Chem. Soc., Chem. Commun. 1980, 476-477.
38. Fryzuk, M. D.; Haddad, T. S.; Rettig, S. J. Organometallics 1989, 8, 1723-1732.
39. Wreford, S. S.; Whitney, J. F. Inorg. Chem. 1981, 20, 3918-3924.
40. (a) Yasuda, H.; Nakamura, A.; Kai, Y.; Kasai, N. Topics in Physical Organometallic Chemistry; Freund Publishing House: Tel Aviv, 1987; Vol. 2.
41. (b) Yasuda, H.; Tatsumi, K.; Okamoto, T.; Mashima, K.; Lee, K.; Nakumura, A.; Kai, Y.; Kanehisa, N.; Kasai, N. J. Am. Chem. Soc. 1985, 107, 2410-2422.
42. Hunter, W. E.; Hrncir, D. C.; Vann Bynum, R.; Penttila, R. A.; Atwood, J. L. Organometallics 1983, 2, 750-755.
43. Atwood, J. L.; Hunter, W. E.; Hrncir, D. C.; Samuel, E.; Alt, H.; Rausch, M. D. Inorg. Chem. 1975, 14, 1757-1762.
44. 1H NMR spectrum features two multiplets centered at δ 5.01; 4.01 for the meso protons and two pseudo doublets of doublets centered at δ 3.56; 3.32 for the anti protons of the cis-1,4- diphenylbutadiene ligand. Morgan, J. B.; Petersen, J. L, unpublished results.
45. Gordon, A. J.; Ford, R. A. The Chemist's Companion; Wiley-Interscience: New York, 1972; pp 431-436.
46. Sekutowski, D. G.; Stucky, G. D. Inorg. Chem. 1975, 14, 2192-2199.
47. 2(N(H)-i-Pr).
48. Diamond, G. M.; Rodewald, S.; Jordan, R. F. Organometallics 1995, 14, 5-7.
49. Yasuda, H.; Kajihara, Y.; Mashima, K.; Nagasuna, K.; Lee, K.; Nakamura, A. Organometallics 1982, 1, 388-396.
50. XSCANS (version 2.0) is a diffractometer control system developed by Bruker AXS, Inc., Madison, WI.
51. The SMART 5.6 and SAINT 5/6.0 programs are part of the Bruker AXS crystallographic software package used for single-crystal data collection, reduction, and preparation.
52. SHELXTL-93 and SHELXTL 6.1 are crystallographic software packages developed by Professor G. Sheldrick, Institut fur Anorganische Chemie, University of Göttingen, D-37077 Göttingen, Germany, for Bruker AXS, Inc., Madison, WI.
53. 1/2, where n is the number of reflections and p is the total number of parameters that were varied during the last refinement cycle.