SnCl2/PdCl2-mediated aldehyde allylation in fully aqueous media

Tetrahedron Letters

Volumn 45, Issue 28, 2004, Pages 5525-5528

  Tan, Xiang Hui ^a   Hou, Yong Quan ^a   Shen, Bo ^a   Liu, Lei ^a,b   Guo, Qing Xiang ^a  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

^b Columbia University ^*  (United States)

Author keywords

Allylation; Aqueous medium; Palladium; SnCl2

Indexed keywords

ALCOHOL; ALDEHYDE; BROMIDE; CHLORIDE; PALLADIUM; TIN CHLORIDE;

ALLYLATION; AQUEOUS SOLUTION; ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; PROTON NUCLEAR MAGNETIC RESONANCE;

EID: 2942650544     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.05.066     Document Type: Article

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30. 3 catalyses, the Pd catalysis reported here is much more robust and efficient. Moreover, we believe that the Pd catalyzed allylation reaction is of special importance because the umpolung of π-palladium complexes has attracted considerable attention recently. (See: Solin N., Kjellgren J., Szabo K.J. Angew. Chem., Int. Ed. 42:2003;3656-3658. and references cited therein.)