Molecular interpretation of the main relaxations found in dielectric spectra of cellulose - Experimental arguments

Cellulose

Volumn 11, Issue 2, 2004, Pages 137-150

  Einfeldt, Jürgen ^a   Meißner, Dana ^a   Kwasniewski, Albert ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

Cellulose; Dielectric spectra; Molecular models

Indexed keywords

CORRELATION METHODS; CRYSTALLIZATION; DERIVATIVES; DIELECTRIC PROPERTIES; MOLECULAR WEIGHT; POLYSACCHARIDES;

DIELECTRIC SPECTROSCOPY; MOLECULAR MOTIONS; SEGMENTAL MOTION;

CELLULOSE;

CELLULOSE; CORRELATION; CRYSTALLIZATION; DIELECTRIC PROPERTIES; MOLECULAR WEIGHT; POLYSACCHARIDES;

CELLULOSE; DIELECTRIC PROPERTY; MOLECULAR STRUCTURE;

EID: 2942633554     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1023/B:CELL.0000025404.61412.d6     Document Type: Article

References (38)

1. Bradley S.A. and Carr S.H. 1976. Mechanical loss processes in polysaccharides. J. Polym. Sci. B - Polymer Phys. 14: 111-124.
2. Einfeldt J., Kwasniewski A., Klemm D., Dicke R. and Einfeldt L. 2000a. Analysis of the side group motion in O-acetyl-starch using regioselective 2-O-acetyl-starches by means of dielectric spectroscopy. Polymer 41: 9273-9281.
3. Einfeldt J., Meißner D. and Kwasniewki A. 2000b. Comparison of the molecular dynamics of celluloses and related polysaccharides in wet and dried states by means of dielectric spectroscopy. Macromol. Chem. Phys. 201: 1969-1975.
4. Einfeldt J., Meißner D., Kwasniewski A. and Einfeldt L. 2001a. Dielectric spectroscopic analysis of wet and well dried starches in comparison with other polysaccharides. Polymer 42: 7049-7062.
5. Einfeldt J., Meißner D. and Kwasniewski A. 2001b. Polymer dynamics of cellulose and other polysaccharides in solid state - secondary dielectric relaxation processes. Prog. Polym. Sci. 26: 1419-1472.
6. Einfeldt J., Einfeldt L., Dicke R., Klemm D. and Kwasniewski A. 2002a. The influence of the type of substituents on the polymer dynamics of different regioselective 2-O-esters of starch using dielectric spectroscopy. Polymer 43: 1391-1397.
7. Einfeldt J., Heinze Th., Liebert T. and Kwasniewski A. 2002b. Influence of the p-toluenesulphonylation of cellulose on the polymer dynamics investigated by dielectric spectroscopy. Carbohydr. Polym. 49: 357-375.
8. Einfeldt J. and Kwasniewski A. 2002c. Characterization of different types of cellulose by dielectric spectroscopy. Cellulose 9: 225-238.
9. Einfeldt J., Meißner D. and Kwasniewski A. 2003. Contribution to the molecular origin of the dielectric relaxation processes in polysaccharides - the high temperature range. J. Non-Cryst. Solids 320: 40-55.
10. Evans J.N.S. 1995. Biomolecular NMR Spectroscopy. Oxford University Press, Oxford, UK, pp. 35 ff and 381 ff.
11. Franz G. and Blaschek W. 1990. Cellulose. In: Dey M.P. (ed.), Methods of Plant Biochemistry. Vol. 2, Polysaccharides. Academic Press, London, pp. 312-317.
12. Gruber E., Weigert J. and Schneider C. 1999. Possibility of assessment of the hornification effect (in German). PTS-Symposium - Dresden, pp. 30 ff.
13. Havriliak S. and Negami S. 1966. A complex plane analysis of alpha-dispersion of some polymeric systems. J. Polym. Sci. C14: 99-107.
14. Havrilaik S. Jr. and Negami S. 1969. On the equivalence of dielectric and mechanical dispersion in poly n-hexyl methacrylate. Br. J. Appl. Phys. (J. Phys. D) 2: 1301-1315.
15. Heymann B. and Grubmüller H. 1999. Chair - Boat transitions and side groups affect the stiffness of polysaccharides. Chem. Phys. Lett. 305: 202-208.
16. 13C NMR investigation of molecular ordering in celluloses. Carbohydr. Res. 302: 19-25.
17. Le Botlan D., Rugraff Y., Martin C. and Colonna P. 1998. Quantitative determination of bound water in wheat starch by time domain NMR spectroscopy, Carbohydr. Res. 308: 29-36.
18. Liedermann K. and Lapcík L. Jr. 2000. Dielectric relaxation in hydroxyethyl cellulose. Carbohydr. Polym. 42: 369-374.
19. Mcdonald J.R. and Franceschetti D.R. 1978, Theory of small-signal ac response of solids and liquids with recombining mobile charge. J. Chem. Phys. 68: 1614-1637.
20. Meißner D., Einfeldt J. and Kwasniewski A. 2000. Contribution to the molecular origin of the dielectric relaxation processes in polysaccharides - the low temperature range. J. Non-Cryst. Sol. 275: 100-209.
21. Meißner D., Einfeldt L. and Einfeldt J. 2001. Dielectric relaxation analysis of cellulose oligomers and polymers in dependence on their chain length. J. Polym. Sci.- Polym. Phys. 39: 2491-2500.
22. Meißner D. and Einfeldt J. 2004. Dielectric relaxation analysis of starch oligomers and polymers with respect to their chain length. J. Polym. Sci. - Polym. Phys. 42: 188-197.
23. Mikahailov G.P., Artyukhov A.I. and Shevelev A. 1969. Studying of molecular motion in cellulose and its derivatives by dielectricand NMR methods. J. Polym. Sci. (USSR) 11: 628-639.
24. Montes H., Mazeau K. and Cavaillé J.Y. 1997. Secondary mechanical relaxations in amorphous cellulose. Macromolecules 30: 6977-6984.
25. Montes H., Mazeau K. and Cavaillé J.Y. 1998. The mechanical β relaxation in amorphous cellulose. J. Non-Cryst. Solids 235: 416-421.
26. Montes H. and Cavaillé J.Y. 1999. Secondary dielectric relaxations in dried amorphous cellulose and dextrane. Polymer 40: 2649-2657.
27. 1H-NMR relaxation of water molecules in aqueous microcrystalline cellulose suspension systems and their viscosity. Cellulose 5: 231-247.
28. Radloff D., Boeffel C. and Spiess H.W. 1996. Cellulose and cellulose/poly(vinyl alcohol) blends. 2. Water organization revealed by solid-state NMR spectroscopy. Macromolecules 29: 1528-1534.
29. Saad G.R., Sakamoto M. and Furuhata K. 1996. Dielectric study of β relaxation in some cellulosic substances. Polymer Int. 41: 293-299.
30. Scandola M. and Cecconalli G. 1985. Viscoelaslic properties of cellulose derivatives: 1. Cellulose acetate. Polymer 26: 1953-1957.
31. Schmidt-Rohr K. and Spiess H.W. 1994. Multidimensional Solid-state NMR and Polymers, Academic Press, London, pp. 102 ff.
32. Schütt H.J. and Gerdes E. 1992. Space-charge relaxation in ionicly conducting oxide glasses I Mode and frequency response. J. Non-Cryst. Sol. 144: 11-13.
33. Sillars R.W. 1937. The properties of dielectrics containing semiconducting particles of various shapes. J. Inst. Electr. Eng. 80: 378-394.
34. Tang H.-R., Godward J. and Hill B. 2000. The distribution of water in native starch granules - a multinuclear NMR study. Carbohydr. Polym. 43: 375-387.
35. 1H-NMR. Langmuir 17: 2694-2702.
36. Van Beek L.K.H. 1967. Dielectric behaviour of heterogeneous systems. Prog. Dielectr. 7: 69-114.
37. Widenhorn R., Rest A. and Bodegom E. 2002. The Meyer-Neldel rule for a property determined by two transport mechanisms. J. Appl. Phys. 91: 6524-6527.
38. Williams G. 1998. Theory of dielectric properties. In: Runt J.P. and Fitzgerald J.J. (eds), Dielectric Spectroscopy of Polymeric Materials. American Chemical Society, Washington, DC, pp. 16 ff.