On the nature of solvent effects on redox properties

Journal of Physical Chemistry A

Volumn 108, Issue 21, 2004, Pages 4805-4811

  Svith, Heidi ^a   Jensen, Henrik ^a   Almstedt, Johan ^b   Andersson, Paula ^b   Lundbäck, Thomas ^c   Daasbjerg, Kim ^a   Jonsson, Mats ^b  

^a AARHUS UNIVERSITY   (Denmark)

^b ROYAL INSTITUTE OF TECHNOLOGY   (Sweden)

^c BIOVITRUM AB   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ACETONITRILE; CYCLIC VOLTAMMETRY; ENTROPY; FREE ENERGY; HYDROGEN BONDS; METHANOL; REACTION KINETICS; REDOX REACTIONS; SOLVENTS;

LINEAR FREE ENERGY RELATIONSHIP (LFER); LINEAR SOLVATION ENERGY RELATIONSHIP (LSER); SOLVATION; SOLVENT EFFECTS;

FREE RADICAL REACTIONS;

EID: 2942534739     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp031268q     Document Type: Article

References (33)

1. Reichardt, C. In Solvents and Solvent Effects in Organic Chemistry, 2nd ed.; VCH: Weinheim, Germany, 1988.
2. Shalev, H.; Evans, D. H. J. Am. Chem. Soc. 1989, 111, 2667.
3. Jonsson, M.; Houmam, A.; Jocys, G.; Wayner, D. D. M. J. Chem. Soc., Perkin Trans. 2, 1999, 425.
4. Pearson, R. G. J. Am. Chem. Soc. 1986, 108, 6109.
5. Trasatti, S. Pure Appl. Chem. 1986, 58, 955.
6. There are uncertainties with respect to liquid junction potentials and the standard state of the electron and therefore the term "absolute potential" is not strictly correct. However, to avoid confusion we have adopted the terminology as suggested by Pearson (ref 4).
7. Baker, M. V.; Kraatz, H.-B.; Quail, J. W. New. J. Chem. 2001, 25, 427.
8. Sahami, S.; Weaver, M. J. J. Solution Chem. 1981, 10, 199.
9. Marcus, Y. Chem. Soc. Rev. 1993, 409 and references therein.
10. Kamlet, M. J.; Abboud, J.-L. M.; Abraham, M. H.; Taft, R. W. J. Org. Chem. 1983, 48, 2877.
11. Fawcett, W. R. In Quantitative Treatments of Solute/Solvent Interactions; Politzer, P., Murray, J. S., Eds.; Elsevier, Amsterdam, 1994; pp 183-212.
12. Koppel, I. A.; Palm, V. A. In Advances in Linear Free Energy Relationships; Chapman, N. B., Shorter, J. Eds.; Plenum: London, 1972; Chapter 5.
13. Drago, R. S. J. Chem. Soc., Perkin Trans. 2 1992, 1827.
14. Drago, R. S.; Hirsch, M. S.; Ferris, D. C.; Chronister, C. W. J. Chem. Soc., Perkin Trans, 2 1994, 219.
15. Svaan, M.; Parker, V. D. Acta Chem. Scand. B 1981, 35, 559.
16. Svaan, M.; Parker, V. D. Acta Chem. Scand. B 1982, 36, 351.
17. Svaan, M.; Parker, V. D. Acta Chem. Scand. B 1982, 36, 357.
18. Svaan, M.; Parker, V. D. Acta Chem. Scand. B 1982, 36, 365.
19. Svaan, M.; Parker, V. D. Acta Chem. Scand. B 1984, 38, 751.
20. Svaan, M.; Parker, V. D. Acta Chem. Scand. B 1984, 38, 759.
21. Svaan, M.; Parker, V. D. Acta Chem. Scand. B 1984, 38, 767.
22. Arnett, E. M.; Venimadhavan, S. J. Am. Chem. Soc. 1991, 113, 6967.
23. Barton, A. F. M. Chem. Rev. 1975, 75, 731.
24. Eberson, L.; Hartshorn, M. P.; Persson, O. J. Chem. Soc., Perkin Trans. 2 1997, 195.
25. Eberson, L.; Hartshorn, M. P.; Radner, F.; Persson, O. J. Chem. Soc., Perkin Trans. 2 1998, 59.
26. Krygowski, T. M.; Fawcett, W. R. J. Am. Chem. Soc. 1975, 97, 2143.
27. NIST Standard Reference Database Number 69, July 2001 Release.
28. Yee, E. L.; Cave, R. J.; Guyer, K. L.; Tyma, P. D.; Weaver, M. J. J. Am. Chem. Soc. 1979, 101, 1131.
29. Söderholm, S.; Werner; H. P.; Krzystek, J.; von Schütz, J. U.; Hellberg, J.; Ahlgren, G. Synth. Met. 1987, 20, 15.
30. Daasbjerg, K.; Pedersen, S. U.; Lund, H. Acta Chem. Scand. 1989, 43, 876.
31. Wizinger, R.; Losinger, S.; Ulrich, P. Helv. Chim. Acta 1956, 39, 5.
32. Wizinger, R.; Ulrich, P. Helv. Chim. Acta 1956, 39, 207.
33. Katritzky, A. R.; Grzeskowiak, N. E.; Eweiss, N. F.; Eisherbini, E. A. J. Chem. Soc., Perkin Trans. 1 1983, 497.