Adsorption and diffusion behavior of ethane and ethylene in sol-gel derived microporous silica

Adsorption

Volumn 11, Issue 5-6, 2005, Pages 491-499

  Dewitt, A Conan ^a   Herwig, K W ^b   Lombardo, Stephen J ^a  

^a University of Missouri   (United States)

^b OAK RIDGE NATIONAL LABORATORY   (United States)

Author keywords

Adsorbents; Diffusion; Gas separation

Indexed keywords

GAS SEPARATION; MICROPOROUS SILICA; SURFACE AREA; TETRAETHYL ORTHOSILICATES;

ADSORBENTS; DIFFUSION; ENTHALPY; ENTROPY; ETHANE; ETHYLENE; MICROPOROUS MATERIALS; SILICA; SOL-GELS;

ADSORPTION;

EID: 29144445802     PISSN: 09295607     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10450-005-5608-1     Document Type: Article

References (38)

1. Achyara, M. and H.C. Foley, "Transport in Nanoporous Carbon Membranes: Experiments and Analysis," AIChE J., 46, 911-922 (2000).
2. Arends, B., K.O. Prins, and N.J. Trappeniers, "Self-Diffusion in Gaseous and Liquid Ethylene," Physica, 107A, 307-318 (1981).
3. Asaeda, M., A. Yamamichi, M. Satoh, and M. Kamakura, "Preparation of Porous Silica Membranes for Separation of Propylene/Propane Gaseous Mixtures," in Inorganic Membranes: ICIM3'94: Proceedings of the Third International Conference on Inorganic Membranes: Worcester, MA, July 10-14, 1994.
4. Bée, M., Quasielastic Neutron Scattering, Adam Hilger, Bristol, 1988.
5. Benes, N.E., H. Jobic, and H. Verweij, "Quasi-Elastic Neutron Scattering Study of the Mobility of Methane in Microporous Silica," Microporous & Mesoporous Mater., 43, 147-152 (2001).
6. Bradley, K.P., S.H. Chen, T.O. Brun, R. Kleb, W.A. Loomis, and J.M. Newsam, "The Design and Performance of QENS, a Medium Resolution, Inverted Geometry, TOF Quasielastic and Inelastic Spectrometer at IPNS," Nucl. Instr. and Meth., A240, 78-89 (1988).
7. Choudhary, V.R. and S. Mayadevi, "Adsorption of Methane, Ethane, Ethylene, and Carbon Dioxide on X, Y, L, and M Zeolites Using a Gas Chromatography Pulse Technique," Separation Sci. & Technol., 28, 1595-1607 (1993a).
8. Choudhary, V.R. and S. Mayadevi, "Adsorption of Methane, Ethane, Ethylene, and Carbon Dioxide on High Silica Pentasil Zeolites and Zeolite Like Materials Using Gas Chromatography Pulse Technique," Separation Sci. & Technol., 28, 2197-2209 (1993b).
9. De Lange, R.S. A., J.H.A. Hekkink, K. Keizer, and A.J. Burggraaf, "Microstructural Properties of Non-Supported Microporous Ceramic Membrane Top-Layers Obtained by the Sol-Gel Process," J. Non-Cryst. Sol., 195, 203-217 (1996).
10. De Lara, E.C. and R. Kahn, "Diffusivity of Hydrogen and Methane Molecules in A Zeolites: Neutron Scattering Measurements and Comparison," Zeolites, 12, 256-260 (1992).
11. Elferink, W.J., B.N. Nair, R.M. de Vos, K. Keizer, and H. Verweij, "Sol-Gel Synthesis and Characterization of Microporous Silica Membranes: II. Tailor-Making Porosity," J. Coll. Interf. Sci., 180, 127-134 (1996).
12. Gaven, J.V., W.H. Stockmayer, and J.S. Waugh, "Self-Diffusion and Impurity-Controlled Proton Relaxation in Liquid Ethane," J. Chem. Phys., 37, 1188-1191 (1962).
13. Gergidis, L.N., D.N. Theodorou, and H. Jobic, "Dynamics of n-Butane-Methane Mixtures in Silicalite, Using Quasielastic Neutron Scattering and Molecular Dynamics Simulations," J. Phys. Chem. B, 104, 5541-5552 (2000).
14. Green, D.W. (Ed.), Perry's Chemical Engineers' Handbook, McGraw-Hill, New York, 1997.
15. Ho, W.S. and K.K. Sirkar (Eds.), Membrane Handbook, Van Nostrand Reinhold, New York, 1992.
16. Hong, U., J. Kärger, and H. Pfeifer, "Selective Two-Component Self-Diffusion Measurement of Adsorbed Molecules by Pulsed Field Gradient Fourier Transform NMR," J. Am. Chem. Soc., 113, 4812-4815 (1991).
17. Hsieh, H.P., Inorganic Membranes for Separation and Reaction, Elsevier, New York, 1996.
18. Jobic, H., "Diffusion Studies Quasi-Elastic Neutron Scattering," in Recent Advances in Gas Separation by Microporous Ceramic Membranes, N.K. Kanellopoulos, ed., Elsevier, New York, 109 (2000).
19. Jobic, H., M. Bee, J. Karger, C. Balzer, and A. Julbe, "Measurement of the Diffusivity of Benzene in Microporous Silica by Quasi-Elastic Neutron Scattering and NMR Pulsed-Field Gradient Technique," Adsorption, 1, 197-201 (1995a).
20. Jobic, H., M. Bee, J. Karger, R.S. Vartapetian, C. Balzer, and A. Julbe, "Mobility of Cyclohexane in a Microporous Silica Sample: A Quasi-Elastic Neutron Scattering and NMR Pulsed-Field Gradient Technique Study," J. Membrane Sci., 108, 71-78 (1995b).
21. Jobic, H., M. Bee, and G.J. Kearley, "Dynamics of Ethane and Propane In Zeolite ZSM-5 Studied by Quasi-Elastic Neutron Scattering," Zeolites, 12, 146-151 (1992).
22. Jobic, H., H. Ernst, W. Heink, J. Karger, A. Tuel, and M. Bée, "Diffusion of Ammonia in Silicalite Studied by QENS and PFG NMR," Microporous & Mesoporous Mater., 26, 67-75 (1998).
23. Jobic, H., A.N. Fitch, and J. Combet, "Diffusion of Benzene in NaX and NaY Zeolites Studied by Quasi-Elastic Neutron Scattering," J. Phys. Chem. B, 104, 8491-8497 (2000).
24. Jobic, H., K. Hahn, J. Kärger, M. Bée, A. Tuel, M. Noack, I. Girnus, and G.J. Kearley, "Unidirectional and Single-File Diffusion of Molecules in One-Dimensional Channel Systems. A Quasi-Elastic Neutron Scattering Study," J. Phys. Chem B, 101, 5834-5841 (1997).
25. Jobic, H., J. Karger, and M. Bée, "Simultaneous Measurement of Self- and Transport-Diffusivities in Zeolites," Phys. Rev. Lett., 82, 4260-4263 (1999).
26. Kärger, J., "Measurement of Diffusion in Zeolites - A Never Ending Challenge?," Adsorption, 9, 29-35 (2003).
27. 3 Membranes," J. Membrane Sci., 39, 285-300 (1988).
28. Lowel, S. and J.E. Shields, Powder Surface Area and Porosity, Chapman Hall, New York, 1984.
29. Nair, B.N., K. Keizer, W.J. Elferrink, M.J. Gilde, Verweij, H., and A.J. Burggraaf, "Synthesis, Characterization and Gas Permeation Studies on Microporous Silica and Alumina-Silica Membranes for Separation of Propane and Propylene," J. Membrane Sci., 116, 161-169 (1996a).
30. Nair, B.N., K. Keizer, H. Verweij, and A.J. Burggraaf, "Surface Selective Approach to Separation of Propylene from Propane," Separation Sci. and Technol., 31, 1907-1914 (1996b).
31. Nivarthi, S.S. and A.V. McCormick, "Diffusion of Coadsorbed Molecules in Zeolites. A pulsed Field Gradient NMR Study," J. Phys. Chem., 99, 4661-4666 (1995).
32. 4 Permeation Through MFI Zeolites," J. of Membrane Sci., 160, 115-125 (1999).
33. Ruthven, D.M., Principles of Adsorption and Adsorption Processes, John Wiley, New York, 1984.
34. Snurr, R.Q. and J. Kaerger, "Molecular Simulations and NMR Measurements of Binary Diffusion in Zeolites," J. Phys. Chem. B, 101, 6469-6473 (1997).
35. Springer T., in Quasielastic Neutron Scattering for the Investigation of Diffusive Motions in Solids and Liquids, G. Hohler, Ed., Springer Tracts in Modern Physics 64, Springer-Verlag, Berlin, pp. 1-100 (1972).
36. Stockmeyer, R. "Diffusive Motion of Hydrogen in Mordenite Studied by Quasi-Elastic Neutron Scattering," Zeolites, 12, 251-255 (1992).
37. Uhlhorn, R.J. R., H.B.J. Huis In't Veld, K. Keizer, and A.J. Burggraaf, "High Permselectivities of Microporous Silica-Modified γ-Alumina Membranes," J. Mat. Sci. Lett., 8, 1135-1138 (1989).
38. Yang, R.T. and E.S. Kikkinides, "New Sorbents for Olefin/Paraffin Separations by Adsorption Via π-Complexation," AIChE J., 41, 509-517 (1995).