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Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication No. CCDC 277690. Copies of the data can be obtained free of charge by application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK. Fax: int. code+ 44(1223)336-033. E-mail: deposit@ccdc.cam.ac.uk.
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Complex 1, as well as 3, reacts in halogenated solvents that therefore could not be used in the low-temperature NMR experiments.
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2 dissociation was observed at room temperature when 2 was dissolved in 1,2-dichloroethane or when 3 was dissolved in halogenated solvents.
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