Experimental evidence for a significant homometallic catalytic binuclear elimination reaction: Linear-quadratic kinetics in the rhodium catalyzed hydroformylation of cyclooctene

Journal of Catalysis

Volumn 237, Issue 1, 2006, Pages 67-78

  Liu, Guowei ^a   Li, Chuanzhao ^a   Guo, Liangfeng ^a   Garland, Marc ^a  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

Catalytic binuclear elimination reaction; In situ quantitative FTIR spectroscopy; Linear quadratic kinetics; Rhodium catalyzed hydroformylation

Indexed keywords

ENTROPY; INFRARED SPECTROSCOPY; KETONES; RHODIUM;

CATALYTIC BINUCLEAR ELIMINATION REACTION; LINEAR-QUADRATIC KINETICS; RHODIUM-CATALYZED HYDROFORMYLATION;

REACTION KINETICS;

EID: 28844503069     PISSN: 00219517     EISSN: 10902694     Source Type: Journal    
DOI: 10.1016/j.jcat.2005.09.033     Document Type: Article

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