Staggered to eclipsed conformational rearrangement of [Co 2(CO)6(PPh3)2] in the solid state: An X-ray diffraction study at high pressure and low temperature

Angewandte Chemie - International Edition

Volumn 44, Issue 47, 2005, Pages 7736-7739

  Casati, Nicola ^a   Macchi, Piero ^a   Sironi, Angelo ^a  

^a UNIVERSITY OF MILAN   (Italy)

Author keywords

Carbonyl ligands; High pressure chemistry; Phase transitions; X ray diffraction

Indexed keywords

CARBONYLATION; CHARACTERIZATION; CONFORMATIONS; CRYSTALLINE MATERIALS; HIGH PRESSURE EFFECTS; PHASE TRANSITIONS; TRANSITION METALS; X RAY DIFFRACTION ANALYSIS;

CARBONYL LIGANDS; ECLIPSED ARRANGEMENT; HIGH-PRESSURE CHEMISTRY; STRUCTURAL EVIDENCE;

COBALT COMPOUNDS;

EID: 28744437104     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502241     Document Type: Article

References (11)

1. For example, see C. M. Edwards, I. S. Butler, Coord. Chem. Rev. 2000, 199, 1-53.
2. P. Macchi, A. Sironi, Coord. Chem. Rev. 2003, 238/239, 383-412.
3. D. M. Adams, P. D. Hatton, A. C. Shaw, J. Phys. Condens. Matter 1991, 3, 6145.
4. P. Macchi, L. Garlaschelli, S. Martinengo, A. Sironi, Inorg. Chem. 1998, 37, 6263.
5. Details for all structures are available as Supporting Information. CCDC 276054-276064 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
6. I. Dance in The Crystal as Supramolecular Entity (Ed.: G. R. Desiraju), Wiley, Chichester, 1995.
7. The reversibility was confirmed by probing the crystal after the pressure was completely released.
8. + salt,
9. H. Borrmann, A. M. Pirani, G. J. Schrobilgen, Acta Crystallogr. Sect. C 1997, 53, 1007).
10. A detailed explanation for this behavior can be found in A. Sironi, Metal Clusters in Chemistry, Vol. 2 (Eds.: P. Braunstein, L. A. Oro, P. R. Raithby), Wiley-VCH, Weinheim, 1999, pp. 937-959.
11. A. Dawson, D. R. Allan, S. Parsons, M. Ruf, J. Appl. Crystallogr. 2004, 37, 410.