A facile and efficient deoxygenation of amine-N-oxides with Mo(CO) 6

Tetrahedron Letters

Volumn 47, Issue 1, 2006, Pages 125-126

  Yoo, Byung Woo ^a   Choi, Jin Woo ^a   Yoon, Cheol Min ^a  

^a Korea University   (South Korea)

Author keywords

Amine; Amine N oxides; Deoxygenation; Mo(CO)6

Indexed keywords

ALCOHOL; AMINE; MOLYBDENUM COMPLEX; OXIDE;

ARTICLE; DEOXYGENATION; REACTION ANALYSIS;

EID: 28544436328     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2005.10.143     Document Type: Article

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27. 6 (264 mg, 1.0 mmol). The mixture was refluxed for 2 h and monitored by TLC. After completion of the reaction, the resulting mixture was concentrated under reduced pressure, extracted with ether, concentrated and the residue was purified by silica gel column chromatography (hexane/ethyl acetate = 1:1) to afford 4-cyanopyridine (99 mg, 95%).