Highly selective photo-catalytic dimerization of α-methylstyrene by a novel palladium complex with photosensitizing ruthenium(II) polypyridyl moiety

Chemical Communications

Volumn , Issue 43, 2005, Pages 5468-5470

  Inagaki, Akiko ^a   Edure, Shinichi ^a   Yatsuda, Shinichi ^a   Akita, Munetaka ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

2,4 DIPHENYL 4 METHYL 1 PENTENE; ALPHA METHYLSTYRENE; BENZENE DERIVATIVE; PALLADIUM COMPLEX; PYRIDINE DERIVATIVE; RUTHENIUM DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; DIMERIZATION; LIGHT IRRADIANCE; PHOTOCATALYSIS; PHOTOSENSITIZATION;

EID: 28044455218     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b508013d     Document Type: Article

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34. 106Pd}.
35. 13C NMR, and ESI-MS spectral data are given as Electronic supplementary information.
36. Although the formation of C was observed under the dark condition, the dimer 4 did not form over a prolonged reaction time.
37. When the formation rate of C from A was compared between the irradiated and dark conditions, the rate under irradiation was nearly as twice as fast compared to that under the dark condition.