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28044456248
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Cimpoesu, F.6
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19
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28044451922
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note
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The +1 oxidation state is generally more stable than the +3 oxidation state for T1, and thus E refers only to B, Al, Ga, and In in this work.
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24
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1542269152
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R. J. Baker, C. Jones, M. Kloth, D. P. Mills, New J. Chem. 2004, 28, 207.
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Baker, R.J.1
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25
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1642439198
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C. L. B. Macdonald, A. M. Corrente, C. G. Andrews, A. Taylor, B. D. Ellis, Chem. Commun. 2004, 250.
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Macdonald, C.L.B.1
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Taylor, A.4
Ellis, B.D.5
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26
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28044441612
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3. A total of 23053 reflections (1.85 ≤ θ ≤ 25.00°) were collected of which 4413 were unique (R(int) = 0.0699); R1 = 0.0930; wR2 = 0.1704; GOF = 1.385; CCDC-280061-280063 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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28
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28044434021
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http://www.webelements.com.
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29
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28044461196
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note
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CSD range for terminal In-Cl bonds: 2.266-2.893 Å, average 2.428 Å.
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30
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13444309354
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C. Peppe, D. G. Tuck, F. M. de Andrade, J. A. Nobrega, M. A. Brown, R. A. Burrow, J. Organomet. Chem. 2005, 690, 925.
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Nobrega, J.A.4
Brown, M.A.5
Burrow, R.A.6
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31
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28044434807
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note
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CSD range for nonbridging In-C σ bonds: 2.044-2.453 Å, average 2.177 Å.
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37
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0000263741
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F. P. Gabbai, A. Schier, J. Riede, H. Schmidbaur, Inorg. Chem. 1995, 34, 3855.
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Gabbai, F.P.1
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Schmidbaur, H.4
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38
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28044471946
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note
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II center.
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39
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28044448664
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note
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Not including In clusters or bridged In atoms, the In-In bond lengths range from 2.654-2.979 Å with an average of 2.795 Å.
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41
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28044473567
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note
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CSD range for terminal In-Cl bonds: 2.266-2.893 Å, average 2.428 Å.
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43
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28044462354
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note
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Details of the synthesis and characterization of the products presented in this work are located in the Supporting Information.
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