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Volumn 44, Issue 45, 2005, Pages 7453-7456

Crown ether ligation: An approach to low-oxidation-state indium compounds

Author keywords

Crown compounds; Indium; Main group elements; Oxidation; Subvalent compounds

Indexed keywords

COMPLEXATION; COORDINATION REACTIONS; INDIUM COMPOUNDS; OXIDATION;

EID: 28044439192     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200502901     Document Type: Article
Times cited : (53)

References (43)
  • 19
    • 28044451922 scopus 로고    scopus 로고
    • note
    • The +1 oxidation state is generally more stable than the +3 oxidation state for T1, and thus E refers only to B, Al, Ga, and In in this work.
  • 26
    • 28044441612 scopus 로고    scopus 로고
    • 3. A total of 23053 reflections (1.85 ≤ θ ≤ 25.00°) were collected of which 4413 were unique (R(int) = 0.0699); R1 = 0.0930; wR2 = 0.1704; GOF = 1.385; CCDC-280061-280063 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
  • 28
    • 28044434021 scopus 로고    scopus 로고
    • http://www.webelements.com.
  • 29
    • 28044461196 scopus 로고    scopus 로고
    • note
    • CSD range for terminal In-Cl bonds: 2.266-2.893 Å, average 2.428 Å.
  • 31
    • 28044434807 scopus 로고    scopus 로고
    • note
    • CSD range for nonbridging In-C σ bonds: 2.044-2.453 Å, average 2.177 Å.
  • 38
    • 28044471946 scopus 로고    scopus 로고
    • note
    • II center.
  • 39
    • 28044448664 scopus 로고    scopus 로고
    • note
    • Not including In clusters or bridged In atoms, the In-In bond lengths range from 2.654-2.979 Å with an average of 2.795 Å.
  • 41
    • 28044473567 scopus 로고    scopus 로고
    • note
    • CSD range for terminal In-Cl bonds: 2.266-2.893 Å, average 2.428 Å.
  • 43
    • 28044462354 scopus 로고    scopus 로고
    • note
    • Details of the synthesis and characterization of the products presented in this work are located in the Supporting Information.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.