Modelling of long-term diffusion-reaction in a bentonite barrier for radioactive waste confinement

Applied Clay Science

Volumn 30, Issue 3-4, 2005, Pages 181-198

  Montes H, G ^a   Marty, N ^a   Fritz, B ^a   Clement, A ^a   Michau, N ^b  

^a CNRS   (France)

^b ANDRA   (France)

Author keywords

Chemical transformations; Engineered barrier; KIRMAT code; Modelling; MX80 bentonite; Solute diffusion; Swelling capacity

Indexed keywords

COMPUTER SIMULATION; DIFFUSION; GEOCHEMISTRY; GEOLOGICAL REPOSITORIES; ION EXCHANGE; MATHEMATICAL MODELS; RADIOACTIVE WASTE DISPOSAL; SWELLING;

BENTONITE BARRIER; CHEMICAL TRANSFORMATIONS; ENGINEERED BARRIER; SOLUTE DIFFUSION; SWELLING CAPACITY;

BENTONITE;

BENTONITE; CONTAINMENT BARRIER; DIFFUSION; RADIOACTIVE WASTE;

EID: 27944492008     PISSN: 01691317     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.clay.2005.07.006     Document Type: Article

References (47)

1. C. Bertrand B. Fritz J.-F. Sureau Hydrothermal experiments and thermo-kinetic modelling of water-sandstone interactions Chemical Geology 116 1994 189-202
2. C.L. Carnahan Numerical simulation of heterogeneous chemical reactions coupled to fluid flow in varying thermal field Scientific Basis For Nuclear Waste Management XV Mat. Res. Soc. Symp. Proc. vol. 257 1992 683-690
3. 2O en fonction de la température Collection Sciences and Techniques 2004 ANDRA 141 pp.
4. F. Collin X.L. Li J.P. Radu R. Chalier Thermo-hydro-mechanical coupling in clay barriers Engineering Geology 64 2002 179-193
5. B. Fritz Etude themodynamique et simulation des réactions entre minéraux et solutions. Application à la géochimie des altérations et des eaux continetales Mémorie di Scienze Géologiche 41 1975 (Strasbourg, France, 153pp.)
6. B. Fritz Etude thermodynamique et modélisation des réactions hydrothermales et diagénétiques Mémorie di Scienze Géologiche 65 1981 197
7. B. Fritz Y. Tardy Séquence de minéraux secondaires dans l'altération des granites et roches basiques: Modèles thermodynamiques Bulletin de la Société Géologique de France 18 1976 7-12
8. A. Gens L.do.N. Guimaraes A. Garcia-Molina E.E. Alonso Factors controlling rock-clay buffer interaction in a radioactive waste repository Engineering Geology 64 2002 297-308
9. F. Gérard A. Clement B. Fritz Numerical validation of a Eulerian hydrochemical code using a 1D multisolute mass transport system involving heterogeneous kinetically controlled reactions Journal of Contaminant Hydrology 30 1998 201-216
10. Guillaume, D., 2002. Etude expérimentale du système fer-smectite en présence de solution à 80 °C et 300 °C. PhD Thesis, Henri Poincaré University, Nancy I, France, 210 pp.
11. H.C. Helgeson T.H. Brown A. Nigrini T.A. Jones Calculations of mass transfer in geochemical processes involving aqueous solutions Geochimica et Cosmochimica Acta 34 1970 569-592
12. H. Hökmark Hydration of the bentonite buffer in a KBS-3 repository Applied Clay Science 26 2004 219-233
13. H. Hökmark O. Karnland R. Pusch A technique for modeling transport/ conversion processes applied to smectite-to-illite conversion in HLW buffers Engineering Geology 47 1997 367-378
14. K. Idemitsu S. Yano X. Xia Y. Inagaki T. Arima T. Mitsugashira M. Hara Y. Suzuki Diffusion behavior of iron corrosion products in buffer materials Materials Research Society Symposia Proceedings 713 2002 113-120
15. Jacquot, E., 2000. Modélisation thermodynamique et cinétique des réactions géochimiques entre fluides de bassin et socle cristallin. PhD Thesis, Louis Pasteur University, Strasbourg I, France, 202p.
16. Jacquot, E., 2002. Composition des eaux interstitielles des argilites du Callovo-Oxfordien non perturbées. Rapport ANDRA No. D NT ASTR 02-041, 13 pp.
17. G. Kälvenius C. Ekberg TACK-a program coupling chemical kinetics with a two-dimensional transport model in geochemical systems Computers Geosciences 29 2003 511-521
18. Th.J.S. Keijzer P.J. Kleingeld J.P.G. Loch Chemical osmosis in compacted clayey material and the prediction of water transport Engineering Geology 53 1999 151-159
19. J.M. Kluska Modélisation Thermodynamique et Cinétique des Réactions Géochimiques dans une Barrière Ouvragée en Bentonite. Simulations dans des conditions réductrices, de 60 à 180 °C en l'absence et en présence d'une source de fer sur une durée de 20 ans Rapport 2001 ANDRA No. CRP 0CGS 01-004, 34 pp.
20. J.M. Kluska B. Fritz A. Clement Predictions of the mineralogical transformations in a bentonite barrier surrounding an iron radioactive container International Meeting "Clay in Natural and Engineered Barriers for Radioactive Waste Confinement", 8-12 December 2002, Reims, France 2002 ANDRA
21. H. Komine Simplified evaluation for swelling characteristics of bentonites Engineering Geology 71 2004 265-279
22. H. Komine N. Ogata New equations for swelling characteristics of bentonite-based buffer materials Canadian Geotechnical Journal 40 2003 460-475
23. Lantenois, S., 2003. Réactivité fer metal/smectites en milieu hydraté à 80 °C. PhD. Thesis, Orleans University, France, 188 pp.
24. Y. Le Gallo O. Bildstein E. Brosse Coupled reaction-flow modelling of diagenic changes in reservoir permeability, porosity and mineral compositions Journal of Hydrology 209 1998 366-388
25. J. Lehikoinen J. Carlsson A. Muurinen M. Olin P. Salonen Evaluation of factors affecting diffusion in compacted bentonite Materials Research Society Symposia Proceedings 412 1996 675-682
26. C.M. Linklater D.J. Sinclair P.L. Brown Coupled chemistry and transport modelling of sulphidic waste rock dumps at the Aitik mine site, Sweden Applied Geochemistry 20 2005 275-293
27. B. Madé A. Clément B. Fritz Modelling mineral/solution interactions: The thermodynamic and kinetic code KINDISP Computers and Geosciences 20 9 1994 1347-1363
28. M.A. Malusis C.D. Shackelford Theory for reactive solute transport through clay membrane barriers Journal of Contaminant Hydrology 59 2002 291-316
29. Montes-H, G., 2002. Etude expérimentale de la sorption d'eau et du gonflement des argiles par microscopie électronique à balayage environnementale (ESEM) et analyse digitale d'images. PhD Thesis, Louis Pasteur University, Strasbourg I, France, 161 pp.
30. G. Montes-H Y. Geraud Sorption kinetic of water vapour of MX80 bentonite submitted to different physical-chemical and mechanical conditions Colloids and Surfaces. A, Physicochemical Engineering Aspects 235 2004 17-23
31. G. Montes-H J. Duplay L. Martinez C. Mendoza Swelling-shrinkage kinetics of MX80 bentonite Applied Clay Science 22 2003 279-293
32. G. Montes-H J. Duplay L. Martinez Y. Geraud B. Rousset-Tournier Influence of interlayer cations on the water sorption and swelling-shrinkage of MX80 bentonite Applied Clay Science 23 2003 309-321
33. G. Montes-H B. Fritz A. Clement N. Michau A simplified method to evaluate the swelling capacity evolution of a bentonite barrier related to geochemical transformations Applied Geochemistry 20 2005 409-422
34. K.L. Nagy R.T. Cygan J.M. Hanchar N.C. Sturchio Gibbsite growth kinetics on gibbsite, kaolinite, and muscovite: Atomic force microscopy evidence for epitaxy and assessment of reactive surface area Geochimica et Cosmochimica Acta 63 16 1999 2337-2351
35. A. Neaman M. Pelletier F. Villieras The effects of exchanged cations, compression, heating and hydration on textural properties of bulk bentonite and its corresponding purified montmorillonite Applied Clay Science 22 2003 153-168
36. Y. Noack F. Collin D. Nahon J. Delvigne L. Michaux Secondary-mineral formation during natural weathering of pyroxene: Review and thermodynamic approach American Journal of Science 293 1993 111-134
37. Perronnet, M. 2004. Réactivité des matériaux argileux dans un contexte de corrosion métallique. Application au stockage des déchets radioactifs en site argileux. Thèse INPL Nancy, 283 pp.
38. C. Poinssot P. Toulhoat B. Goffé Chemical interaction between a simulated nuclear waste glass and different backfill materials under a thermal gradient Applied Geochemistry 13 6 1998 715-734
39. E. Sauzeat D. Guillaume A. Neaman J. Dubessy M. François C. Pfeiffert M. Pelletier R. Ruch O. Barres J. Yvon F. Villéras M. et Cathelineau Caractérisation minéralogique, cristallochimique et texturale de l'argile MX80 Rapport 2001 ANDRA No. CRP0ENG 01-001, 82 pp.
40. D. Savage D. Noy M. Mihara Modelling the interaction of bentonite with hyperalkaline fluids Applied Geochemistry 17 2002 207-223
41. C.I. Steefel A.C. Lasaga Permeability changes due to coupled flow and reaction In: D.C. Melchior R.L. Basset (Eds.) Chemical Modelling of Aqueous Systems II Amer. Chem. Soc., Symp. Ser. vol. 416 1990 212-216
42. C. Tournassat A. Neaman F. Villiéras D. Bosbach L. Charlet Nanomorphology of montmorillonite particles: Estimation of the clay edge sorption site density by low pressure gas adsorption and AFM observations American Mineralogist 88 2003 1989-1995
43. F.J. Ulm F.H. Heukamp J.T. Germaine Residual design strength of cement-based materials for nuclear waste storage systems Nuclear Engineering and Design 211 2002 51-60
44. P. Vieillard A new method for the prediction of Gibbs free energies of formation of hydrated clay minerals based on the electronegativity scale Clays and Clay Minerals 48 4 2000 459-473
45. P. Vieillard A new method for the prediction of Gibbs free energies of formation of phyllosilicates (10Å and 14Å) based on the electronegativity scale Clays and Clay Minerals 50 3 2002 352-363
46. A.F. White M.L. Peterson Role of reactive-surface-area characterization in geochemical kinetic models In: D. Melchior R. Bassett (Eds.) Chemicals Modelling of Aqueous Systems II Assoc. Chem. Soc. Symp. Series vol. 416 1990 461-475
47. X. Xia K. Idemitsu T. Arima Y. Inagaki T. Ishidera S. Kurosawa K. Iijima H. Sato Corrosion of carbon steel in compacted bentonite and its effect on neptunium diffusion under reducing condition Applied Clay Science 28 2005 89-100