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A Russel type bimolecular decay of the peroxo-radicals is expected to yield 2 and 3 in equal amounts (not shown in Scheme 2). The two-step overoxidation of 2 to 3 and 4 or parallel decomposition routes are responsible for different product distributions generally observed (Table 1).
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19 kinetics are reported in the supporting information (Figures S4 and S5).
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52
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Detected products account for 20-50% of substrate conversion.
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53
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183W NMR spectroscopic experiments, performed at higher POM concentrations, show the _evolution of the original 10 signal spin system to a spectrum dominated by one resonance at -102.50 ppm, whose assignment is unknown so far.
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