Stability of polyynes in air and their degradation by ozonolysis

Polymer Degradation and Stability

Volumn 91, Issue 2, 2006, Pages 317-323

  Cataldo, Franco ^a  

^a Soc Lupi Chem Research Institute   (Italy)

Author keywords

Oligoynes; Oxidation; Ozonolysis; Polyacetylenes; Polymeric ozonides; Polyynes; Spectroscopy; Stability

Indexed keywords

DEGRADATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; OXIDATION; PRECIPITATION (CHEMICAL); THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS;

ALIPHATIC HYDROCARBONS; OLIGOYNES; OZONOLYSIS; POLYACETYLNES; POLYMERIC OZONIDES; POLYYNES;

AROMATIC HYDROCARBONS;

EID: 27844446186     PISSN: 01413910     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.polymdegradstab.2005.04.046     Document Type: Article

References (20)

1. F. Cataldo Polyynes: synthesis, properties and applications 2005 CRC Press, Taylor & Francis Group Boca Raton, FL
2. F. Cataldo Simple generation and detection of polyynes in an arc discharge between graphite electrodes in various solvents Carbon 41 2003 2671 2672
3. F. Cataldo Synthesis of polyynes in a submerged electric arc in organic solvents Carbon 42 2004 129 142
4. F. Cataldo Submerged electric arc between graphite electrodes: a one-pot tool for the synthesis of long chain polyynes in solution Tetrahedron Lett 45 2004 141 144
5. F. Cataldo Polyynes production in a solvent-submerged electric arc between graphite electrodes. Part 1: synthesis and spectroscopy Fuller Nanotub Car Nanostruct 12 2004 603 617
6. F. Cataldo Polyynes production in a solvent-submerged electric arc between graphite electrodes. Part 2: analysis by liquid chromatography Fuller Nanotub Car Nanostruct 12 2004 619 631
7. F. Cataldo Polyynes production in a solvent-submerged electric arc between graphite electrodes. Part 3: chemical reactivity and stability toward air, ozone and light Fuller Nanotub Car Nanostruct 12 2004 633 646
8. 2 in hexane and methanol: experiments and theoretical study. Carbon, in press.
9. S. Szafert, and J.A. Gladysz Carbon in one dimension: structural analysis of the higher conjugated polyynes Chem Rev 103 2003 4175 4205
10. Cataldo F. The simplest approach to prepare solutions of polyynes in hydrocarbons. Tetrahedron Lett 2005;46:3665-7.
11. F. Cataldo A study on ethylene and acetylene photooligomerization and photopolymerization J Photochem Photobiol 99 1996 75 81
12. F. Cataldo Photochemical polymerization of acetylene in water suspension. A study of the resulting photopolymer in comparison with thermally aged linear polyacetylene Eur Polym J 30 1994 1007 1011
13. S.D. Razumovskii, and G.E. Zaikov Ozone and its reactions with organic compounds 1984 Elsevier Amsterdam p. 111-8
14. P.S. Bailey Ozonation in organic chemistry Nonolefinic compounds vol. II 1982 Academic Press New York [chapter 2]
15. D. Cremer, R. Crehuet, and J. Anglada The ozonolysis of acetylene - a quantum chemical investigation J Am Chem Soc 123 2001 6127 6141
16. 70 polymeric oxides (fullerene ozopolymers) Fuller Nanotub Car Nanostruct 11 2003 1 13
17. 70 polymeric fullerene oxides (fullerene polymeric ozonides) Fuller Nanotub Car Nanostruct 11 2003 105 113
18. 70 fullerenes Carbon 40 2002 1457 1467
19. 70 fullerene ozonation Polym Degrad Stab 70 2000 237 243
20. K. Nakanishi Infrared absorption spectroscopy 1972 Holden-Day Inc. San Francisco