Polyynes production in a solvent-submerged electric arc between graphite electrodes. III. Chemical reactivity and stability toward air, ozone, and light

Fullerenes Nanotubes and Carbon Nanostructures

Volumn 12, Issue 3, 2004, Pages 633-646

  Cataldo, Franco ^a  

^a Soc Lupi Chem Research Institute   (Italy)

Author keywords

Bromination; Chemistry; Oxidation; Ozonation; Polyynes; Stability; UV photolysis

Indexed keywords

BROMINE; ELECTRIC ARCS; ELECTRODES; GRAPHITE; MONOCHROMATORS; OXIDATION; OZONIZATION; PHOTOLYSIS; SOLVENTS; ULTRAVIOLET RADIATION;

BROMINATION; OZONATION; POLYYNES; UV PHOTOLYSIS;

ORGANIC POLYMERS;

EID: 5444242862     PISSN: 1536383X     EISSN: None     Source Type: Journal    
DOI: 10.1081/FST-200026951     Document Type: Article

References (14)

1. Cataldo, F. Simple generation and detection of polyynes in an arc discharge between graphite electrodes in various solvents. Carbon 2003, 41, 2671.
2. Cataldo, F. Polyynes production in a solvent-submerged electric arc between graphite electrodes. Part 1: synthesis and spectroscopy. Fullerenes, Nanotubes and Carbon Nanostructures 2004, 12, 603.
3. Cataldo, F. Polyynes production in a solvent-submerged electric arc between graphite electrodes. Part 2: analysis by liquid chromatography. Fullerenes, Nanotubes and Carbon Nanostructures 2004, 12, 619.
4. Cataldo, F. Essay on the synthesis of ozone. Part 1: electrochemical methods. Recent Research and Development in Electrochemistry 2000, 3, 61.
5. Gibtner, Th.; Hampel, F.; Gisselbrecht, J.P.; Hirsch, A. End-cap stabilized oligoynes: model compounds for the linear sp carbon allotrope carbyne. Chem. Eur. J. 2002, 8, 408 (and references cited therein).
6. Hlavaty, J.; Kavan, L.; Kubitsa, J. Carbonaceous materials from end-capped carbynes. Carbon 2002, 40, 345.
7. nH (n = 4-10, 12). Tetrahedron 1972, 28, 4601.
8. Ravagnan, L.; Siviero, F.; Lenardi, C.; Piseri, P.; Barborini, E.; Dilani, P. Cluster-beam deposition and in situ characterization of carbyne-rich carbon film. Phys. Rev. Lett. 2002, 89, 285506.
9. 60 particles suspended in solution. Carbon 2003, 41, 2141.
10. Tsuji, M.; Tsuji, T.; Kuboyama, S.; Yoon, S.H.; Korai, Y.; Tsujimoto, T.; Kubo, K.; Mori, A.; Mochida, I. Formation of hydrogen-capped polyynes by laser ablation of graphite particles suspended in solution. Chem. Phys. Lett. 2002, 355, 101.
11. Cataldo, F. On the action of polymers having unconjugated and cross or linearly conjugated unsaturations: chemistry and technological aspects. Polym. Deg. Stab. 2001, 73, 511.
12. Cataldo, F. Ozone interaction with conjugated polymers. Part 1: polyacetylene. Polym. Deg. Stab. 1998, 60, 223.
13. Cataldo, F. Ozone interaction with conjugated polymers. Part 2: polyphe-nylacetylene. Polym. Deg. Stab. 1998, 60, 233.
14. Ninomiya, I.; Naito, T. Photochemical Synthesis; Academic Press: London, 1989; 212.