Photoassisted reaction of sulfur mustard under UV light irradiation

Environmental Science and Technology

Volumn 39, Issue 22, 2005, Pages 8742-8746

  Zuo, Guo Min ^a   Cheng, Zhen Xing ^a   Li, Guo Wen ^a   Wang, Lian Yuan ^a   Miao, Ting ^a  

^a RESEARCH INSTITUTE OF CHEMICAL DEFENSE   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CONDENSATION; CONTAMINATION; OZONE; PHOTONS; POLYMERS; ULTRAVIOLET RADIATION;

CONDENSED PHASES; HEAVY POLYMERS; LIGHT IRRADIATION; PHOTOASSISTED REACTION;

SULFUR;

MUSTARD GAS; POLYMER;

PHOTODEGRADATION;

AIR MONITORING; ARTICLE; CHEMICAL BOND; LIGHT ABSORPTION; OXIDATION; PHOTOREACTIVITY; ULTRAVIOLET IRRADIATION; VAPOR;

DECONTAMINATION; MUSTARD GAS; ULTRAVIOLET RAYS;

EID: 27744601908     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es050708j     Document Type: Article

References (21)

1. Yang, Y.-C.; Baker, J. A.; Ward, J. R. Decontamination of chemical warfare agents. Chem. Rev. 1992, 92, 1929-1943.
2. Wagner, G. W.; Koper, O. B.; Lucas E.; Decker, S.; Klabunde, K. J. Reactions of VX, GD, and HD with nanosize CaO. Autocatalytic dehydrohalogenation of HD. J. Phys. Chem. B 2000, 104, 5118-5123.
3. Wagner, G. W.; Bartram, P. W.; Koper, O.; Klabunde, K. J. Reactions of VX, GD, and HD with nanosize MgO. J. Phys. Chem. B 1999, 103, 3225-3228.
4. Narske, R. M.; Klabunde, K. J.; Fultz, S. Solvent effects on the heterogeneous adsorption and reactions of (2-chloroethyl) ethyl sulfide on nanocrystalline magnesium oxide. Langmuir, 2002, 18, 4819-4825.
5. Wagner, G. W.; Yang, Y.-C. Rapid nucleophilic/oxidative decontamination of chemical warfare agents. Ind. Eng. Chem. Res. 2002, 41, 1925-1928.
6. Wagner, G. W.; Procell, L. R.; Yang, Y.-C.; Bunton, C. A. Molybdate/peroxide oxidation of mustard in microemulsions. Langmuir, 2001, 17, 4809-4811.
7. 2 surfaces: Principles, mechanisms, and selected results. Chem. Rev. 1995, 95, 735-758.
8. 2 powder. J. Phys. Chem. B 2000, 104, 12299-12305.
9. Obee, T. N.; Satyapal, S. Photocatalytic decomposition of DMMP on titania. J. Photochem. Photobiol., A 1998, 118, 45-51.
10. Vorontsov, A. V.; Panchenko, A. A.; Savinov, E. N.; Lion, C.; Smirniotis, P. G. Photocatalytic degradation of 2-phenethyl-2-chloroethyl sulfide in liquid and gas phases. Environ. Sci. Technol. 2002, 36, 5261-5269.
11. Vorontsov, A. V.; Lion, C.; Savinov, E. N.; Smirniotis, P. G. Pathways of photocatalytic gas-phase destruction of HD simulant 2-chloroethyl ethyl sulfide. J. Catal. 2003, 220, 414-423.
12. 2: Kinetic investigations and catalyst deactivation. Appl. Catal., B 2003, 42, 77-87.
13. 2 powders. J. Phys. Chem. B 2003, 107, 10571-10575.
14. 2 mixed-oxide photocatalyst: Site poisoning by oxidation products and reactivation. Langmuir 2004, 20, 3674-3678.
15. 2. Environ. Sci. Technol. 2003, 37, 3448-3453.
16. 2: Involvement of lattice oxygen. J. Phys. Chem. B 2004, 108, 17857-17865.
17. 2 photocatalytic reduction of bis(2-dipyridyl)- disulfide to 2-mercaptopyridine in aqueous media. Langmuir 1999, 15, 7084-7087.
18. 2. J. Photochem. Photobiol., A 1998, 115, 169-173.
19. 2 bead. J. Mol. Catal. A. Chem. 2001, 172, 247-251.
20. Munro, N. B.; Talmage, S. S.; Griffin, G. D.; Waters, L. C.; Watson, A. P.; King, J. F.; Hauschild, V. The sources, fate, and toxicity of chemical warfare agent degradation products. Environ. Health Perspect. 1999, 107, 933-974.
21. Zuo, G.-M.; Cheng, Z.-X.; Xu, M.; Qiu, X.-Q. Study on the gas-phase photolytic and photocatalytic oxidation of trichloroethylene. J. Photochem. Photobiol., A 2003, 161, 51-56.